Article
Chemistry, Multidisciplinary
Jimin Guo, Yunlong Yu, Wei Zhu, Rita E. Serda, Stefan Franco, Lu Wang, Qi Lei, Jacob Ongudi Agola, Achraf Noureddine, Evelyn Ploetz, Stefan Wuttke, C. Jeffrey Brinker
Summary: Armored red blood cells are a new type of hybrid biomaterials with native red blood cells assembled within and protected by a functional exoskeleton of interconnected MOF nanoparticles. The formation of exoskeletons is rapid and based on metal-phenolic coordination and hydrogen-bonding interactions. Armored RBCs retain the original properties of RBCs and demonstrate enhanced resistance against external stressors, offering potential applications in blood nitric oxide sensing or multimodal imaging.
ADVANCED FUNCTIONAL MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Tian Wang, Weichao Chen, Qingda Liu, Wei Wang, Yinming Wang, Biao Wu, Wenxiong Shi, Yunqing Zhu, Peilei He, Xun Wang
Summary: Tailoring the spatial distribution of ligands on polyoxometalates has led to the formation of subnanometer rhombic dodecahedral building blocks, which self-assemble into microscale rhombic dodecahedral POM assemblies. These assemblies exhibit excellent catalytic performance in the cycloaddition of CO2 with epoxides.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Alessandro Alcinesio, Idil Cazimoglu, Gabriella Raye Kimmerly, Vanessa Restrepo Schild, Ravinash Krishna Kumar, Hagan Bayley
Summary: The authors applied modular design to construct modular synthetic tissues, assembling different functional 3D-printed building blocks for storing and releasing reagents, performing logic operations, responding to magnetic fields, and encapsulating living cells. They successfully built synthetic tissues capable of transmitting electrical signals and assembled hybrid tissues composed of both synthetic modules and modules containing living cells. By incorporating mutant protein nanopores within the building blocks, they created modular synthetic tissues with electrical outputs modulated by chemical inputs.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Multidisciplinary Sciences
Zhihua Cheng, Matthew R. Jones
Summary: The study reports the self-assembly of 2D chiral superlattices from achiral tetrahedron-shaped building blocks, explains the formation mechanism, and lays the scientific foundation for the high-throughput assembly of planar chiral metamaterials.
NATURE COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Andreas Frank, Christian Hils, Melina Weber, Klaus Kreger, Holger Schmalz, Hansooo-Werner Schmidt
Summary: By matching the functional groups of the surface patches on polymer fibers with the corresponding substituents of BTAs, specific superstructures can be induced.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2021)
Article
Chemistry, Multidisciplinary
Cheng Zhu, Jianbo Jin, Mengyu Gao, Maria C. Folgueras, Ye Zhang, Chung-Kuan Lin, Peidong Yang, Alexander M. Oddo
Summary: The structural diversity and tunable optoelectronic properties of halide perovskites come from the rich chemistry of metal halide ionic octahedra. The ability to manipulate the assembly of these octahedral building blocks is crucial for constructing new perovskite materials.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2022)
Review
Chemistry, Multidisciplinary
Kun Lan, Qiulong Wei, Dongyuan Zhao
Summary: This Review discusses the synthesis of novel mesoporous TiO2 materials, with a focus on the monomicelle assembly strategy for controlling the formation of mesostructured TiO2. Typical applications of mesoporous TiO2 in batteries and photocatalysis are highlighted, and the outlook for the synthesis of mesoporous TiO2 with tailored architectures through self-assembly is discussed.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Review
Chemistry, Multidisciplinary
Jamie M. Cameron, Geoffroy Guillemot, Theodor Galambos, Sharad S. Amin, Elizabeth Hampson, Kevin Mall Haidaraly, Graham N. Newton, Guillaume Izzet
Summary: Hybrid polyoxometalates (POMs) have emerged as promising building blocks for the construction of new nanomaterials, offering a range of attractive properties and design opportunities. Their ability to be covalently coupled to a variety of organic moieties allows for the rational design of complex molecular architectures with unique functionalities, showing great potential for applications in catalysis, energy-storage, and molecular biology.
CHEMICAL SOCIETY REVIEWS
(2022)
Review
Nanoscience & Nanotechnology
Nam Hyeong Kim, Hojae Choi, Zafar Muhammad Shahzad, Heesoo Ki, Jaekyoung Lee, Heeyeop Chae, Yong Ho Kim
Summary: Proteins play a crucial role in various phenomena throughout the life of living things. They form complex structures and regulate reactions, as well as exhibit different biological functions depending on the situation. The self-assembly of proteins is the fundamental principle behind the formation of hierarchical structures. These structures enable multivalent binding, ultra-sensitive regulation, and compartmentalization, and have been extensively utilized in biology. Recent advancements in the de novo design of protein assemblies have shown promising applications in understanding biological phenomena and therapeutics.
Article
Chemistry, Multidisciplinary
Bing Hu, Wei-Yang Wen, Hai-Yan Sun, Yan-Qi Wang, Ke-Zhao Du, Wen Ma, Guo-Dong Zou, Zhao-Feng Wu, Xiao-Ying Huang
Summary: In this study, a new hierarchical assembly strategy is proposed for the rational and precise construction of complex single-crystal superstructures. Unprecedented superclusters in Rubik's cube form are formed by aggregating oxohalide clusters as secondary building units. These Rubik's cubes then act as isolable tertiary building units to assemble diverse single-crystal superstructures. The captured intermediate assembly states provide a profound understanding of the assembly process at the atomic level.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Review
Chemistry, Multidisciplinary
Li Shao, Jinrong Ma, Jesse L. Prelesnik, Yicheng Zhou, Mary Nguyen, Mingfei Zhao, Samson A. Jenekhe, Sergei V. Kalinin, Andrew L. Ferguson, Jim Pfaendtner, Christopher J. Mundy, James J. De Yoreo, Franccommaois Baneyx, Chun-Long Chen
Summary: This article discusses the characteristics and applications of hierarchical materials that exhibit order over multiple length scales. It highlights the advantages of using proteins, peptides, and peptidomimetics as building blocks for hierarchical structures. The article reviews recent progress in the rational design and characterization of hierarchical materials, with a focus on stimuli-responsive and smart architectures. It also explores the use of computational simulations and data-driven predictions to understand the assembly process of hierarchical materials. The article suggests that further research in these areas will enable predictive materials synthesis based on designed interactions, surface effects, and solution conditions.
Review
Chemistry, Physical
Qianwei Liu, Bixin Jin, Qin Li, Huanzhi Yang, Yunjun Luo, Xiaoyu Li
Summary: Self-assembly is a common phenomenon in living systems, and scientists have been trying to emulate its intricacy, homogeneity, and versatility in artificial building blocks. Self-sorting assembly in multicomponent systems allows for the spontaneous recognition and spatial aggregation of the same or interactive building units, leading to well-ordered products or hierarchical structures in a one-step manner. This efficient assembly strategy has attracted significant research attention, particularly in artificial systems using supramolecular and polymeric building blocks.
Review
Chemistry, Multidisciplinary
Jose V. Rival, Paloli Mymoona, Kavalloor Murali Lakshmi, Nonappa, Thalappil Pradeep, Edakkattuparambil Sidharth Shibu
Summary: Ligand protected noble metal nanoparticles serve as excellent building blocks for colloidal self-assembly, leading to the development of multifunctional nanomaterials with enhanced optoelectronic properties and well-defined molecular compositions. The emergence of atomically precise monolayer thiol-protected noble metal nanoclusters has overcome challenges in plasmonic nanoparticle self-assemblies, showing hierarchical structural complexity and potential applications in various fields. This review focuses on the formulation and periodic self-assembly of different noble metal nanoclusters, as well as discusses the amplification of physicochemical properties induced by self-assembly and their potential applications in molecular recognition, sensing, gas storage, device fabrication, bioimaging, therapeutics, and catalysis.
Article
Chemistry, Multidisciplinary
Ke Li, Shu Zhang, Kai-Ling Zhu, Li-Ping Cui, Le Yang, Jia-Jia Chen
Summary: Using an aqueous flowing in-operando Raman characterization system, researchers have successfully visualized the assembly process of single-core molybdate into giant molybdenum blue clusters. They also identified the intermediates and mechanisms driving the self-assembly process, shedding light on the catalytic role of the H+/e(-) redox couple.
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
(2023)
Article
Chemistry, Organic
Qixia Bai, Ying Liu, Tun Wu, Haoyue Su, Gang Chen, Yuming Guan, Ming Wang, Ting-Zheng Xie, Zhe Zhang, Pingshan Wang
Summary: The structures of metallocages are sensitive to various stimuli due to the dynamic reversibility of the coordination-driven force, with the strength of the metal ligand dative bonds playing a crucial role.
ORGANIC CHEMISTRY FRONTIERS
(2022)
Editorial Material
Multidisciplinary Sciences
Yan Ai, Wei Li, Dongyuan Zhao
Summary: 2D mesoporous materials, which combine the unique features of 2D and mesoporous structures, represent a new research direction in materials science. This perspective article highlights the latest progress of 2D mesoporous materials.
NATIONAL SCIENCE REVIEW
(2022)
Review
Computer Science, Artificial Intelligence
Jinghua Zhang, Chen Li, Yimin Yin, Jiawei Zhang, Marcin Grzegorzek
Summary: Microorganisms are widely distributed in human daily living environment and play essential roles in environmental pollution control and health. Automatic microorganism image analysis faces challenges such as the need for robust algorithms and addressing image characteristic issues.
ARTIFICIAL INTELLIGENCE REVIEW
(2023)
Article
Chemistry, Physical
Jun-Ye Zhang, Jiayu Liang, Bingbao Mei, Kun Lan, Lianhai Zu, Tiancong Zhao, Yuzhu Ma, Yan Chen, Zirui Lv, Yi Yang, Chuanghui Yu, Zhe Xu, Bao Yu Xia, Wei Li, Qinghong Yuan, Dongyuan Zhao
Summary: In this study, Ni/NiO@MoO3-x composite nanoarrays were synthesized through a moderate reduction strategy, which exhibited ultrahigh alkaline HER activity and higher stability compared to the traditional Pt/C catalyst.
ADVANCED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Yan Yu, Yujun Xie, Pengfei Zhang, Wei Zhang, Wenxing Wang, Shuyu Zhang, Qiongrong Ou, Wei Li
Summary: The design of unique U-SiO2 dielectric support nanoparticles successfully regulates the surface plasmon resonance properties of small metallic nanoparticles. The formation of plasmonic hot spots leads to highly efficient visible-light-driven photocatalytic activity.
Article
Chemistry, Multidisciplinary
Hui Xu, Junliang Chen, Zhenghao Zhang, Chin-Te Hung, Jianping Yang, Wei Li
Summary: In this study, a highly efficient electrocatalytic reduction catalyst was prepared by encapsulating ultrasmall CuPd alloy nanoparticles. The catalyst exhibits high conversion efficiency, selectivity and stability. Experimental and theoretical results also reveal the unique selectivity of different catalysts for the reduction of NO3-.
ADVANCED MATERIALS
(2023)
Article
Biochemical Research Methods
Liang Peng, Huarong Peng, Wei Li, Dongyuan Zhao
Summary: Functional mesoporous carbonaceous nanomaterials with large pores have wide accessibility and can transport chemicals efficiently in various fields including biomedical applications, gas separation, catalysis, sensing, and energy storage and conversion. The assembly of monomicelles, composed of block copolymers/surfactants and precursor species, has been used to control the nanostructure and mesoporosity of carbonaceous nanomaterials. This method allows for a high degree of control over the final product's structure, making it possible to shape the nanomaterial into unique nanostructures that are otherwise difficult to synthesize using conventional templating methods.
Article
Chemistry, Physical
Yao Liu, Xiangyong Wu, Abdul Moeez, Zhi Peng, Yongyao Xia, Dongyuan Zhao, Jun Liu, Wei Li
Summary: This paper investigates the degradation mechanisms of NASICON-type sodium vanadium phosphate (NVP) cathode materials in sodium-ion batteries (SIBs) and proposes a solution to the capacity degradation caused by sodium loss. By developing a sodium-rich NVP cathode (Na4VP) and assembling full cells using Na-free anode and hard carbon anode, the authors were able to significantly improve the cycle life and energy density.
ADVANCED ENERGY MATERIALS
(2023)
Article
Multidisciplinary Sciences
Zhoudong Yang, Boya Wang, Yongjin Chen, Wanhai Zhou, Hongpeng Li, Ruizheng Zhao, Xinran Li, Tengsheng Zhang, Fanxing Bu, Zaiwang Zhao, Wei Li, Dongliang Chao, Dongyuan Zhao
Summary: This study investigates the reversible nature of the sulfur oxidation reaction (SOR) in sulfur-based aqueous batteries (SABs) by activating the elaborate mesocrystal NiS2 (M-NiS2). By utilizing a unique 6e(-) solid-to-solid conversion mechanism, an unprecedented SOR efficiency of ca. 96.0% is achieved. The research reveals the importance of the kinetics and thermodynamics in determining the SOR efficiency, and provides insights for the development of high-energy aqueous batteries.
NATIONAL SCIENCE REVIEW
(2023)
Article
Chemistry, Multidisciplinary
Tao Zhao, Xin Wang, Zhihao Sun, Haifeng Wang, Pengpeng Qiu, Qi Xiao, Wan Jiang, Lianjun Wang, Fanxing Bu, Wei Luo
Summary: A kinetically mediated micelle assembly strategy is presented to synthesize hollow UiO-66(Ce) single crystals with large radial mesopores and high surface area, which exhibit excellent photocatalytic performance for H-2 generation.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Ruizheng Zhao, Xusheng Dong, Pei Liang, Hongpeng Li, Tengsheng Zhang, Wanhai Zhou, Boya Wang, Zhoudong Yang, Xia Wang, Lipeng Wang, Zhihao Sun, Fanxing Bu, Zaiwang Zhao, Wei Li, Dongyuan Zhao, Dongliang Chao
Summary: The poor thermodynamic stability and sluggish electrochemical kinetics of metallic Zn anode in aqueous solution restrict its practical application. To overcome these problems, zincophilic surface modification strategies have been developed. However, there is still a lack of understanding regarding the selection of zincophilic sites based on the metrics of thermodynamics inertia and kinetics zincophilia. In this study, hetero-metallic interfaces are optimized to prioritize the Bi@Zn interface, which exhibits high efficiency due to its thermodynamics inertia and kinetics zincophilia. A practical metric for prioritizing zincophilic sites is proposed, and the Bi@Zn anode shows excellent performance in terms of low overpotential and stable cycle life.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Qiu He, Zhaohuai Li, Mingwei Wu, Ming Xie, Fanxing Bu, Huazhang Zhang, Ruohan Yu, Liqiang Mai, Yan Zhao
Summary: Uniform porous ionic dividers with functionalized surfaces can solve Li-dendrite issues in Li-metal batteries. In this study, single metal and nitrogen co-doped carbon-sandwiched MXene nanosheets were fabricated, which eliminated Li dendrites through redistributing the Li-ion flux, conducting Li ions, and obstructing the growth path of Li dendrites. With a Zn-NC@MXene-coated PP divider, the Li||Li symmetric battery showed ultralow overpotential and long cycle life. The well-designed multifunctional ion divider also showed potential for applications in Li||LiFePO4 and Li||sulfur batteries.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Multidisciplinary
Kun Lan, Lu Liu, Jiayu Yu, Yuzhu Ma, Jun-Ye Zhang, Zirui Lv, Sixing Yin, Qiulong Wei, Dongyuan Zhao
Summary: This study presents an ingenious stepwise monomicelle assembly route for the syntheses of highly ordered mesoporous crystalline TiO2 membranes with controlled mesophase, mesoporosity, and thickness. The process involves the preparation of monomicelle hydrogels and follows self-assembly by stepwise solvent evaporation, enabling the sensitive hydrolysis of TiO2 oligomers and dilatory micelle assembly. The fabricated mesoporous TiO2 membranes exhibit tunable ordered mesophases, controlled mesopore sizes, and anatase grain sizes, and can be extended to diverse substrates with tailored thickness.
Article
Chemistry, Applied
Qingmeng Xu, Fanxing Bu, Chen Sun, Xiao Huang, Hongjie Luo
Summary: Cellulose nanocrystals (CNCs)/DMSO organogels were carefully investigated in this study, and it was found that metal ions played a vital role in organogel formation, similar to hydrogels. The coordination between cations and DMSO alleviated the influence of cation valence on gel mechanical strength. Both CNCs/DMSO and CNCs/H2O gels exhibited instant thixotropic behavior, making them potentially useful for drug delivery applications.
CARBOHYDRATE POLYMERS
(2023)
Article
Chemistry, Multidisciplinary
Jingyu Zhang, Zhongliang Li, Jialong Li, Yalin He, Haojie Tong, Shuang Li, Zhanli Chai, Kun Lan
Summary: In this study, high-crystalline g-C3N4 samples, including K-CCN, Li/K-CCN, and Li/Na/K-CCN, were prepared via the molten salt strategy using pre-prepared BCN as a precursor. The Li/Na/K-CCN sample exhibited the highest photocatalytic hydrogen evolution rates and the highest apparent quantum yield compared to other CCN samples. The improved photocatalytic performance of Li/Na/K-CCN is attributed to the construction of type-II heterojunction and the institution of the built-in electric field between triazine-based CCN and heptazine-based BCN.