Material Properties of Functional Polyethylenes from Transition-Metal-Catalyzed Ethylene–Polar Monomer Copolymerization

An Ionic Cluster Strategy for Performance Improvements and Product Morphology Control in Metal-Catalyzed Olefin–Polar Monomer Copolymerization

(2022) Chen Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A disubstituted-norbornene-based comonomer strategy to address polar monomer problem

(2021) Menghe Xu et al.   Science Bulletin

Recent advances in nickel mediated copolymerization of olefin with polar monomers

(2021) Hongliang Mu et al.   COORDINATION CHEMISTRY REVIEWS

Efficient Copolymerization of Acrylate and Ethylene with Neutral P, O-Chelated Nickel Catalysts: Mechanistic Investigations of Monomer Insertion and Chelate Formation

(2021) Shuoyan Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Synthesis of Norbornene-Based Polar-Functionalized Polyolefin Elastomers

(2021) Wenbing Wang et al.   MACROMOLECULES

Hydrogen‐Bonding‐Induced Heterogenization of Nickel and Palladium Catalysts for Copolymerization of Ethylene with Polar Monomers

(2021) Hu Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoresponsive Palladium and Nickel Catalysts for Ethylene Polymerization and Copolymerization

(2021) Dan Peng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Nonalternating Polyketones Using Cationic Diphosphazane Monoxide-Palladium Complexes

(2021) Shi-Yu Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Synthesis of Functional Thermoplastic Elastomer with Excellent Mechanical Properties by Scandium‐Catalyzed Copolymerization of Ethylene and Fluorostyrenes

(2021) Tiantian Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High Density Polyethylenes Bearing Isolated In‐Chain Carbonyls**

(2021) Shan Tang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Terpolymerization of Ethylene and Two Different Methoxyaryl‐Substituted Propylenes by Scandium Catalyst Makes Tough and Fast Self‐Healing Elastomers

(2021) Yang Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Polyethylene materials with in-chain ketones from nonalternating catalytic copolymerization

(2021) Maximilian Baur et al.   SCIENCE

Early Transition Metal Catalysis for Olefin-Polar Monomer Copolymerization

(2020) Tobin Jay Marks et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catechol Functionalized Polyolefins

(2020) Yinna Na et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A simple and versatile nickel platform for the generation of branched high molecular weight polyolefins

(2020) Tao Liang et al.   Nature Communications

A Self‐Supporting Strategy for Gas‐Phase and Slurry‐Phase Ethylene Polymerization using Late‐Transition‐Metal Catalysts

(2020) Shengyu Dai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Synthesis of Polar Functionalized Polyethylene Thermoplastic Elastomer

(2020) Shengyu Dai et al.   MACROMOLECULES

Facile Synthesis of High-Molecular-Weight Vinyl Sulfone (Sulfoxide) Modified Polyethylenes via Coordination–Insertion Copolymerization

(2020) Yanping Zhang et al.   MACROMOLECULES

Photodegradable branched polyethylenes from carbon monoxide copolymerization under benign conditions

(2020) Tobias O. Morgen et al.   Nature Communications

Toward the Copolymerization of Propylene with Polar Comonomers

(2020) Stephen L. J. Luckham et al.   ACCOUNTS OF CHEMICAL RESEARCH

Insertion copolymerization of functional olefins: Quo Vadis?

(2020) Rajkumar S. Birajdar et al.   EUROPEAN POLYMER JOURNAL

Polyolefins with Intrinsic Antimicrobial Properties

(2020) Chen Zou et al.   MACROMOLECULES

Polyolefin thermoplastic elastomers from polymerization catalysis: Advantages, pitfalls and future challenges

(2020) Giorgia Zanchin et al.   PROGRESS IN POLYMER SCIENCE

Interplay of Supramolecular Chemistry and Photochemistry with Palladium-Catalyzed Ethylene Polymerization

(2020) Guohong Wang et al.   CCS Chemistry

Synthesis of Self-Healing Polymers by Scandium-Catalyzed Copolymerization of Ethylene and Anisylpropylenes

(2019) Haobing Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Emerging Palladium and Nickel Catalysts for Copolymerization of Olefins with Polar Monomers

(2019) Chen Tan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Olefins and Vinyl Polar Monomers: Bridging the Gap for Next Generation Materials

(2019) Eva Harth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Expanding Polyethylene and Polypropylene Applications to High-Energy Areas by Applying Polyolefin-Bonded Antioxidants

(2019) T. C. Mike Chung   MACROMOLECULES

Scandium-Catalyzed Regio- and Stereoselective Cyclopolymerization of Functionalized α,ω-Dienes and Copolymerization with Ethylene

(2019) Haobing Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Systematic Studies on (Co)Polymerization of Polar Styrene Monomers with Palladium Catalysts

(2019) Lei Cui et al.   MACROMOLECULES

Recent advances in thermoplastic elastomers from living polymerizations: Macromolecular architectures and supramolecular chemistry

(2019) Weiyu Wang et al.   PROGRESS IN POLYMER SCIENCE

Polar-Functionalized, Crosslinkable, Self-Healing, and Photoresponsive Polyolefins

(2019) Chen Zou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functional Isotactic Polypropylenes via Efficient Direct Copolymerizations of Propylene with Various Amino-Functionalized α-Olefins

(2019) Ruining Shang et al.   MACROMOLECULES

Direct and Tandem Routes for the Copolymerization of Ethylene with Polar Functionalized Internal Olefins

(2019) Min Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts

(2018) Zhou Chen et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Versatile Ligand Platform for Palladium- and Nickel-Catalyzed Ethylene Copolymerization with Polar Monomers

(2018) Min Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Homo- and Copolymerization of Polar Monomers: Synthesis of Aliphatic and Aromatic Polymers

(2018) Shingo Ito   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Recent developments in redox-active olefin polymerization catalysts

(2018) Jordan M. Kaiser et al.   COORDINATION CHEMISTRY REVIEWS

Electron-Rich Metal Cations Enable Synthesis of High Molecular Weight, Linear Functional Polyethylenes

(2018) Wei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Increasing Polypropylene High Temperature Stability by Blending Polypropylene-Bonded Hindered Phenol Antioxidant

(2018) Gang Zhang et al.   MACROMOLECULES

Direct Synthesis of Polar-Functionalized Linear Low-Density Polyethylene (LLDPE) and Low-Density Polyethylene (LDPE)

(2018) Yinna Na et al.   MACROMOLECULES

Polyethylene containing antioxidant moieties exhibiting high thermal-oxidative stability for high temperature applications

(2018) Wei Zhu et al.   POLYMER

Synthesis of polyolefin elastomers from unsymmetrical α-diimine nickel catalyzed olefin polymerization

(2018) Jun Fang et al.   Polymer Chemistry

Redox-Controlled Polymerization and Copolymerization

(2018) Changle Chen   ACS Catalysis

Designing catalysts for olefin polymerization and copolymerization: beyond electronic and steric tuning

(2018) Changle Chen   Nature Reviews Chemistry

Positive effect of polar styrenes on copolymerization with ethylene and mechanism

(2018) Bo Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Direct Synthesis of Various Branched, Carboxylic Acid-Functionalized Polyolefins: Characterization, Derivatization, and Properties

(2018) Shengyu Dai et al.   MACROMOLECULES

Selective Chain-End Functionalization of Polar Polyethylenes: Orthogonal Reactivity of Carbene and Polar Vinyl Monomers in Their Copolymerization with Ethylene

(2018) Xiaoming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

High-Impact Polyamide Composites with Linear Ethylene-Norbornene Anhydride Copolymers from Insertion Polymerization

(2017) Nicole Schuster et al.   MACROMOLECULAR MATERIALS AND ENGINEERING

Polypropylene Copolymer Containing Cross-Linkable Antioxidant Moieties with Long-Term Stability under Elevated Temperature Conditions

(2017) Gang Zhang et al.   MACROMOLECULES

Reactivity of Difunctional Polar Monomers and Ethylene Copolymerization: A Comprehensive Account

(2017) Shahaji R. Gaikwad et al.   MACROMOLECULES

Efficient Modulation of Polyethylene Microstructure by Proper Activation of (α-Diimine)Ni(II) Catalysts: Synthesis of Well-Performing Polyethylene Elastomers

(2017) Ilaria D’Auria et al.   MACROMOLECULES

Direct Synthesis of Thermoplastic Polyolefin Elastomers from Nickel-Catalyzed Ethylene Polymerization

(2017) Kunbo Lian et al.   MACROMOLECULES

Synthesis and Reactivity of Palladium(II) Alkyl Complexes that Contain Phosphine-cyclopentanesulfonate Ligands

(2017) Rebecca E. Black et al.   ORGANOMETALLICS

Eugenol as renewable comonomer compared to 4-penten-1-ol in ethylene copolymerization using a palladium aryl sulfonate catalyst

(2017) L.R. Parisi et al.   POLYMER

Modulating polyolefin properties through the incorporation of nitrogen-containing polar monomers

(2017) Yinna Na et al.   Polymer Chemistry

Combining polyethylene and polypropylene: Enhanced performance with PE/iPP multiblock polymers

(2017) James M. Eagan et al.   SCIENCE

Rational Design of High-Performance Phosphine Sulfonate Nickel Catalysts for Ethylene Polymerization and Copolymerization with Polar Monomers

(2017) Min Chen et al.   ACS Catalysis

Polyolefins, a Success Story

(2017) et al.   Polymers

Heteroatom-assisted olefin polymerization by rare-earth metal catalysts

(2017) Chunxiang Wang et al.   Science Advances

Crystalline Isotactic Polar Polypropylene from the Palladium-Catalyzed Copolymerization of Propylene and Polar Monomers

(2016) Yusuke Ota et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Synthesis of Telechelic Polyethylene by Selective Insertion Polymerization

(2016) Zhongbao Jian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Synthesis of Functionalized High-Molecular-Weight Polyethylene by Copolymerization of Ethylene with Polar Monomers

(2016) Shengyu Dai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Functional Short-Bite Ligands: Synthesis, Coordination Chemistry, and Applications of N-Functionalized Bis(diaryl/dialkylphosphino)amine-type Ligands

(2016) Christophe Fliedel et al.   CHEMICAL REVIEWS

Systematic Investigations of Ligand Steric Effects on α-Diimine Palladium Catalyzed Olefin Polymerization and Copolymerization

(2016) Shengyu Dai et al.   MACROMOLECULES

Controlled Chain Walking for the Synthesis of Thermoplastic Polyolefin Elastomers: Synthesis, Structure, and Properties

(2016) Kyle S. O’Connor et al.   MACROMOLECULES

Controlled isomerization polymerization of olefins, cycloolefins, and dienes

(2016) Daisuke Takeuchi et al.   POLYMER

Highly Isoselective Coordination Polymerization ofortho-Methoxystyrene with β-Diketiminato Rare-Earth-Metal Precursors

(2015) Dongtao Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insertion Homo- and Copolymerization of Diallyl Ether

(2015) Zhongbao Jian et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Robust Palladium(II) α-Diimine Catalysts for Slow-Chain-Walking Polymerization of Ethylene and Copolymerization with Methyl Acrylate

(2015) Shengyu Dai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From Multisite Polymerization Catalysis to Sustainable Materials and All-Polyolefin Composites

(2015) Markus Stürzel et al.   CHEMICAL REVIEWS

Suppression of Chain Transfer in Catalytic Acrylate Polymerization via Rapid and Selective Secondary Insertion

(2015) Zhongbao Jian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

(α-Diimine)palladium catalyzed ethylene polymerization and (co)polymerization with polar comonomers

(2015) Lihua Guo et al.   Science China-Chemistry

Ethylene Polymerization and Copolymerization with Polar Monomers by Cationic Phosphine Phosphonic Amide Palladium Complexes

(2015) Xuelin Sui et al.   ACS Catalysis

Palladium and Nickel Catalyzed Chain Walking Olefin Polymerization and Copolymerization

(2015) Lihua Guo et al.   ACS Catalysis

Long-Spaced Polyketones from ADMET Copolymerizations as Ideal Models for Ethylene/CO Copolymers

(2015) Patrick Ortmann et al.   ACS Macro Letters

Quantification of the Steric Influence of Alkylphosphine–Sulfonate Ligands on Polymerization, Leading to High-Molecular-Weight Copolymers of Ethylene and Polar Monomers

(2014) Yusuke Ota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nanocomposites of Phosphonic-Acid-Functionalized Polyethylenes with Inorganic Quantum Dots

(2014) Thomas Rünzi et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Enhanced Polymeric Dielectrics through Incorporation of Hydroxyl Groups

(2014) Mayank Misra et al.   MACROMOLECULES

Transition-Metal-Catalyzed Functional Polyolefin Synthesis: Effecting Control through Chelating Ancillary Ligand Design and Mechanistic Insights

(2014) Brad P. Carrow et al.   MACROMOLECULES

Syntheses of Well-Defined Functional Isotactic Polypropylenes via Efficient Copolymerization of Propylene with ω-Halo-α-alkenes by Post-metallocene Hafnium Catalyst

(2014) Xiaoyan Wang et al.   MACROMOLECULES

Copolymerization of Ethylene and Methyl Acrylate by Cationic Palladium Catalysts That Contain Phosphine-Diethyl Phosphonate Ancillary Ligands

(2014) Nathan D. Contrella et al.   ORGANOMETALLICS

The microstructure and melt properties of CO–ethylene copolymers with remarkably low CO content

(2014) Saeeda S. Soomro et al.   Polymer Chemistry

Ortho-Phosphinobenzenesulfonate: A Superb Ligand for Palladium-Catalyzed Coordination–Insertion Copolymerization of Polar Vinyl Monomers

(2013) Akifumi Nakamura et al.   ACCOUNTS OF CHEMICAL RESEARCH

Saturated Polar-Substituted Polyethylene Elastomers from Insertion Polymerization

(2013) Thomas Rünzi et al.   ADVANCED FUNCTIONAL MATERIALS

Incorporation of Vinyl Chloride in Insertion Polymerization

(2013) Hannes Leicht et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of functional ‘polyolefins’: state of the art and remaining challenges

(2013) Nicole M. G. Franssen et al.   CHEMICAL SOCIETY REVIEWS

Copolymerization of Ethylene with Functionalized Olefins by [ONX] Titanium Complexes

(2013) Zhou Chen et al.   MACROMOLECULES

Ethylene/allyl monomer cooligomerization by nickel/phosphine–sulfonate catalysts

(2012) Shingo Ito et al.   DALTON TRANSACTIONS

Synthesis of Functional Polyolefins Using Cationic Bisphosphine Monoxide–Palladium Complexes

(2012) Brad P. Carrow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organometallics Roundtable 2011

(2012) John A. Gladysz et al.   ORGANOMETALLICS

Multinuclear Olefin Polymerization Catalysts

(2011) Massimiliano Delferro et al.   CHEMICAL REVIEWS

New Polyethylene Based Anion Exchange Membranes (PE–AEMs) with High Ionic Conductivity

(2011) Min Zhang et al.   MACROMOLECULES

o-Diarylphosphinoferrocene Sulfonate Palladium Systems for Nonalternating Ethene–Carbon Monoxide Copolymerization

(2011) Chao Chen et al.   ORGANOMETALLICS

Efficient Synthesis of Hydroxylated Polyethylene via Copolymerization of Ethylene with 5-Norbornene-2-methanol using Bis(β-enaminoketonato)titanium Catalysts

(2011) Miao Hong et al.   ORGANOMETALLICS

Ketene Functionalized Polyethylene: Control of Cross-Link Density and Material Properties

(2010) Frank A. Leibfarth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroxyl-Functionalized Norbornene Based Co- and Terpolymers by Scandium Half-Sandwich Catalyst

(2010) Incoronata Tritto et al.   MACROMOLECULAR CHEMISTRY AND PHYSICS

Synthesis of Functionalized Isotactic Polypropylene Dielectrics for Electric Energy Storage Applications

(2010) Xuepei Yuan et al.   MACROMOLECULES

[O−NSR]TiCl3-Catalyzed Copolymerization of Ethylene with Functionalized Olefins

(2009) Xiao-Hong Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coordination−Insertion Copolymerization of Fundamental Polar Monomers

(2009) Akifumi Nakamura et al.   CHEMICAL REVIEWS

Ethylene/Polar Monomer Copolymerization Behavior of Bis(phenoxy–imine)Ti Complexes: Formation of Polar Monomer Copolymers

(2008) Hiroshi Terao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bimetallic Effects in Homopolymerization of Styrene and Copolymerization of Ethylene and Styrenic Comonomers:  Scope, Kinetics, and Mechanism

(2008) Neng Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Linear Polyethylene with Tunable Surface Properties by Catalytic Copolymerization of Ethylene withN-Vinyl-2-pyrrolidinone andN-Isopropylacrylamide

(2008) Kirill M. Skupov et al.   MACROMOLECULES