4.5 Article

Deformation Behavior and Microstructure Evolution of CoCrNi Medium-Entropy Alloy Shaped Charge Liners

Journal

METALS
Volume 12, Issue 5, Pages -

Publisher

MDPI
DOI: 10.3390/met12050811

Keywords

shaped charge liner; CoCrNi; ultrahigh strain rate; nanosized precipitation

Funding

  1. NSFC [11790292, 11972346, 11672316]
  2. NSFC Basic Science Center Program for Multiscale Problems in Non-linear Mechanics [11988102]
  3. Strategic Priority Research Program [XDB22040302, XDB22040303]
  4. Key Research Program of Frontier Sciences of the Chinese Academy of Sciences [QYZDJSSW-JSC011]
  5. State Key Laboratory of Explosion Science and Technology, Beijing Institute of Technology

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The microstructure evolution and dynamic deformation behavior of a CoCrNi medium entropy alloy under an ultrahigh explosive loading rate were investigated. Dynamic recrystallization occurred during the extreme strain rate and large plastic deformation. The content of Cr element at the grain boundaries increased significantly, promoting the formation of nanosized Cr-rich precipitates that acted as obstacles for grain boundary movement and crack initiation.
To investigate the microstructure evolution and dynamic deformation behavior of a CoCrNi medium entropy alloy under an ultrahigh explosive loading rate, CoCrNi-shaped charged liners were fabricated and fired into steel targets. Targets with residual jet fragments were recovered for detailed microstructural analysis using scanning electrical microscopy, X-ray diffraction, electron backscattered diffraction, and transmission electron microscopy. The results indicate that the grain size was reduced by more than 3 times and grains were found to be equiaxed in the residual jet, which indicates that dynamic recrystallization (DRX) occurred during this extremely high strain rate and large plastic deformation. Furthermore, the content of Cr element in CoCrNi at the grain boundaries increased significantly after detonation deformation. The reduced grain sizes are believed to reduce the bulk diffusion path of Cr from grain interior into grain boundaries with the support of sufficient energy provided by the ultrahigh temperature. The enrichment of Cr at grain boundaries promotes the formation of nanosized Cr-rich precipitates with body-centered cubic (BCC) structures, which were found to be widely distributed along grain boundaries in the residual jet. These precipitates were considered obstacles for grain boundary movement and promotion of crack initiation along the grain boundaries, which might cause ductility loss of the CoCrNi-shaped charge jet and loss of penetration capability.

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