4.6 Article

Preparation and characterization of soluble bismaleimide-triazine resins based on asymmetric bismaleimide

Journal

JOURNAL OF APPLIED POLYMER SCIENCE
Volume 134, Issue 9, Pages -

Publisher

WILEY-BLACKWELL
DOI: 10.1002/app.44519

Keywords

differential scanning calorimetry (DSC); mechanical properties; polyimides; thermal properties; thermogravimetric analysis (TGA)

Funding

  1. Natural Science Foundation of Shanghai [13ZR1451300]

Ask authors/readers for more resources

A series of bismaleimide-triazine resins (EBT) were prepared from 2-(4'-maleimido) phenyl-2-(4'-maleimidophenoxyl) phenylbutane (EBA-BMI) and 2,2-bis(4-cyanatophenyl) propane (BADCy). The resins show attractive processability with good solubility in low boiling point solvents and wide processing temperature windows. Introduction of diallylbisphenol A (DBA) can decrease the curing temperature of EBT resins that the curing exothermic peak temperature shifted from 291 to 237 degrees C as the content of DBA increased from 0 to 20%. The curing condition influenced the thermal properties of the cured EBT resins. The glass transition temperature increased as the curing temperature and curing time increased. The cured EBT resins show high glass transition temperature up to 352 degrees C, high thermal stability with 5% weight loss temperature over 405 degrees C, low coefficient of thermal expansion about 45 to 52 ppm/degrees C, and high storage modulus up to 2.6 GPa at 250 degrees C. (C) 2016 Wiley Periodicals, Inc.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available