4.2 Article

Thermal conductivity and flammability of multiwall carbon nanotube/polyurethane foam composites

Journal

JOURNAL OF CELLULAR PLASTICS
Volume 53, Issue 2, Pages 215-230

Publisher

SAGE PUBLICATIONS LTD
DOI: 10.1177/0021955X16644893

Keywords

Rigid polyurethane foam; nanocomposites; carbon nanotubes; thermal conductivity; thermal resistance; flammability

Funding

  1. CONACYT (Mexico) [220513]
  2. CIAM [188089]

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The thermal conductivity and fire response of multiwall carbon nanotube/polyurethane foam composites are investigated for similar to 45 kg/m(3) foams with multiwall carbon nanotube concentrations of 0.1, 1, and 2 wt.%. The thermal conductivity of such nanocomposites shows a modest increase with increased multiwall carbon nanotube content, which is explained by a high value of interfacial thermal resistance, as predicted by existent thermal models. A strong correlation between multiwall carbon nanotube content, foam's cellular morphology, and fire behavior was observed. The flame propagation speed increases with the addition of 0.1 wt.% multiwall carbon nanotubes and then reduces as the multiwall carbon nanotube content increases. The mass lost after flame extinction reduces with the addition of multiwall carbon nanotubes, suggesting an increased resistance to flame attack due the multiwall carbon nanotube presence.

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