4.8 Review

Energetic Aqueous Batteries

Journal

ADVANCED ENERGY MATERIALS
Volume 12, Issue 27, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202201074

Keywords

aqueous electrolytes; aqueous rechargeable batteries; high energy density; high specific capacity; high voltage

Funding

  1. National Natural Science Foundation of China [52071171, 22109060]
  2. Liaoning Revitalization Talents Program - Pan Deng Scholars [XLYC1802005]
  3. Liaoning BaiQianWan Talents Program [LNBQW2018B0048]
  4. Natural Science Fund of Liaoning Province for Excellent Young Scholars [2019-YQ-04]
  5. Key Project of Scientific Research of the Education Department of Liaoning Province [LZD201902]
  6. Shenyang Science and Technology Project [21-108-9-04]
  7. Research Fund for the Doctoral Program of Liaoning Province [2020-BS-085]
  8. 2021 Annual Scientific Research Funding Project of the Educational Department of Liaoning Province [LJKZ0101]
  9. Australian Research Council (ARC) [FT210100298, FT210100806, DP220100603, LP210100467, LP210200504, LP210200345, IC180100005]
  10. CSIRO Energy Centre
  11. Victorian Government through Study Melbourne
  12. Kick-Start Project
  13. Australian Research Council [LP210200345] Funding Source: Australian Research Council

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This review highlights the strategies proposed so far to pursue high energy density aqueous batteries, focusing on various aspects such as electrolytes, electrode chemistry, cathode materials, anode materials, and battery configurations. The emerging electrochemistry and the future development of high-energy aqueous batteries are also discussed.
Rechargeable aqueous batteries are considered to be one of the most effective energy storage technologies to balance the cost-efficiency, safety, and energy/power demands. The further progress of aqueous batteries with high energy density is needed to meet the ever-increasing energy-storage demands. This review highlights the strategies proposed so far to pursue the high energy density aqueous batteries, including the aspects of the electrolytes (from concentrated to dilute), the electrode chemistry (from inserted to converted), the cathode materials (from inorganic to organic), the anode materials (from compound to metallic), and the battery configurations (from integrated to decoupled). Critical appraisals of the emerging electrochemistry are presented for addressing the key issues in boosting the energy densities. Finally, the authors render insights into the future development of high-energy aqueous batteries.

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