4.6 Article

Is proton a charge carrier for d-MnO2 cathode in aqueous rechargeable magnesium-ion batteries?

Journal

JOURNAL OF ENERGY CHEMISTRY
Volume 68, Issue -, Pages 572-579

Publisher

ELSEVIER
DOI: 10.1016/j.jechem.2021.12.016

Keywords

Magnesium-ion batteries; Cathode; delta-MnO2 ; Mg ion insertion/extraction; Proton insertion/extraction

Funding

  1. National Natural Science Foundation of China [21975168]
  2. Sichuan Science and Technol-ogy Program [2021JDJQ0020]
  3. Fundamental Research Funds for the Central Universities [1082204112219]

Ask authors/readers for more resources

This study investigates the highly porous delta-MnO2 as a potential cathode material for aqueous magnesium-ion batteries. The results show that delta-MnO2 exhibits high capacity and excellent rate capability, but low-capacity retention. The two-step discharging process and the partial irreversibility of Mg2+ ion insertion/extraction are confirmed through detailed analysis of the electrochemical performance and element state.
Manganese dioxide (MnO2) is considered as a potential cathode material for aqueous magnesium-ion batteries. However, the charge/discharge mechanism of MnO2 in aqueous electrolyte is still unclear. In present study, highly porous delta-MnO2 is investigated, which delivers a high capacity of 252.1 mAh g(-1) at 0.05 A g(-1) and excellent rate capability, i.e., 109.7 mAh g(-1) at 1 A g(-1), but a low-capacity retention of 54.4% after 800 cycles at 1 A g(-1). The two-step discharging process, namely a consequent H+ and Mg2+ insertion reaction, is verified, by comparing the electrochemical performance of delta-MnO2 in 1 M MgCl2 and 1 M MnCl2 aqueous electrolyte and analyzing detailedly the Mg content and the bonding state of Mn at different charge/discharge state. Furthermore, partial irreversibility of Mg2+ ion insertion/extraction is observed, which may be one of the major reasons leading to capacity decay. (C)& nbsp;2021 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by ELSEVIER B.V. and Science Press. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Cell Biology

Integrated lipidomic and transcriptomic analysis reveals clarithromycin-induced alteration of glycerophospholipid metabolism in the cerebral cortex of mice

Xiaojie Wang, Liang Wang, Mingyi Luo, Qian Bu, Chunqi Liu, Linhong Jiang, Rui Xu, Shaomin Wang, Haoluo Zhang, Jiamei Zhang, Xuemei Wan, Hongchun Li, Yonghai Wang, Bin Liu, Ying Zhao, Yuanyuan Chen, Yanping Dai, Min Li, Hongbo Wang, Jingwei Tian, Yinglan Zhao, Xiaobo Cen

Summary: Clarithromycin (CLA) treatment causes anxiety-like behaviors, possibly through altered glycerophospholipid metabolism.

CELL BIOLOGY AND TOXICOLOGY (2023)

Article Neurosciences

Neonatal exposure to sevoflurane induces adolescent neurobehavioral dysfunction by interfering with hippocampal glycerophoslipid metabolism in rats

Yonghai Wang, Hongchun Li, Ying Zhao, Feng Qin, Liang Wang, Linhong Jiang, Xiaojie Wang, Rong Chen, Yuman He, Qinfan Wei, Shu Li, Yuanyuan Chen, Yuzhou Xiao, Yanping Dai, Qian Bu, Yinglan Zhao, Jingwei Tian, Hongbo Wang, Xiaobo Cen

Summary: Sevoflurane exposure in the neonatal period causes cognitive impairment and social behavior deficits in adolescent rats. Lipidomics and proteomics analysis revealed the remodeling of lipid metabolism and downregulation of LPCAT1 expression in the hippocampus, suggesting their involvement in neurobehavioral dysfunction.

CEREBRAL CORTEX (2023)

Article Chemistry, Multidisciplinary

Integrative phosphatidylcholine metabolism through phospholipase A2 in rats with chronic kidney disease

Yan-ni Wang, Zhi-hao Zhang, Hong-jiao Liu, Zhi-yuan Guo, Liang Zou, Ya-mei Zhang, Ying-yong Zhao

Summary: Dysregulation in lipid metabolism is closely related to the pathogenesis of chronic kidney disease (CKD). This study identified differential plasma lipid species in CKD rats and revealed that dysregulation of PC metabolism was involved in CKD pathology. Moreover, administration of Rheum officinale improved kidney function and aberrant PC metabolism in CKD rats.

ACTA PHARMACOLOGICA SINICA (2023)

Article Cell Biology

Blocking circadian clock factor Rev-erbα inhibits growth plate chondrogenesis via up-rtgulatin MAPK-ERK1/2 pathway

Zhuang Qian, Zhen Liu, Zhenhua Feng, Zhenning Cai, Yong Qiu, Zezhang Zhu

Summary: Emerging evidence suggests that the circadian clock gene Rev-erb alpha plays a role in cartilage metabolism, but its contribution to growth plate chondrogenesis remains unclear. In this study, it was found that inhibiting Rev-erb alpha suppressed longitudinal bone elongation and disrupted growth plate development. Mechanistically, knock-down of Rev-erb alpha up-regulated the MAPK-ERK1/2 pathway in chondrocytes. However, inhibition of this pathway partially alleviated the effects of Rev-erb alpha inhibition on bone elongation and growth plate development. These findings provide evidence for the important role of Rev-erb alpha in growth plate chondrogenesis.

CELL CYCLE (2023)

Article Engineering, Chemical

E-waste derived CuAu bimetallic catalysts supported on carbon cloth enabling effective degradation of bisphenol A via an electro-Fenton process

Mengxiang Ye, Chao Zhang, Zhenzhen Liu, Huaimeng Li, Zhen Fu, Haimin Zhang, Guozhong Wang, Yunxia Zhang

Summary: The conversion of e-waste into high-performance catalysts offers an economical solution for the degradation of bisphenol A (BPA). In this study, CuAu bimetallic catalysts were electro-codeposited on carbon cloth (CC) with waste central processing unit (CPU) leachate as the electrolyte. The resulting CuAu/CC composites were efficient electro-catalysts for the decontamination of BPA via the electro-Fenton process. The optimized CuAu/CC electrodes achieved 99.5% BPA removal and 64.2% total organic carbon (TOC) removal within 120 minutes.

SEPARATION AND PURIFICATION TECHNOLOGY (2023)

Article Oncology

Identification of nine mutant genes and establishment of three prediction models of organ tropism metastases of non-small cell lung cancer

Shuchen Chen, Wanyi Huang, Zhenzhen Liu, Meizi Jin, Jielin Li, Lihui Meng, Ting Li, Yuzhu Diao, Hong Gao, Chengyu Hong, Jian Zheng, Fei Li, Yue Zhang, Dan Bi, Lin Teng, Xiaoling Li

Summary: This study identifies nine mutant genes and smoking history associated with organ tropism metastases of NSCLC and provides three models for predicting metastatic organs.

CANCER MEDICINE (2023)

Article Environmental Sciences

Study on the enantioselective bioaccumulation and dissipation of uniconazole enantiomers in earthworm-soil microcosm through supercritical fluid chromatography-tandem mass spectrometry (SFC-MS/MS)

Chunhong Teng, Ying Li, Tao Cang, Hao Xu, Zhenzhen Liu, Peipei Qi, Zhiwei Wang, Huiyu Zhao, Shanshan Di, Xinquan Wang

Summary: This study investigated the enantioselective bioaccumulation and dissipation of uniconazole enantiomers in an earthworm-soil microcosm. A fast enantioseparation method was established using supercritical fluid chromatography-tandem mass spectrometry. The results showed that the bioaccumulation of uniconazole enantiomers in earthworms increased with time and reached a maximum on the 7th day, while the dissipation in soil was slow. No enantioselectivity was observed in the earthworm-soil microcosm.

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH (2023)

Review Immunology

Advances in experimental models of rheumatoid arthritis

Siwei Wang, Yanhua Zhou, Jiangrong Huang, Huilin Li, Huidan Pang, Dandan Niu, Guangyao Li, Fei Wang, Zushan Zhou, Zhenzhen Liu

Summary: This review provides an overview of the establishment, pathological features, potential mechanisms, advantages, and limitations of currently available rheumatoid arthritis (RA) models. It highlights the importance of translating laboratory research into clinical practice.

EUROPEAN JOURNAL OF IMMUNOLOGY (2023)

Article Chemistry, Applied

Rapid and sensitive analytical strategy for multi-class antibiotic residues analysis in aquatic products with amphiphilic magnetic polymer particles as an effective cleanup adsorbent

Zhenzhen Liu, Huiyu Zhao, Jiao Wang, Zhiwei Wang, Shanshan Di, Hao Xu, Qiang Wang, Xinhong Wang, Xinquan Wang, Peipei Qi

Summary: A sample pretreatment method based on magnetic dispersive solid-phase extraction was developed for the analysis of multi-class antibiotics in aquatic products. By optimizing the extraction and purification procedure, the simultaneous extraction of multiple antibiotics was achieved using acetonitrile-2% acetic acid. The use of amphiphilic magnetic particles and C18 as adsorbents effectively removed matrix interferences, resulting in significantly reduced matrix effects of analytes. The method showed satisfactory linearity, recovery, precision, and sensitivity under the optimized conditions, with limits of quantification ranging from 0.25 to 0.5 µg/kg. Additionally, the method demonstrated advantages in terms of operation convenience and efficiency due to the use of magnetic particles. It was successfully applied to analyze antibiotic residues in freshwater and seafood products, highlighting its suitability for antibiotic residues analysis in aquatic products.

FOOD CHEMISTRY (2023)

Article Environmental Sciences

An Efficient and Robust Hybrid SfM Method for Large-Scale Scenes

Zhendong Liu, Wenhu Qv, Haolin Cai, Hongliang Guan, Shuaizhe Zhang

Summary: In this paper, an efficient and robust hybrid SfM method is proposed to address the challenges of loose spatial distribution of images within subclusters and unbalanced connectivity between subclusters. The method employs a multifactor joint scene partition measure and a preassignment balanced image expansion algorithm to improve the degree of connection among subclusters. Experimental results demonstrate that the proposed method outperforms state-of-the-art methods in terms of accuracy and robustness.

REMOTE SENSING (2023)

Article Green & Sustainable Science & Technology

The Impact and Internal Mechanism of Environmental Decentralization on Green Total Factor Production

Bin Luo, Zhenhai Liu, Sichao Mai

Summary: Since the 1960s, scholars have conducted empirical research on environmental federalism theory, mainly focusing on whether a country's environmental regulation should be centralized or decentralized. Countries have been actively exploring and implementing their own environmental governance systems, especially in the face of resource constraints, environmental challenges, and the need for sustainable development. Encouraging enterprises' technological innovation to build an appropriate environmental governance system and promote green development is an urgent practical problem to be solved.

SUSTAINABILITY (2023)

Article Agronomy

Biodegradable film mulching promotes better soil quality and increases summer maize grain yield in North China Plain

Ming Li, Qingfen Zhang, Shiyu Wei, Zhendong Liu, Rui Zong, Tuo Jin, Mingming Zhang, Chitao Sun, Quanqi Li

Summary: The cumulative effects of biodegradable film mulch on soil quality were investigated in the study. It was found that both black and transparent biodegradable film mulching reduced soil bulk density, increased soil microbial and enzyme activity, but did not significantly affect soil nutrient content. Black biodegradable film mulching showed the highest increase in soil quality index and significantly improved summer maize grain yield.

ARCHIVES OF AGRONOMY AND SOIL SCIENCE (2023)

Review Infectious Diseases

Isolated cryptococcal osteomyelitis of the sacrum in an immunocompetent patient: a case report and literature review

Yanchun Zhong, Yuxi Huang, Di Zhang, Zhaoyuan Chen, Zhenxing Liu, Yongjun Ye

Summary: This article reports a rare case of isolated sacral cryptococcal osteomyelitis in an immunocompetent patient. Furthermore, it identified and reviewed 18 published cases of spine cryptococcal osteomyelitis. Clinical manifestation and imaging are insufficient to diagnose cryptococcal osteomyelitis of the spine, and invasive examinations, such as puncture biopsy and fungal examinations, are needed. Antifungal therapy yields satisfactory results for the treatment of cryptococcal osteomyelitis of the spine, however, if the infective lesion is large, especially when it compresses the spinal cord and nerves, a regimen combining aggressive surgery with antifungal therapy is indispensable.

BMC INFECTIOUS DISEASES (2023)

Article Chemistry, Physical

Highly electrochemically stable Li2B12H12-Al2O3 nanocomposite electrolyte enabling A 3.8 V room-temperature all-solid-state Li-ion battery

Chongyang Zhou, Han Sun, Qian Wang, Jakob B. Grinderslev, Dan Liu, Yigang Yan, Torben R. Jensen

Summary: Designing solid electrolytes compatible with high-voltage cathodes for all-solid-state lithium batteries is challenging. In this study, a nanocomposite Li2B12H12-Al2O3 was treated for 120 hours, resulting in an electrochemical stability window up to approximately 3.8 V and a high lithium ionic conductivity of Sigma(Li+) = 2.73 x 10-5 S cm-1 at 30 degrees C due to the interfacial interaction via B-O bonds. The electrolyte also exhibited compatibility with the lithium metal anode, demonstrating stable Li plating/stripping for 300 cycles.

JOURNAL OF ALLOYS AND COMPOUNDS (2023)

Article Biochemistry & Molecular Biology

Oxidative stress and inflammation are mediated via aryl hydrocarbon receptor signalling in idiopathic membranous nephropathy

Yan-Ni Wang, Hua Miao, Xiao-Yong Yu, Yan Guo, Wei Su, Fei Liu, Gang Cao, Ying-Yong Zhao

Summary: Patients with membranous nephropathy (MN) are diagnosed by the presence of phospholipase A2 receptor (PLA2R) before they progress to renal failure. The aryl hydrocarbon receptor (AHR), NF-kB, and Nrf2 pathways are involved in the pathogenesis and progression of chronic kidney disease. This study investigated the effect of AHR signalling on the NF-kB and Nrf2 pathways in MN patients, rats, and podocytes.

FREE RADICAL BIOLOGY AND MEDICINE (2023)

Article Chemistry, Applied

In-situ coating and surface partial protonation co-promoting performance of single-crystal nickel-rich cathode in all-solid-state batteries

Maoyi Yi, Jie Li, Mengran Wang, Xinming Fan, Bo Hong, Zhian Zhang, Aonan Wang, Yanqing Lai

Summary: In this study, polyacrylic acid (PAA) was used as a binder for the cathode in all-solid-state batteries. Through H+/Li+ exchange reaction, a uniform PAA-Li coating layer was formed on the cathode surface, improving the stability of the cathodic interface and the crystal structure. The SC-NCM83-PAA cathode exhibited superior cycling performance compared to traditional PVDF binder.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Arbitrary skin metallization by pencil-writing inspired solid-ink rubbing for advanced energy storage and harvesting

Yonghan Zhou, Zhongfeng Ji, Wenrui Cai, Xuewei He, Ruiying Bao, Xuewei Fu, Wei Yang, Yu Wang

Summary: By learning from the pencil-writing process, a solid-ink rubbing technology (SIR-tech) has been invented to develop durable metallic coatings on diverse substrates. The composite metallic skin by SIR-tech outperforms pure liquid-metal coating and shows great potential for various applications.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Coupling Sb2WO6 microflowers and conductive polypyrrole for efficient potassium storage by enhanced conductivity and K plus diffusivity

Ruiqi Tian, Hehe Zhang, Zeyu Yuan, Yuehua Man, Jianlu Sun, Jianchun Bao, Ming-Sheng Wang, Xiaosi Zhou

Summary: In this study, polypyrrole-encapsulated Sb2WO6 microflowers were synthesized and demonstrated to exhibit excellent potassium storage properties and cycling stability. The improved performance of Sb2WO6@PPy was attributed to the unique microflower structure, enhanced electronic conductivity, and protective PPy coating.

JOURNAL OF ENERGY CHEMISTRY (2024)

Review Chemistry, Applied

Physics-based battery SOC estimation methods: Recent advances and future perspectives

Longxing Wu, Zhiqiang Lyu, Zebo Huang, Chao Zhang, Changyin Wei

Summary: This paper presents a comprehensive survey on physics-based state of charge (SOC) algorithms applied in advanced battery management system (BMS). It discusses the research progresses of physical SOC estimation methods for lithium-ion batteries and presents future perspectives for this field.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

d-d Orbital coupling induced by crystal-phase engineering assists acetonitrile electroreduction to ethylamine

Honggang Huang, Yao Chen, Hui Fu, Cun Chen, Hanjun Li, Zhe Zhang, Feili Lai, Shuxing Bai, Nan Zhang, Tianxi Liu

Summary: The d-d orbital coupling induced by crystal-phase engineering effectively adjusts the electronic structure of electrocatalysts, improving their activity and stability, which is significant for electrocatalyst research.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

In-doping collaboratively controlling back interface and bulk defects to achieve efficient flexible CZTSSe solar cells

Quanzhen Sun, Yifan Li, Caixia Zhang, Shunli Du, Weihao Xie, Jionghua Wu, Qiao Zheng, Hui Deng, Shuying Cheng

Summary: In this study, indium (In) ions were introduced into flexible Cu2ZnSn(S,Se)(4) (CZTSSe) solar cells to modify the back interface and passivate deep level defects in CZTSSe bulk. The results showed that In doping effectively inhibited the formation of secondary phase and V-Sn defects, decreased the barrier height at the back interface, passivated deep level defects in CZTSSe bulk, increased carrier concentration, and significantly reduced the V-OC deficit. Eventually, a flexible CZTSSe solar cell with a power conversion efficiency of 10.01% was achieved. This synergistic strategy of interface modification and bulk defects passivation through In incorporation provides a new approach for fabricating efficient flexible kesterite-based solar cells.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Toward a comprehensive hypothesis of oxygen-evolution reaction in the presence of iron and gold

Negah Hashemi, Jafar Hussain Shah, Cejun Hu, Subhajit Nandy, Pavlo Aleshkevych, Sumbal Farid, Keun Hwa Chae, Wei Xie, Taifeng Liu, Junhu Wang, Mohammad Mahdi Najafpour

Summary: This study investigates the effects of Fe on the oxygen-evolution reaction (OER) in the presence of Au. The study identifies two distinct areas of OER associated with Fe and Au sites at different overpotentials. Various factors were varied to observe the behaviors of FeOxHy/Au during OER. The study reveals strong electronic interaction between Fe and Au, and proposes a lattice OER mechanism based on FeOxHy.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Exploring the impact of Nafion modifier on electrocatalytic CO2 reduction over Cu catalyst

Yingshi Su, Yonghui Cheng, Zhen Li, Yanjia Cui, Caili Yang, Ziyi Zhong, Yibing Song, Gongwei Wang, Lin Zhuang

Summary: This study systematically investigates the key roles of Nafion on Cu nanoparticles electrocatalyst for CO2RR. The Nafion modifier suppresses the hydrogen evolution reaction, increases CO2 concentration and mass transfer process, and activates CO2 molecule to enhance C2 product generation. As a result, the selectivity of the hydrogen evolution reaction is reduced and the efficiency of C2 products is significantly improved.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Electronic structure and spin state regulation of vanadium nitride via a sulfur doping strategy toward flexible zinc-air batteries

Daijie Deng, Honghui Zhang, Jianchun Wu, Xing Tang, Min Ling, Sihua Dong, Li Xu, Henan Li, Huaming Li

Summary: By doping sulfur into vanadium nitride, the S-VN/Co/NS-MC catalyst exhibits enhanced oxygen reduction reaction activity and catalytic performance. When applied in liquid and flexible ZABs, it shows higher power density, specific capacity, and cycling stability.

JOURNAL OF ENERGY CHEMISTRY (2024)

Review Chemistry, Applied

Self-assembly of perovskite nanocrystals: From driving forces to applications

Yi Li, Fei Zhang

Summary: Self-assembly of metal halide perovskite nanocrystals holds significant application value in the fields of display, detector, and solar cell due to their unique collective properties. This review covers the driving forces, commonly used methods, and different self-assembly structures of perovskite nanocrystals. Additionally, it summarizes the collective optoelectronic properties and application areas of perovskite superlattice structures, and presents an outlook on potential issues and future challenges in the development of perovskite nanocrystals.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Ag-integrated mixed metallic Co-Fe-Ni-Mn hydroxide composite as advanced electrode for high-performance hybrid supercapacitors

Anki Reddy Mule, Bhimanaboina Ramulu, Shaik Junied Arbaz, Anand Kurakula, Jae Su Yu

Summary: Direct growth of redox-active noble metals and rational design of multifunctional electrochemical active materials play crucial roles in developing novel electrode materials for energy storage devices. In this regard, silver (Ag) has attracted great attention in the design of efficient electrodes. The construction of multifaceted heterostructure cobalt-iron hydroxide (CFOH) nanowires (NWs)@nickel cobalt manganese hydroxides and/or hydrate (NCMOH) nanosheets (NSs) on the Ag-deposited nickel foam and carbon cloth (i.e., Ag/ NF and Ag/CC) substrates is reported. The as-fabricated Ag@CFOH@NCMOH/NF electrode delivered superior areal capacity value of 2081.9 μA h cm-2 at 5 mA cm-2. Moreover, as-assembled hybrid cell based on NF (HC/NF) device exhibited remarkable areal capacity value of 1.82 mA h cm-2 at 5 mA cm-2 with excellent rate capability of 74.77% even at 70 mA cm-2. Furthermore, HC/NF device achieved maximum energy and power densities of 1.39 mW h cm-2 and 42.35 mW cm-2, respectively. To verify practical applicability, both devices were also tested to serve as a self-charging station for various portable electronic devices.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Insights into ionic association boosting water oxidation activity and dynamic stability

Zanling Huang, Shuqi Zhu, Yuan Duan, Chaoran Pi, Xuming Zhang, Abebe Reda Woldu, Jing-Xin Jian, Paul K. Chu, Qing-Xiao Tong, Liangsheng Hu, Xiangdong Yao

Summary: In this study, it was found that Ni sites act as a host to attract Fe(III) to form Fe(Ni)(III) binary centers, which promote the oxygen evolution reaction (OER) activity and stability by cyclical formation of intermediates. Additionally, other ions can also catalyze the OER process on different electrodes.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Reversible Mn2+/Mn4+double-electron redox in P3-type layer-structured sodium-ion cathode

Jie Zeng, Jian Bao, Ya Zhang, Xun-Lu Li, Cui Ma, Rui-Jie Luo, Chong-Yu Du, Xuan Xu, Zhe Mei, Zhe Qian, Yong-Ning Zhou

Summary: The balance between cationic redox and oxygen redox is crucial for achieving high energy density and cycle stability in sodium batteries. This study demonstrates the reversible Mn2+/Mn4+ redox in a P3-Na0.65Li0.2Co0.05Mn0.75O2 cathode material through Co substitution, effectively suppressing the contribution of oxygen redox and improving structure stability.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

The initial stages of Li2O2 formation during oxygen reduction reaction in Li-O2 batteries: The significance of Li2O2 in charge-transfer reactions within devices

Daniela M. Josepetti, Bianca P. Sousa, Simone A. J. Rodrigues, Renato G. Freitas, Gustavo Doubek

Summary: Lithium-oxygen batteries have high energy density potential but face challenges in achieving high cyclability. This study used operando Raman experiments and electrochemical impedance spectroscopy to evaluate the initial discharge processes in porous carbon electrodes. The results indicate that the reaction occurs at the Li2O2 surface and the growth of Li2O2 forms a more compact and homogeneous structure.

JOURNAL OF ENERGY CHEMISTRY (2024)

Article Chemistry, Applied

Porous metal oxides in the role of electrochemical CO2 reduction reaction

Ziqi Zhang, Jinyun Xu, Yu Zhang, Liping Zhao, Ming Li, Guoqiang Zhong, Di Zhao, Minjing Li, Xudong Hu, Wenju Zhu, Chunming Zheng, Xiaohong Sun

Summary: This paper explores the challenge of increasing global CO2 emissions and highlights the role of porous metal oxide materials in electrocatalytic reduction of CO2 (CO2RR). Porous metal oxides offer high surface area and tunability for optimizing CO2RR reaction mechanisms.

JOURNAL OF ENERGY CHEMISTRY (2024)