4.2 Article

New Measurements of the Apparent Thermal Conductivity of Nanofluids and Investigation of Their Heat Transfer Capabilities

Journal

JOURNAL OF CHEMICAL AND ENGINEERING DATA
Volume 62, Issue 1, Pages 491-507

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.jced.6b00767

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The aim of this paper is to investigate in depth whether adding nanoparticles or nanotubes to a fluid enhances its heat transfer capabilities. For this reason, the thermal conductivities and viscosities of a selection of nanofluids were thoroughly examined. The systems studied were (a) ethylene glycol with added CuO, TiO2, or Al2O3 nanoparticles and (b) water with TiO2 or Al2O3 nanoparticles or multiwall carbon nanotubes (MWCNTs). All of the measurements were conducted at 298.15 K. In a very recent paper, it was shown that instruments employing the transient hot-wire technique can produce excellent measurements when a finite element method (FEM) is employed to describe the instrument for the geometry of the hot wire. Furthermore, it was shown that an approximate analytic solution can be employed with equal success, over the time range from 0.1 to 1 s, provided that four specific criteria are satisfied. Subsequently a transient hot-wire instrument was, designed, constructed, and employed for the measurement of the thermal conductivities of nanofluids with an uncertainty of about 2%. A second, validated technique, namely, a hot-disk instrument, was also employed to conduct measurements on some of the systems to provide mutual support for the tesults of the thermal conductivity measurements. To investigate the effect of any enhancement Of the thermal conductivity of the fluids on their application in practical heat transfer, the viscosities of typical concentrations of:several of the nanofluids were also measured. A parallel-plate rotational rheometer, able to measure the viscosities of Newtonian and non-Newtonian liquids with an uncertainty of better than 5%, was employed for, these measurements because most of the nano fluids considered showed behavior comparable to a Bingham plastic. All of these measurements have:allowed an investigation of the change in the heat transfer capability of the base fluid when nanoparticles or MWCNTs are added to it for a typical heat exchanger. It is shown that in general the combined changes in physical properties that accompany suspension of nanoparticles in fluids mean that the heat transfer benefits are all rather modest, even when they are achieved.

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