In Situ Anchoring Anion-Rich and Multi-Cavity NiS2 Nanoparticles on NCNTs for Advanced Magnesium-Ion Batteries

Magnesium (Mg)-ion batteries with low cost and good safety characteristics has attracted a great deal of attention recently. However, the high polarity and the slow diffusion of Mg2+ in the cathode material limit the development of practical Mg cathode materials. In this paper, an anion-rich electrode material, NiS2, and its composite with Ni-based carbon nanotubes (NiS2/NCNTs) are explored as the cathode materials for Mg-ion batteries. These NiS2/NCNTs with excellent Mg2+ storage property is synthesized by a simple in situ growth of NiS2 nanoparticles on NCNTs. NiS2 with both a large regular cavity structure and abundant sulfur-sulfur (S-S) bonds with high electronegativity can provide a large number of active sites and unobstructed transport paths for the insertion-disinsertion of Mg2+. With the aid of 3D NCNTs skeleton as the transport channel of the electron, the NiS2/NCNTs exhibit a high capacity of 244.5 mAh g(-1) at 50 mA g(-1) and an outstanding rate performance (94.7 mAh g(-1) at 1000 mA g(-1)). It achieves capacitance retention of 58% after 2000 cycles at 200 mA g(-1). Through theoretical density functional theory (DFT) calculations and a series of systematic ex situ characterizations, the magnesiation/demagnesiation mechanisms of NiS2 and NiS2/NCNTs and are elucidated for fundamental understanding.

Automated summary

In this paper, NiS2 and its composite with Ni-based carbon nanotubes (NiS2/NCNTs) are explored as cathode materials for Mg-ion batteries. NiS2/NCNTs with excellent Mg2+ storage property is synthesized by growing NiS2 nanoparticles on NCNTs. NiS2 with a large regular cavity structure and abundant sulfur-sulfur (S-S) bonds can provide active sites and unobstructed transport paths for the insertion-disinsertion of Mg2+. NiS2/NCNTs exhibit high capacity and outstanding rate performance.