Article
Chemistry, Physical
Lisha Wu, Yanfeng Dong
Summary: This article discusses the main challenges of aqueous zinc ion batteries (ZIBs) and introduces the latest advances of carbon nanomaterials in addressing these challenges, highlighting the key role of carbon nanomaterials in enhancing zinc storage performance and new-concept batteries.
ENERGY STORAGE MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Yingxiao Du, Yang Feng, Ruotong Li, Zhi Peng, Xinyue Yao, Siying Duan, Shude Liu, Seong Chan Jun, Jing Zhu, Lei Dai, Qi Yang, Ling Wang, Zhangxing He
Summary: This study synthesizes a Zn@Bi alloy anode and explores its effect on mitigating dendrite formation in aqueous zinc ion batteries. The addition of bismuth inhibits hydrogen evolution reaction and corrosion of zinc anodes. The use of Zn@Bi anodes leads to uniform zinc deposition and extended cycling performance in AZIBs.
Review
Chemistry, Multidisciplinary
Manqi Peng, Kyungsoo Shin, Lixia Jiang, Ye Jin, Ke Zeng, Xiaolong Zhou, Yongbing Tang
Summary: Alloy-type anodes have high theoretical capacity but face challenges such as volume expansion and fragility. This review summarizes recent progress in the research of batteries based on alloy-type anodes and highlights improvements in structural design, protective interface, and electrolyte selection as effective means to enhance their performance.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Review
Chemistry, Multidisciplinary
Jiasheng Yue, Shi Chen, Jingjing Yang, Shuqiang Li, Guoqiang Tan, Ran Zhao, Chuan Wu, Ying Bai
Summary: This review provides an overview of the development of multi-ion engineering in aqueous zinc-based batteries, summarizing different battery configurations and their corresponding reaction mechanisms. The nomenclature of different configurations is proposed based on the reaction mechanisms of additional ions, setting the foundation for future discussions and development. The performance enhancement, challenges, and future directions of multi-ion strategies are also discussed.
ADVANCED MATERIALS
(2023)
Article
Chemistry, Physical
Yue Li, Xiaosha Cui, Jianfeng Yan, Yaxiong Zhang, Erqing Xie, Jiecai Fu
Summary: To address the poor performance of the cathode in zinc ion batteries, researchers propose an electric field balancing strategy by constructing a ferroelectric interface on the cathode surface to regulate the behavior of electrolyte ions. The MnO2@β-PVDF cathode with an appropriate thickness coating of ferroelectric materials exhibits the highest capacity of 277.6 mAh g-1 (at 0.1 A g-1) and a capacity retention of 68.6% after 120 cycles, surpassing both the pristine MnO2 and non-ferroelectric materials coated MnO2 electrodes.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Lu Yang, Tengsheng Zhang, Sainan Liu, Ziqing Wang, Zhexuan Liu, Xinxin Cao, Guozhao Fang, Shuquan Liang
Summary: This study proposes an ionic self-concentrated electrolyte (ISCE) that enables uniform Zn deposition and reversible reaction of MnO2 cathode. The Zn/Zn symmetrical batteries exhibit long-life cycle stability, while the Zn/MnO2 battery demonstrates high capacity and stability over many cycles.
Review
Multidisciplinary Sciences
Panlong Li, Zhong Fang, Xiaoli Dong, Congxiao Wang, Yongyao Xia
Summary: This review provides an overview of the state-of-the-art Li-metal anodes, focusing on two typical failure modes: capacity degradation and dendritic growth of Li metal. The critical correlations between composition, structure, and failure are explained, and the chemical and electrochemical stabilities of the lithium anode are discussed. The review also suggests strategies to improve the practical performance of LMBs.
NATIONAL SCIENCE REVIEW
(2022)
Article
Chemistry, Physical
Qiuju Xu, Wencai Zhou, Tuo Xin, Zilong Zheng, Xiangcheng Yuan, Jinzhang Liu
Summary: By preparing a Ti-MOF derived nanocomposite coating, researchers have successfully improved the anode performance of aqueous Zn-based batteries, including corrosion resistance, cycle life, and the reduction of dendrite growth and hydrogen gas evolution. When combined with a MnO2 cathode, this anode exhibits higher and more stable capacity.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Review
Chemistry, Applied
Ang Li, Jiayi Li, Yurong He, Maochun Wu
Summary: Zinc (Zn) metal has great potential as an anode material for rechargeable aqueous batteries due to its low cost, high abundance, low electrochemical potential, and large specific capacity. However, the poor reversibility caused by dendrite formation and side reactions has hindered its practical application. This review provides a systematic summary and discussion on electrolyte strategies for high-performance aqueous Zn batteries. Various electrolyte modulation strategies are classified and elaborated, and the remaining challenges and promising future research directions are highlighted.
JOURNAL OF ENERGY CHEMISTRY
(2023)
Article
Chemistry, Multidisciplinary
Mingqiang Liu, Lu Yao, Yuchen Ji, Mingzheng Zhang, Yulu Cai, Hongyang Li, Wenguang Zhao, Yan Zhao, Zexin Zou, Runzhi Qin, Yuetao Wang, Lele Liu, Hao Liu, Thomas S. Miller, Feng Pan, Jinlong Yang, Yihang Gan, Kai Yang
Summary: A new method of achieving ultrafine Zn nanograin anodes in aqueous Zn batteries (AZBs) has been reported, using ethylene glycol monomethyl ether (EGME) molecules to manipulate zinc nucleation and growth processes. The addition of EGME increased the driving force for nucleation and prevented H corrosion and dendritic protuberances by refining the grains. The nanoscale anode demonstrated high Coulombic efficiency, long-term cycle life, and compatibility with state-of-the-art cathodes, suggesting significant implications for the commercial future of AZBs.
Review
Chemistry, Multidisciplinary
Ying Liu, Yi Liu, Xiang Wu
Summary: This review focuses on the research progress of aqueous zinc-ion batteries (AZIBs), which are considered as a low-cost and safe alternative to Li-ion batteries. The challenges and solutions regarding the cathode, anode, and electrolyte are discussed, with emphasis on the adverse reactions of the zinc metal anode. Surface modification, internal structure optimization, and electrolyte regulation are identified as potential strategies to improve the electrochemical performance of AZIBs.
Article
Chemistry, Multidisciplinary
Longtao Ma, Qing Li, Yiran Ying, Feixiang Ma, Shengmei Chen, Yangyang Li, Haitao Huang, Chunyi Zhi
Summary: By using a ZnF2 solid ion conductor to isolate Zn metal, the hydrogen evolution in Zn metal batteries has been significantly reduced, leading to improved performance and stability of the batteries.
ADVANCED MATERIALS
(2021)
Review
Chemistry, Physical
Chuanhao Nie, Gulian Wang, Dongdong Wang, Mingyue Wang, Xinran Gao, Zhongchao Bai, Nana Wang, Jian Yang, Zheng Xing, Shixue Dou
Summary: Aqueous Zn-ion batteries have gained significant attention as a promising energy storage candidate due to their safety, cost-effectiveness, and eco-friendliness. However, the cycling stability of Zn metal anodes is a major challenge due to issues such as dendrite growth and hydrogen evolution. Interface engineering strategies, including controllable synthesis of Zn, surface engineering, electrolyte formulation, and separator design, have been developed to address these challenges. This review provides an update on these strategies and discusses future challenges and perspectives for the development of practical AZIBs.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
Mengxun Chen, Weiyi Cao, Lichang Wang, Xin Ma, Kai Han
Summary: The utilization of a chessboard-like Si/graphite anode with a homogeneous distribution of Si on the surface of graphite provides high specific capacity and excellent cycling performance for lithium-ion batteries, achieved through low-cost raw materials and industrial production methods.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Chemistry, Physical
Chuheng Cao, Keqin Zhou, Wencheng Du, Cheng Chao Li, Minghui Ye, Yufei Zhang, Yongchao Tang, Xiaoqing Liu
Summary: In this study, a soft solid-like viscoelastic Zn powder composite (ss-ZnP) anode based on a rheological oligomer (E-44) gluing strategy is proposed. The ss-ZnP anode exhibits enhanced ion/electron transport and alleviated volume effect, leading to excellent electrochemical performance in Zn-ion batteries. Furthermore, the excellent malleability of ss-ZnP greatly facilitates the assembly of various types of batteries.
ADVANCED ENERGY MATERIALS
(2023)
Article
Chemistry, Physical
M. Fayette, A. Nelson, R. D. Robinson
JOURNAL OF MATERIALS CHEMISTRY A
(2015)
Article
Electrochemistry
M. Fayette, U. Bertocci, G. R. Stafford
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2016)
Article
Nanoscience & Nanotechnology
Daniel A. McCurry, Martha Kamundi, Matthew Fayette, Fred Wafula, Nikolay Dimitrov
ACS APPLIED MATERIALS & INTERFACES
(2011)
Article
Electrochemistry
C. Mitchell, M. Fayette, N. Dimitrov
ELECTROCHIMICA ACTA
(2012)
Article
Electrochemistry
J. Nutariya, M. Fayette, N. Dimitrov, N. Vasiljevic
ELECTROCHIMICA ACTA
(2013)
Article
Chemistry, Physical
M. Kamundi, L. Bromberg, E. Fey, C. Mitchell, M. Fayette, N. Dimitrov
JOURNAL OF PHYSICAL CHEMISTRY C
(2012)
Article
Electrochemistry
Lori Ana Bromberg, Jiaxin Xia, Matthew Fayette, Nikolay Dimitrov
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
(2014)
Article
Chemistry, Multidisciplinary
M. Fayette, Y. Liu, D. Bertrand, J. Nutariya, N. Vasiljevic, N. Dimitrov
Article
Chemistry, Physical
M. Fayette, J. Nutariya, N. Vasiljevic, N. Dimitrov
Article
Chemistry, Physical
L. Bromberg, M. Fayette, B. Martens, Z. P. Luo, Y. Wang, D. Xu, J. Zhang, J. Fang, N. Dimitrov
Article
Chemistry, Physical
M. Fayette, R. D. Robinson
JOURNAL OF MATERIALS CHEMISTRY A
(2014)
Article
Nanoscience & Nanotechnology
Matthew Fayette, Hee Jung Chang, Ismael A. Rodriguez-Perez, Xiaolin Li, David Reed
ACS APPLIED MATERIALS & INTERFACES
(2020)
Article
Chemistry, Physical
Ismael A. Rodriguez-Perez, Hee Jung Chang, Matthew Fayette, Bhuvaneswari M. Sivakumar, Daiwon Choi, Xiaolin Li, David Reed
Summary: Zinc-MnO2 based batteries have attracted attention for grid-level applications due to impressive theoretical performance, cost effectiveness, and intrinsic safety. This research elucidates the detailed redox processes at the cathode during battery operation and explores the impact of electrolyte additives, providing insight into the overall electrochemical reaction mechanisms during battery operation.
JOURNAL OF MATERIALS CHEMISTRY A
(2021)
Article
Chemistry, Physical
Hee Jung Chang, Ismael A. Rodriguez-Perez, Matthew Fayette, Nathan L. Canfield, Huilin Pan, Daiwon Choi, Xiaolin Li, David Reed
Summary: The study demonstrates that using sodium carboxymethyl cellulose (CMC) binder significantly improves the electrochemical performance of Zn/MnO2 aqueous batteries, offering desirable adhesion, wettability, and chemical stability.