Controlling Ni redox states by dynamic ligand exchange for electroreductive Csp3–Csp2 coupling

Modular terpene synthesis enabled by mild electrochemical couplings

(2022) Stephen J. Harwood et al.   SCIENCE

Synergistic Catalyst–Mediator Pairings for Electroreductive Cross-Electrophile Coupling Reactions

(2022) Jordan L. S. Zackasee et al.   ACS Catalysis

Quaternary stereocentres via catalytic enantioconvergent nucleophilic substitution reactions of tertiary alkyl halides

(2021) Zhaobin Wang et al.   Nature Chemistry

Redox Activity of Pyridine-Oxazoline Ligands in the Stabilization of Low-Valent Organonickel Radical Complexes

(2021) Clifton L. Wagner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Process Chemistry Benchmark for sp2–sp3 Cross Couplings

(2021) Gregory L. Beutner et al.   JOURNAL OF ORGANIC CHEMISTRY

Overcoming the Naphthyl Requirement in Stereospecific Cross-Couplings to Form Quaternary Stereocenters

(2021) Jianyu Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Monovalent Nickel-Mediated Radical Formation: A Concerted Halogen-Atom Dissociation Pathway Determined by Electroanalytical Studies

(2021) Qiao Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Application of Pulse Radiolysis to the Study of Ni(I) Intermediates in Ni-Catalyzed Cross-Coupling Reactions

(2021) Nicholas A. Till et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental Electrochemical Potentials of Nickel Complexes

(2021) Tianning Diao et al.   SYNLETT

Advances on the Merger of Electrochemistry and Transition Metal Catalysis for Organic Synthesis

(2021) Christian A. Malapit et al.   CHEMICAL REVIEWS

Photoredox Iridium–Nickel Dual Catalyzed Cross-Electrophile Coupling: From a Batch to a Continuous Stirred-Tank Reactor via an Automated Segmented Flow Reactor

(2021) Rohit Duvadie et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Carbonyl 1,2-transposition through triflate-mediated α-amination

(2021) Zhao Wu et al.   SCIENCE

General C(sp2)-C(sp3) Cross-Electrophile Coupling Reactions Enabled by Overcharge Protection of Homogeneous Electrocatalysts

(2020) Blaise L. Truesdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General Paradigm in Photoredox Nickel-Catalyzed Cross-Coupling Allows for Light-Free Access to Reactivity

(2020) Rui Sun et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

On the Nature of C(sp3)–C(sp2) Bond Formation in Nickel-Catalyzed Tertiary Radical Cross-Couplings: A Case Study of Ni/Photoredox Catalytic Cross-Coupling of Alkyl Radicals and Aryl Halides

(2020) Mingbin Yuan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Electrophile Coupling of Aryl Chlorides with Primary Alkyl Chlorides

(2020) Seoyoung Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development and Execution of an Ni(II)-Catalyzed Reductive Cross-Coupling of Substituted 2-Chloropyridine and Ethyl 3-Chloropropanoate

(2020) Sri Krishna Nimmagadda et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Upscaling Photoredox Cross-Coupling Reactions in Batch Using Immersion-Well Reactors

(2020) Isabelle Grimm et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Expanding the Medicinal Chemist Toolbox: Comparing Seven C(sp2)–C(sp3) Cross-Coupling Methods by Library Synthesis

(2020) Amanda W. Dombrowski et al.   ACS Medicinal Chemistry Letters

Palladium‐Catalyzed Chlorocarbonylation of Aryl (Pseudo)Halides Through In Situ Generation of Carbon Monoxide

(2020) Philip Boehm et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cross-Electrophile Coupling of Unactivated Alkyl Chlorides

(2020) Holt A. Sakai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Electrophile Couplings of Activated and Sterically Hindered Halides and Alcohol Derivatives

(2020) Jiandong Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ni(4-tBustb)3: A Robust 16-Electron Ni(0) Olefin Complex for Catalysis

(2020) Lukas Nattmann et al.   ORGANOMETALLICS

A Comparative Review of Metal‐Based Charge Carriers in Nonaqueous Flow Batteries

(2020) Travis C. Palmer et al.   ChemSusChem

Quaternary Centers via Ni-Catalyzed Cross-Coupling of Tertiary Carboxylic Acids and Aryl Zinc Reagents

(2019) Phil S. Baran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ru-Catalyzed Selective C-H Bond Hydroxylation of Cyclic Imides

(2019) Yu-Chao Yuan et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Characterization of (Xantphos)Ni(I)-Mediated Alkyl Bromide Activation: Oxidative Addition, Electron Transfer, or Halogen-Atom Abstraction

(2019) Justin B. Diccianni et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrochemically Driven, Ni-Catalyzed Aryl Amination: Scope, Mechanism, and Applications

(2019) Yu Kawamata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Reductant-Free Electrochemical Nickel-Catalyzed Couplings of Aryl and Alkyl Bromides in Acetonitrile

(2019) Robert J. Perkins et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

An Electrochemically Promoted, Nickel-Catalyzed Mizoroki–Heck Reaction

(2019) Benjamin R. Walker et al.   ACS Catalysis

A Practical Method for Continuous Production of sp3‐Rich Compounds from (Hetero)Aryl Halides and Redox‐Active Esters

(2019) Eiichi Watanabe et al.   CHEMISTRY-A EUROPEAN JOURNAL

Intermediacy of Ni–Ni Species in sp2 C–O Bond Cleavage of Aryl Esters: Relevance in Catalytic C–Si Bond Formation

(2018) Rosie J. Somerville et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactions of the Ni(0) Compound Ni(PPh3)4 with Unactivated Alkyl Halides: Oxidative Addition Reactions Involving Radical Processes and Nickel(I) Intermediates

(2018) Ryley Kehoe et al.   ORGANOMETALLICS

Synthesis of Functionalized 1,3-Butadienes via Pd-Catalyzed Cross-Couplings of Substituted Allenic Esters in Water at Room Temperature

(2018) Daniel J. Lippincott et al.   ORGANIC LETTERS

Ni-Catalyzed Reductive Coupling of Electron-Rich Aryl Iodides with Tertiary Alkyl Halides

(2018) Xuan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cross-Coupling of Chloro(hetero)arenes with Thiolates Employing a Ni(0)-Precatalyst

(2018) Paul H. Gehrtz et al.   ORGANIC LETTERS

Palladium-Catalyzed Late-Stage Direct Arene Cyanation

(2018) Da Zhao et al.   Chem

Enabling the Cross-Coupling of Tertiary Organoboron Nucleophiles through Radical-Mediated Alkyl Transfer

(2017) David N. Primer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Size-selective catalysts in five functionalized porous coordination polymers with unsaturated zinc centers

(2017) Dongsheng Deng et al.   NEW JOURNAL OF CHEMISTRY

Oxidative Addition of Aryl Electrophiles to a Prototypical Nickel(0) Complex: Mechanism and Structure/Reactivity Relationships

(2017) Sonia Bajo et al.   ORGANOMETALLICS

When Weaker Can Be Tougher: The Role of Oxidation State (I) in P- vs N-Ligand-Derived Ni-Catalyzed Trifluoromethylthiolation of Aryl Halides

(2017) Indrek Kalvet et al.   ACS Catalysis

A General Small-Scale Reactor To Enable Standardization and Acceleration of Photocatalytic Reactions

(2017) Chi “Chip” Le et al.   ACS Central Science

Stereospecific and stereoconvergent cross-couplings between alkyl electrophiles

(2017) Erika L. Lucas et al.   Nature Reviews Chemistry

The merger of transition metal and photocatalysis

(2017) Jack Twilton et al.   Nature Reviews Chemistry

Silyl Radical Activation of Alkyl Halides in Metallaphotoredox Catalysis: A Unique Pathway for Cross-Electrophile Coupling

(2016) Patricia Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Identification of novel small-molecule inhibitors targeting menin–MLL interaction, repurposing the antidiarrheal loperamide

(2016) Liyan Yue et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Nickel-Catalyzed Reductive Couplings

(2016) Xuan Wang et al.   Topics in Current Chemistry

Methods and Mechanisms for Cross-Electrophile Coupling of Csp2 Halides with Alkyl Electrophiles

(2015) Daniel J. Weix   ACCOUNTS OF CHEMICAL RESEARCH

Nickel-Catalyzed Reductive Coupling of Aryl Bromides with Tertiary Alkyl Halides

(2015) Xuan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex

(2014) Shaozhong Ge et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Reductive Coupling of Alkyl Acids with Unactivated Tertiary Alkyl and Glycosyl Halides

(2014) Chenglong Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Carbon–Carbon Bond-Forming Reactions of Unactivated Tertiary Alkyl Halides: Suzuki Arylations

(2013) Susan L. Zultanski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group

(2013) Xi Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Coupling Reactions of Alkyl Electrophiles, Including Unactivated Tertiary Halides, To Generate Carbon–Boron Bonds

(2012) Alexander S. Dudnik et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Coupling of Aryl Bromides with Tertiary Grignard Reagents Utilizing Donor-Functionalized N-Heterocyclic Carbenes (NHCs)

(2011) Claudia Lohre et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nickel-Catalyzed Kumada Cross-Coupling Reactions of Tertiary Alkylmagnesium Halides and Aryl Bromides/Triflates

(2011) Amruta Joshi-Pangu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Cross-Couplings Involving Carbon−Oxygen Bonds

(2010) Brad M. Rosen et al.   CHEMICAL REVIEWS

Stereospecific Nickel-Catalyzed Cross-Coupling Reactions of Alkyl Ethers: Enantioselective Synthesis of Diarylethanes

(2010) Buck L. H. Taylor et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold(III)-Catalyzed Halogenation of Aromatic Boronates withN-Halosuccinimides

(2010) Di Qiu et al.   ORGANIC LETTERS

Synthesis and reactivity of a putative biogenetic precursor to tricholomenyns B, C, D and E

(2010) Xinghua Ma et al.   TETRAHEDRON LETTERS

Contribution of Electrochemistry to Organometallic Catalysis

(2008) Anny Jutand   CHEMICAL REVIEWS