Journal
MICROPOROUS AND MESOPOROUS MATERIALS
Volume 336, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.micromeso.2022.111846
Keywords
Biofuels; Sugar alcohols; Cellulose; Solid acids; Glucose
Categories
Funding
- Saudi Aramco [CENT 2207]
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This paper evaluates the potential of cellulose-to-glucose reaction and transformation into fuels/chemicals, and analyzes the roles of catalysts such as ionic liquids, sulfonated mesoporous carbon systems, and Fe-modified zeolites in the process. It also discusses the parameters and catalyst-stability challenges of the upgrading process, and provides new directions for further research.
The abundant of cellulose biomass resources and the projected global market escalations for allied chemicals and fuels inferred that large-scale valorization would benefit the global energy and chemical industries. In line with this strategy, the paper carefully reviewed and examined resourceful literature on the potentials of solid acids for cellulose-to-glucose reaction and the transformation into fuels/chemicals. It initially evaluated the cellulose to glucose path by considering ionic liquids as the media for hydrolysis. The influence of employing sulfonated mesoporous carbon systems was adequately explored. In addition to critical analysis of the cellulose to sugar alcohols, the paper also analyzed the role of Fe-modified zeolites for glucose upgrading. It simultaneously discussed the parameters necessary for process upgrade and addressing catalyst-stability challenges. We have also provided new directions for further investigations in line with the findings established.
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