Article
Chemistry, Multidisciplinary
Qifan Liu, Zhiyuan Ma, Zhe Chen, Mangwei Cui, Hao Lei, Jiaqi Wang, JinBo Fei, Ning He, Yao Liu, Qingjiang Liu, Wenzheng Li, Yan Huang
Summary: A modification strategy of polyaniline (PANI) coating on zinc ferricyanide (ZnHCF) is proposed to inhibit the dissolution of ZnHCF and achieve two stable discharge voltage platforms and high capacity in Zn-ion batteries. The battery also exhibits high stretchability and maintains stable electrochemical properties during stretching.
CHEMICAL COMMUNICATIONS
(2022)
Review
Chemistry, Multidisciplinary
Zhiheng Li, Jian Tan, Caiyun Gao, Yuan Wang, Yonggang Wang, Mingxin Ye, Jianfeng Shen
Summary: Organic compounds are attractive alternatives to conventional inorganic materials for aqueous zinc-ion batteries, due to their high theoretical capacities, structural tunability, controllable synthesis, and environmental friendliness. This review provides a systematic overview of recent developments, energy storage mechanisms, and design strategies for aqueous Zn-organic batteries (ZOBs). It summarizes the ion storage mechanisms, analyzes the dynamic behavior, and highlights the synthesis strategies of organic electrode materials. It also discusses strategies to improve the electrochemical performance and the challenges for practical applications of aqueous ZOBs.
ENERGY & ENVIRONMENTAL SCIENCE
(2023)
Article
Chemistry, Physical
Yunxia Liang, Fangong Kong, Zirui Wang, Manman Ren, Xiaoxia Cai, Weiliang Liu, Jinshui Yao, Changbin Zhang, Hui Zhao
Summary: The electrodeposited manganese dioxide on the Zn metal electrode is designed to guide uniform zinc deposition, which greatly extends the service life and improves the cycling stability of ARZIBs.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Chemistry, Multidisciplinary
Baozhi Yu, Ye Fan, Srikanth Mateti, Donggun Kim, Chen Zhao, Shengguo Lu, Xin Liu, Qiangzhou Rong, Tao Tao, Khagesh Kumar Tanwar, Xin Tan, Sean C. Smith, Ying Ian Chen
Summary: By utilizing stable lithium cloth anodes, polysulfone-functionalized separators, and sulfur/graphene/boron nitride nanosheet cathodes, the shuttle effect of polysulfides and the growth of lithium dendrites have been effectively controlled, leading to excellent mechanical flexibility and outstanding electrochemical performance in flexible lithium-sulfur batteries, indicating great potential for large-scale development of high-performance flexible batteries.
Review
Energy & Fuels
Wentao Yu, Yongfu Liu, Lingli Liu, Xulai Yang, Yongsheng Han, Peng Tan
Summary: Zn-LiMn2O4 hybrid batteries, with advantages of high energy density, low cost, inherent safety, and environmental friendliness, are still facing challenges in stability and performance improvement. Recent research has focused on enhancing the performance and stability of the LiMn2O4 electrode, Zn electrode, and aqueous electrolyte.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Chemistry, Physical
Jinyun Zhu, Tianzhen Jian, Yuxin Wu, Wenqing Ma, Yao Lu, Lingchao Sun, Fanhui Meng, Bo Wang, Feipeng Cai, Jinhua Gao, Guangda Li, Lishan Yang, Xiuling Yan, Caixia Xu
Summary: This study investigates the Zn2+ storage mechanism of VS2 nanosheets as cathode for ZIBs, experimentally demonstrating the intercalation/conversion reaction mechanism of the Zn/VS2 battery. By controlling the recharge depth, irreversible conversion reactions can be blocked, leading to improved cycling performance and energy efficiency of the battery.
APPLIED SURFACE SCIENCE
(2021)
Article
Engineering, Environmental
Mei Guan, Zhiguang Li, Li Hao, Minyan Zhou, Long Chen, Huayao Chen, Hongjun Zhou, Xinhua Zhou
Summary: The study developed a strategy for the functionalization of boron nitride nanosheets, achieving high dispersibility at high concentrations and demonstrating loading and release of pesticides and essential oils through redox stimuli, with low cytotoxicity and antibacterial activity.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Nermina Brljak, Ruitao Jin, Tiffany R. Walsh, Marc R. Knecht
Summary: The study identified a peptide sequence with affinity for h-BN, called BP7, and developed a new method to manipulate the surface properties of nanosheet materials through mutation studies and bio-conjugation. When conjugated with a fatty acid, BP7 was able to create highly viscoelastic interfaces, offering a new pathway for organizing and conjugating h-BN nanosheets in liquid water.
Article
Chemistry, Physical
Canbin Deng, Yang Li, Sijing Liu, Jinglei Yang, Baoling Huang, Jiapeng Liu, Jiaqiang Huang
Summary: Aqueous zinc-ion batteries (ZIBs) are a promising option for large-scale energy storage applications due to their low cost, eco-friendliness, and high safety. However, they currently face challenges such as poor cycling stability caused by dendrite growth, corrosion, and hydrogen evolution at the electrolyte/anode interface. In this study, humic acid (HA), a natural soil ingredient, is applied to the zinc surface to stabilize the anode/electrolyte interface. Theoretical calculations and electrochemical analyses show that HA improves the Zn deposition kinetics, suppresses corrosion and hydrogen evolution, and enhances the overall performance of ZIBs. This research provides valuable insights for engineering electrolyte/electrode interfaces and suggests the potential of leveraging natural materials and mechanisms for more sustainable batteries.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Physical
Lu Sun, Yuanqing Yao, Lixin Dai, Miaolun Jiao, Baofu Ding, Qiangmin Yu, Jun Tang, Bilu Liu
Summary: This study developed a high-performance zinc dual-ion battery using an environmentally friendly hydrogel-based water-in-salt electrolyte. The battery exhibited fast degradation, high ionic conductivity, and high stability, paving the way for sustainable and high-performance energy storage systems.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Shaocheng Li, Xianlang Lu, Yanda Lou, Kejun Liu, Benxue Zou
Summary: Boron nitride (BN) has attracted attention for its various excellent properties, and a novel method to produce boron nitride nanosheets (BNNSs) has been proposed. Characterization results showed that the prepared BNNSs had high crystallinity, improved stripping efficiency of h-BN, enhanced performance and yield of BNNSs, and reduced cost and environmental pollution of BNNS preparation.
Article
Green & Sustainable Science & Technology
Degu Lere Keshebo, Chien-Chieh Hu, Wei-Song Hung, Chih-Feng Wang, Hsieh-Chih Tsai, Kueir-Rarn Lee, Juin-Yih Lai
Summary: A novel and green method using tannic acid for aqueous-phase exfoliation of hexagonal boron nitride nanosheets was demonstrated in this study, showing potential for environmental membrane applications. The prepared membrane exhibited excellent stability, solvent transport efficiency, solute screening, and antifouling performance in both water and organic solvents. The robust nanochannel and thin laminar networks of the nanosheets contributed to the membrane's rapid solvent transport and efficient separation capabilities.
JOURNAL OF CLEANER PRODUCTION
(2021)
Review
Materials Science, Multidisciplinary
Mingjie Wu, Gaixia Zhang, Huaming Yang, Xianhu Liu, Marc Dubois, Marc A. Gauthier, Shuhui Sun
Summary: Due to their high safety, abundant reserves, low cost, and high energy density, aqueous Zn-based rechargeable batteries (AZBs) have attracted extensive attention. To improve the performance of AZBs, efforts are focused on modifying electrode materials and electrolytes, as well as exploring different redox mechanisms based on various cathode materials and aqueous electrolytes.
Article
Engineering, Environmental
Raghubeer S. Bangari, Anshul Yadav, Jayam Bharadwaj, Niraj Sinha
Summary: This study synthesized BNNS incorporated PVDF-based membranes using phase inversion method for removal of MB from water. The optimized BNNS-PVDF membrane demonstrated high adsorption capacity, good separation behavior and continuous flow adsorption of MB contaminated water.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2022)
Article
Chemistry, Physical
Mengyang Niu, Zheng Zhao, Baokai Wang, Chang Yu, Mengyi Li, Jiajun Hu, Lifeng Zhu, Xu Hao, Shiqin Wan, Ming Yue, Weiwei Xuan, Qipeng Lu, Wenbin Cao, Kexin Chen, Qi Wang
Summary: In this study, flexible composite films with extremely high in-plane thermal conductivity were prepared using one-dimensional AlN whiskers and nanofibrillated cellulose. The composite films exhibited excellent thermal conductivity, thermal stability, and mechanical strength, indicating broad potential applications.
JOURNAL OF MATERIALS CHEMISTRY A
(2023)
Article
Chemistry, Physical
Orkun Furat, Donal P. Finegan, Zhenzhen Yang, Matthias Neumann, Sangwook Kim, Tanvir R. Tanim, Peter Weddle, Kandler Smith, Volker Schmidt
Summary: The operating temperature has a significant impact on the degradation behavior of batteries. This study investigates the structural degradation of lithium-ion positive electrodes under different operating temperatures, and finds that particle porosity increases with higher cycling temperature, while particle surface area remains similar across different cycling-temperature aging conditions.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Junyan Li, Ming Lu, Weijia Zheng, Wei Zhang
Summary: MXenes are two-dimensional materials with unique structures and properties, which have attracted significant scientific interest. Ion intercalation, as an important mechanism, plays a crucial role in regulating the electronic and chemical properties of MXene materials. This review provides an overview of the interaction events between ions and MXenes, including advanced characterization techniques, influencing factors, mechanisms, and functionalization roles of ion intercalation.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Zhengtai Zha, Tianjiang Sun, Diantao Li, Tao Ma, Weijia Zhang, Zhanliang Tao
Summary: A novel zwitterion additive is developed to improve the electrochemical performance and cycling stability of aqueous zinc batteries. The zwitterion forms a stable solid electrolyte interphase on the electrode surface, isolating the zinc anode from the electrolytes and enabling fast zinc ion migration. The proposed electrolyte shows promising results in symmetric cells and full cells, with long cycling stability and high capacity retention.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Nyung Joo Kong, Myeong Seon Kim, Jae Hyun Park, Jongbok Kim, Jungho Jin, Hyun-Wook Lee, Seok Ju Kang
Summary: Polymeric conducting binders have significant research value as they can serve as both binders and conducting agents, increasing the proportion of active materials in batteries and the volumetric energy density. This study explores the potential of a composite of PEDOT:PSS and polyethylene glycol (PEG) as a high-performing binder for silicon anodes. The addition of PEG polymer enhances the conductivity of PEDOT:PSS and improves the mechanical properties of the silicon anode, resulting in extended cycle endurance. The use of operando optical microscopy allows for direct observation of the binder's operation. Consequently, the bifunctional PEDOT:PSS/PEG binder shows promise for high-performance lithium-ion battery binders.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Yangze Huang, Lixuan Zhang, Jiawen Ji, Chenyang Cai, Yu Fu
Summary: This study proposed a novel temperature-dependent viscoelastic liquid electrolyte and a hollow transition bi-metal selenide as the sulfur host material to address the issues in Li-S batteries. The experiments showed promising results in stabilizing the anode and improving cycling performance.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Ao Yu, Wei Zhang, Nimanyu Joshi, Yang Yang
Summary: This review provides a comprehensive overview of research progress in ZIB anodes, including protective coating layers on zinc surfaces and intercalated anode materials. By designing protective coating layers and selecting appropriate intercalated anode materials, the inherent limitations of zinc metal anode can be overcome, leading to improved reliability and performance of ZIBs.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Xin Wang, Yumiao Tian, Konghua Yang, Chenhui Ma, Wenqiang Lu, Xiaofei Bian, Nan Chen, Heng Jiang, Yan Li, Xing Meng, Pengyue Gao, Dong Zhang, Fei Du
Summary: Researchers developed a new sandwich deposition approach using boron nitride layer as a current collector, which enhances the performance of aqueous zinc-ion batteries.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Sang Jun Lee, Dongwoo Kang, Dong Yeol Hyeon, Dong Seok Kim, Suyoon Eom, Su Hwan Jeong, Dong Park Lee, Dawon Baek, Jou-Hyeon Ahn, Gyeong Hee Ryu, Kwi-Il Park, San Moon, Joo-Hyung Kim
Summary: This study utilizes the ice-templating method to create a self-supporting three-dimensional hierarchical porous structure, which effectively inhibits sodium dendrite growth and improves the performance and longevity of sodium-metal batteries.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Yifan Yu, Meng Lei, Yangyang Liu, Keyi Chen, Chuanzhong Lai, Jiulin Hu, Chilin Li
Summary: Metal fluorides as conversion-reaction cathodes have advantages such as low cost, environmentally friendly, and high energy density. In this study, a hydroxyl-rich copper fluoride (Cu2(OH)3F) was proposed as a conversion cathode, coupled with an electrolyte additive engineering, to address the poor reversibility issue. The presence of OH in Cu2(OH)3F enables effective suppression of Cu+ dissolution, resulting in better reaction reversibility and kinetics.
ENERGY STORAGE MATERIALS
(2024)
