High-valent copper in biomimetic and biological oxidations

Simplest Monodentate Imidazole Stabilization of the oxy-Tyrosinase Cu2 O2 Core: Phenolate Hydroxylation through a CuIII Intermediate

(2016) Linus Chiang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tyrosinase versus Catechol Oxidase: One Asparagine Makes the Difference

(2016) Even Solem et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2 O2 Core with Unexpected Structure and Reactivity

(2016) Isaac Garcia-Bosch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heterogeneous formulation of the tricopper complex for efficient catalytic conversion of methane into methanol at ambient temperature and pressure

(2016) Chih-Cheng Liu et al.   Energy & Environmental Science

Synthesis and Catalytic Reactivity of a Dicopper(II) μ-η2:η2-Peroxo Species Supported by 1,4,7-Tri-tert-butyl-1,4,7-triazacyclononane

(2016) Gregory J. Karahalis et al.   INORGANIC CHEMISTRY

Direct Copper(III) Formation from O2 and Copper(I) with Histamine Ligation

(2016) J. Brannon Gary et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Low Temperature Syntheses and Reactivity of Cu2O2 Active-Site Models

(2015) Cooper Citek et al.   ACCOUNTS OF CHEMICAL RESEARCH

Developing Mononuclear Copper–Active-Oxygen Complexes Relevant to Reactive Intermediates of Biological Oxidation Reactions

(2015) Shinobu Itoh   ACCOUNTS OF CHEMICAL RESEARCH

A TEMPO-Free Copper-Catalyzed Aerobic Oxidation of Alcohols

(2015) Boran Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electron transfer and reaction mechanism of laccases

(2015) Stephen M. Jones et al.   CELLULAR AND MOLECULAR LIFE SCIENCES

Formation of Hybrid Guanidine-Stabilized Bis(μ-oxo)dicopper Cores in Solution: Electronic and Steric Perturbations

(2015) Sonja Herres-Pawlis et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A room temperature catalyst for toluene aliphatic C–H bond oxidation: Tripodal tridentate copper complex immobilized in mesoporous silica

(2015) Chih-Cheng Liu et al.   JOURNAL OF CATALYSIS

Hydrogen Atom Abstraction from Hydrocarbons by a Copper(III)-Hydroxide Complex

(2015) Debanjan Dhar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chemical Plausibility of Cu(III) with Biological Ligation in pMMO

(2015) Cooper Citek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Biomimetic Catalytic Aerobic Functionalization of Phenols

(2014) Kenneth Virgel N. Esguerra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SelectiveOrtho-Hydroxylation-Defluorination of 2-Fluorophenolates with a Bis(μ-oxo)dicopper(III) Species

(2014) Joan Serrano-Plana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Observation of a CuII2(μ-1,2-peroxo)/CuIII2(μ-oxo)2Equilibrium and its Implications for Copper-Dioxygen Reactivity

(2014) Matthew T. Kieber-Emmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper Active Sites in Biology

(2014) Edward I. Solomon et al.   CHEMICAL REVIEWS

BOX Ligands in Biomimetic Copper-Mediated Dioxygen Activation: A Hemocyanin Model

(2014) Adam Walli et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Primary Amine Stabilization of a Dicopper(III) Bis(μ-oxo) Species: Modeling the Ligation in pMMO

(2014) Cooper Citek et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Weakly Coupled Biologically Relevant CuII2(μ-η1:η1-O2) cis-Peroxo Adduct that Binds Side-On to Additional Metal Ions

(2014) Kristian E. Dalle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Oxidation of Methane to Methanol by Dioxygen Mediated by Tricopper Clusters

(2013) Sunney I. Chan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Phenol Hydroxylation with Dioxygen: Extension of the Tyrosinase Mechanism beyond the Protein Matrix

(2013) Alexander Hoffmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

1,4,7-Triazacyclononane Ligands Bearing Tertiary Alkyl Nitrogen Substituents

(2013) Arumugam Thangavel et al.   INORGANIC CHEMISTRY

On the Dielectric “Constant” of Proteins: Smooth Dielectric Function for Macromolecular Modeling and Its Implementation in DelPhi

(2013) Lin Li et al.   Journal of Chemical Theory and Computation

An O-Centered Structure of the Trinuclear Copper Center in the Cys500Ser/Glu506Gln Mutant of CueO and Structural Changes in Low to High X-Ray Dose Conditions

(2012) Hirofumi Komori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydroxylation of p-substituted phenols by tyrosinase: Further insight into the mechanism of tyrosinase activity

(2012) Jose Luis Muñoz-Muñoz et al.   BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS

Cu(I)/O2 Chemistry Using a β-Diketiminate Supporting Ligand Derived from N,N-Dimethylhydrazine: A [Cu3O2]3+ Complex with Novel Reactivity

(2012) Aalo K. Gupta et al.   INORGANIC CHEMISTRY

Modeling Tyrosinase and Catecholase Activity Using New m-Xylyl-Based Ligands with Bidentate Alkylamine Terminal Coordination

(2012) Sukanta Mandal et al.   INORGANIC CHEMISTRY

Self-assembly of the oxy-tyrosinase core and the fundamental components of phenolic hydroxylation

(2012) Cooper Citek et al.   Nature Chemistry

Copper(I)/TEMPO-catalyzed aerobic oxidation of primary alcohols to aldehydes with ambient air

(2012) Jessica M Hoover et al.   Nature Protocols

Synthetic model of the asymmetric [Mn3CaO4] cubane core of the oxygen-evolving complex of photosystem II

(2012) S. Mukherjee et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Metal-templated ligand architectures for trinuclear chemistry: tricopper complexes and their O2reactivity

(2012) Davide Lionetti et al.   Chemical Science

Copper–O2 reactivity of tyrosinase models towards external monophenolic substrates: molecular mechanism and comparison with the enzyme

(2011) Malte Rolff et al.   CHEMICAL SOCIETY REVIEWS

Rapid C–H Bond Activation by a Monocopper(III)–Hydroxide Complex

(2011) Patrick J. Donoghue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

O2 Activation and Selective Phenolate ortho Hydroxylation by an Unsymmetric Dicopper μ-η1:η1-Peroxido Complex

(2010) Isaac Garcia-Bosch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic oxygenation of phenols by arthropod hemocyanin, an oxygen carrier protein, from Portunus trituberculatus

(2010) Nobutaka Fujieda et al.   DALTON TRANSACTIONS

Four-electron Reduction of Dioxygen by a Multicopper Oxidase, CueO, and Roles of Asp112and Glu506Located Adjacent to the Trinuclear Copper Center

(2009) Kunishige Kataoka et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Reaction Coordinate of a Functional Model of Tyrosinase: Spectroscopic and Computational Characterization

(2009) Bryan T. Op’t Holt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phenolate Hydroxylation in a Bis(μ-oxo)dicopper(III) Complex: Lessons from the Guanidine/Amine Series

(2009) Sonja Herres-Pawlis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aliphatic C−H Bond Activation Initiated by a (μ-η2:η2-Peroxo)dicopper(II) Complex in Comparison with Cumylperoxyl Radical

(2009) Takahiro Matsumoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A [Cu2O]2+core in Cu-ZSM-5, the active site in the oxidation of methane to methanol

(2009) Julia S. Woertink et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Tyrosinase-Like Reactivity in a CuIII2(μ-O)2 Species

(2008) Anna Company et al.   CHEMISTRY-A EUROPEAN JOURNAL