Solvation Effects on Quantum Tunneling Reactions

Solvation Effects in Organic Chemistry

(2022) Cynthia J. Burrows et al.   JOURNAL OF ORGANIC CHEMISTRY

Characterization of the Simplest Thiolimine – The Higher Energy Tautomer of Thioformamide

(2021) Bastian Bernhardt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sequential Hydrogen Tunneling in o ‐Tolylmethylene

(2021) Thomas Lohmiller et al.   CHEMISTRY-A EUROPEAN JOURNAL

Solvation Effects in Organic Chemistry: A Short Historical Overview

(2021) Christian Reichardt   JOURNAL OF ORGANIC CHEMISTRY

Heavy-Atom Tunneling in Organic Reactions

(2020) Claire Castro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heavy Atom Tunneling in Semibullvalenes: How Driving Force, Substituents, and Environment Influence the Tunneling Rates

(2020) Tim Schleif et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heavy‐Atom Tunneling Through Crossing Potential Energy Surfaces: Cyclization of a Triplet 2‐Formylarylnitrene to a Singlet 2,1‐Benzisoxazole

(2020) Cláudio M. Nunes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Mystery of the Benzene‐Oxide/Oxepin Equilibrium—Heavy‐Atom Tunneling Reversed by Solvent Interactions

(2020) Tim Schleif et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

External Electric Fields Interrupt the Concerted Cope Rearrangement of Semibullvalene

(2020) Croix J. Laconsay et al.   JOURNAL OF ORGANIC CHEMISTRY

Effects of Entangled IR Radiation and Tunneling on the Conformational Interconversion of 2-Cyanophenol

(2019) A. J. Lopes Jesus et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Competitive Nitrogen versus Carbon Tunneling

(2019) Cláudio M. Nunes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conformer-Specific Heavy-Atom Tunneling in the Rearrangement of Benzazirines to Ketenimines

(2019) Tim Schleif et al.   JOURNAL OF ORGANIC CHEMISTRY

Kinetically unstable 2–isocyanophenol isolated in cryogenic matrices: Vibrational excitation, conformational changes and spontaneous tunneling

(2019) A.J. Lopes Jesus et al.   CHEMICAL PHYSICS LETTERS

Heavy Atom Secondary Kinetic Isotope Effect on H-Tunneling

(2018) André K. Eckhardt et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Activation of Molecular Hydrogen by Arylcarbenes

(2018) Enrique Mendez‐Vega et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photochemistry of 2-Formylphenylnitrene: A Doorway to Heavy-Atom Tunneling of a Benzazirine to a Cyclic Ketenimine

(2017) Cláudio M. Nunes et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen Tunneling above Room Temperature Evidenced by Infrared Ion Spectroscopy

(2017) Mathias Schäfer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tunneling Control of Chemical Reactions: The Third Reactivity Paradigm

(2017) Peter R. Schreiner   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tunnelling in carbonic acid

(2016) J. Philipp Wagner et al.   CHEMICAL COMMUNICATIONS

On the Photochemistry of 1,2-Benzisoxazole: Capture of Elusive Spiro-2H-azirine and Ketenimine Intermediates

(2016) Cláudio M. Nunes et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The first experimental observation of the higher-energy trans conformer of trifluoroacetic acid

(2016) R.F.G. Apóstolo et al.   JOURNAL OF MOLECULAR STRUCTURE

Concerted Electronic and Nuclear Fluxes During Coherent Tunnelling in Asymmetric Double-Well Potentials

(2016) Timm Bredtmann et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Thermally activated tunneling in organic reactions

(2016) Edyta M. Greer et al.   TETRAHEDRON

Activation of Molecular Hydrogen by a Singlet Carbene through Quantum Mechanical Tunneling

(2015) Stefan Henkel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Narrowband NIR-Induced In Situ Generation of the High-Energy Trans Conformer of Trichloroacetic Acid Isolated in Solid Nitrogen and its Spontaneous Decay by Tunneling to the Low-Energy Cis Conformer

(2015) R. F. G. Apóstolo et al.   CROATICA CHEMICA ACTA

Reactions that involve tunneling by carbon and the role that calculations have played in their study

(2015) Weston Thatcher Borden   Wiley Interdisciplinary Reviews-Computational Molecular Science

Deuterium and Hydrogen Tunneling in the Hydrogenation of 4-Oxocyclohexa-2,5-dienylidene

(2014) Stefan Henkel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heavy-Atom Tunneling in the Ring Opening of a Strained Cyclopropene at Very Low Temperatures

(2014) Melanie Ertelt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Near-infrared and ultraviolet induced isomerization of crotonic acid in N2 and Xe cryomatrices: First observation of two high-energy trans C–O conformers and mechanistic insights

(2014) Nihal Kuş et al.   JOURNAL OF CHEMICAL PHYSICS

Tunneling Isomerization of Small Carboxylic Acids and Their Complexes in Solid Matrixes: A Computational Insight

(2014) Masashi Tsuge et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Near-Infrared Laser-Induced Generation of Three Rare Conformers of Glycolic Acid

(2014) Anna Halasa et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Conformational Switching in Pyruvic Acid Isolated in Ar and N2 Matrixes: Spectroscopic Analysis, Anharmonic Simulation, and Tunneling

(2014) Igor Reva et al.   JOURNAL OF PHYSICAL CHEMISTRY A

The reactivity game: theoretical predictions for heavy atom tunneling in adamantyl and related carbenes

(2014) S. Kozuch   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Aryl Nitrene Rearrangements: Spectroscopic Observation of a Benzazirine and Its Ring Expansion to a Ketenimine by Heavy-Atom Tunneling

(2013) Hiroshi Inui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Infrared spectra of free radicals and protonated species produced in para-hydrogen matrices

(2013) Mohammed Bahou et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Matrix-isolation and ab initio study of the complex between formic acid and xenon

(2012) Qian Cao et al.   JOURNAL OF MOLECULAR STRUCTURE

Tunneling Lifetime of the ttc/VIp Conformer of Glycine in Low-Temperature Matrices

(2012) Gábor Bazsó et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Infrared Characterization of the HCOOH···CO2 Complexes in Solid Argon: Stabilization of the Higher-Energy Conformer of Formic Acid

(2012) Masashi Tsuge et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Tunneling Rearrangement of 1-Azulenylcarbene

(2012) Stefan Henkel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isotope Effects and Heavy-Atom Tunneling in the Roush Allylboration of Aldehydes

(2012) Mathew J. Vetticatt et al.   ORGANIC LETTERS

Methylhydroxycarbene: Tunneling Control of a Chemical Reaction

(2011) P. R. Schreiner et al.   SCIENCE

Formic and acetic acids in a nitrogen matrix: Enhanced stability of the higher-energy conformer

(2010) Susy Lopes et al.   JOURNAL OF CHEMICAL PHYSICS

Interaction of Formic Acid with Nitrogen: Stabilization of the Higher-Energy Conformer

(2010) Kseniya Marushkevich et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Electronic Effects on Atom Tunneling: Conformational Isomerization of MonomericPara-Substituted Benzoic Acid Derivatives

(2010) Shadi Amiri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Evidence for Heavy-Atom Tunneling in the Ring-Opening of Cyclopropylcarbinyl Radical from Intramolecular12C/13C Kinetic Isotope Effects

(2010) Ollie M. Gonzalez-James et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Calculations Predict That Carbon Tunneling Allows the Degenerate Cope Rearrangement of Semibullvalene to Occur Rapidly at Cryogenic Temperatures

(2010) Xue Zhang et al.   ORGANIC LETTERS