4.7 Article

Identifying the principal factors controlling uranium enrichment: Semi-quantitative mineralogy and geochemistry of the sandstone-type Qianjiadian uranium deposit, northeast China

Journal

ORE GEOLOGY REVIEWS
Volume 144, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.oregeorev.2022.104807

Keywords

Sandstone-type uranium deposit; Uranium enrichment; Visible and near infrared -shortwave infrared spectroscopy; Semi-quantitative estimation; Qianjiadian; Drill core

Funding

  1. youth foundation of BRIUG [YQJ2009, YQJ2010]
  2. HNKF project [YHSL1403-7, YH2001-05]
  3. National Natural Science Foundation of China [41872201]

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The Qianjiadian deposit is the first late Mesozoic-Cenozoic sandstone-type uranium deposit discovered in the Songliao Basin, northeast China. The study of gamma ray intensity and mineralogical and geochemical characteristics suggests that low-temperature groundwater redox reactions were the main control on uranium enrichment.
The Qianjiadian deposit is the first late Mesozoic-Cenozoic sandstone-type uranium deposit discovered in the Songliao Basin, northeast China. It remains uncertain whether high-temperature hydrothermal fluid or low temperature groundwater dominated the mineralization process that led to uranium enrichment in this deposit. We investigated the gamma ray intensity and semi-quantitative mineralogical and geochemical characteristics of drill cores from the Qianjiadian deposit. A total of 60 gamma ray anomalies were identified; most of these anomalies are associated with negative Fe2O3 and Fe3+/Fe2+ anomalies, four are associated with positive total organic carbon (TOC) anomalies, and none are associated with positive carbonate (calcite + dolomite) anomalies. The absence of positive carbonate anomalies, together with low kaolinite crystallinities, rules out the influence of high-temperature fluid on uranium enrichment. The dominant negative Fe2O3 and Fe3+/Fe2+ anomalies and the occurrence of pyrite in thin section and gray-red sandstone and native sulfur in some U-rich drill cores indicate that redox reactions in low-temperature groundwater may have been the principal control on uranium enrichment. In addition, two gamma ray anomalies are associated with positive TOC, Fe2O3, and Fe3+/ Fe2+ anomalies and another two are associated only with positive kaolinite anomalies, suggesting that carbonaceous debris and kaolinite could also cause limited uranium enrichment.

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