4.1 Article

Upgrading of superior strength-ductility trade-off of CoCrFeNiMn microstructural

Journal

MATERIALIA
Volume 22, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.mtla.2022.101394

Keywords

High entropy alloy; Thermomechanical processing; Microstructure engineering; Strength-ductility trade-off

Funding

  1. National Research Foundation of Korea (NRF) - Korea Gov-ernment (MSIP) [NRF-2021R1A2C3006662]

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In this study, a simple thermomechanical process was proposed to address the strength-ductility trade-off issue in CoCrFeNiMn high entropy alloy. By retaining partially recovered deformation-induced twins and appropriate size and volume fraction of precipitates, a microstructure with improved mechanical properties was obtained.
One of the challenging phenomena in the materials science community is the issue of the strength-ductility trade -off. Pre-strain followed by annealing at low temperatures was used as a novel strategy to overcome the strength-ductility trade-off of CoCrFeNiMn high entropy alloy. The proposed process aims to retain the deformation-induced twins after partial recovery. However, the lack of precipitate in the processed alloy bears in mind to consider the effect of precipitation. In this paper, for the first time, we proposed a simple thermomechanical process including light cryogenic rolling (reduction of thickness-28%) followed by low-temperature annealing (at 500 degrees C for 180 min) to obtain a unique microstructure. The microstructure with partial recovery contains retained deformation-induced twins along with bcc Cr-rich precipitates under optimum conditions (size and vol-ume fraction) and no brittle sigma precipitates. This microstructure provides the appropriate balance between deformation and precipitation strengthening. The microstructure exhibits much improved mechanical properties (UTS-1.25 GPa and uniform elongation-15%). Additionally, a model was introduced for predicting mechanical properties using microstructural parameters. The present results indicated that this thermomechanical process-ing could be used as an innovative processing strategy for achieving superior strength-ductility trade-off by microstructural engineering. We believe that a similar concept may be applied for optimizing the mechanical properties of other fcc high or medium entropy alloys based on the Co-Cr-Fe-Ni-Mn system.

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