Article
Chemistry, Physical
Pan Ye, Xiaowei Li, Kuidong He, Xuri Wang, Ahmad Naveed, Yu Zhou, Mingru Su, Panpan Zhang, Yunjian Liu
Summary: A polymer coating with semi-interpenetrating network (s-IPN) structure was designed to protect the Zn anode in aqueous Zn-ion batteries. The s-IPN polymer coating enables uniform Zn deposition and excellent dendrite growth resistance, leading to significantly improved cycle life and stability of the battery.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Huige Chen, Zechu Guo, Huashan Wang, Weiyuan Huang, Feng Pan, Ziqi Wang
Summary: A delayed nucleation strategy is proposed to improve the performance of Zn anodes in aqueous Zn-ion batteries. Through a liquid metal (LM) interlayer, the reduction and deposition of Zn are temporally and spatially separated, achieving fast Zn redox kinetics and dendrite-free Zn (002) deposition. The flexible anode (Zn@LM-AgT) demonstrates stabilized Zn plating/stripping cycling over 700 hours with reduced overpotential, and when coupled with a vanadium-based cathode, the full cell exhibits six times higher remaining capacity after 1000 cycles compared to the reference cell. The delayed nucleation mechanism provides a novel approach to high-performance metallic anodes.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Physical
Xiaomin Huang, Heng Cao, Yu Liu, Qiang Hu, Qiaoji Zheng, Jingxin Zhao, Dunmin Lin, Bingang Xu
Summary: Aqueous rechargeable Zn-ion batteries (ARZIBs) have gained attention for their safety, high energy density, and environmental friendliness. However, dendrite formation and corrosive reactions on the Zn anode surface have posed challenges. In this study, Ga3+-doped NaV2(PO4)(3) with Na superionic conductor (NASICON) structure was used as an artificial layer to stabilize the Zn anode. The optimal NVP-Ga(0.5) layer effectively homogenized ion flux and promoted uniform deposition of zinc, inhibiting dendrite growth and parasitic reactions. The resulting batteries showed stable operation and high discharge capacity.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Ping Xiao, Yu Wu, Kailang Liu, Xin Feng, Jianing Liang, Yinghe Zhao, Chenggang Wang, Xijin Xu, Tianyou Zhai, Huiqiao Li
Summary: An ultrathin and ultra-flat Sb2O3 molecular crystal layer was introduced to stabilize Zn anode and suppress dendrite growth and side reactions, significantly improving the cycle life of aqueous Zn metal batteries.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Ping Xiao, Yu Wu, Kailang Liu, Xin Feng, Jianing Liang, Yinghe Zhao, Chenggang Wang, Xijin Xu, Tianyou Zhai, Huiqiao Li
Summary: In this study, we introduced an ultrathin and ultra-flat Sb2O3 molecular crystal layer to stabilize the anode of Zn metal batteries. The experimental results show that the Sb2O3 layer can effectively control the deposition of Zn metal and significantly improve the cycle life of the batteries.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Nanoscience & Nanotechnology
Wenqi Bi, Jingjing Chai, Lanfen Meng, Zhendong Li, Tengpeng Xiong, Jie Shu, Xiayin Yao, Zhe Peng
Summary: Rechargeable aqueous zinc metal batteries have received great attention due to their safety and low cost. However, the growth of zinc dendrites in aqueous electrolytes severely limits the lifespan of these batteries. In this study, a strategy was proposed to enhance the activity of zinc-alloying sites by introducing a small amount of polar organic additive in the electrolyte, forming a molecular crowding layer to prevent parasitic water reduction during zinc deposition. This multifunctional interfacial structure allows stable cycling of the zinc anode and can potentially improve the performance of other aqueous metal batteries.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Article
Chemistry, Physical
Yao Li, Zhixiang Tan, Yongshi Liang, Yong Xiao, Dandan Cen, Yingliang Liu, Yeru Liang
Summary: In this study, an amine-functionalized carbon cloth was used as the host to prepare a dendrite-free Zn anode, which showed stable performance and longer cycling life compared to conventional Zn anodes. The results indicate that the amine functionalization improves the binding energy between Zn atoms and CC, leading to enhanced conductivity and dendrite suppression.
ACS APPLIED ENERGY MATERIALS
(2021)
Article
Engineering, Environmental
Tiansheng Mu, Hongfu Lu, Yang Ren, Xin Wan, Xing Xu, Siping Tan, Yulin Ma, Geping Yin
Summary: An artificial protective layer with interface defects is proposed to improve the cycling stability and rate performance of lithium metal anodes. The study focuses on titanium oxide (TiO2) and demonstrates that the interfacial oxygen-deficient TiO2 coating (H-TiO2) promotes lithium ion diffusion kinetics and prevents lithium dendrite formation. The H-TiO2 protective layer enables lithium metal anodes to have ultra-long cycling stability and improves the performance of full cells paired with LiFePO4 cathode.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Physical
Hee Jae Kim, Nurzhan Umirov, Jae-Sang Park, Jae-Hong Lim, Jiefang Zhu, Sung-Soo Kim, Seung-Taek Myung
Summary: In this study, the addition of phosphorous pentoxide (P2O5) to carbonate-based electrolytes was found to effectively suppress the dendritic growth on the surface of a lithium-metal anode, leading to improved lifespan and coulombic efficiency. The reduction mechanism of the P2O5-induced solid-electrolyte interphase (SEI) formation on Li metal was also elucidated, providing insights into the inhibitory effect on dendritic growth.
ENERGY STORAGE MATERIALS
(2022)
Article
Chemistry, Physical
Mengxuan Sun, Yongxiu Sun, Nengze Wang, Lei Hu, Xiaohe Ren, Chunyang Jia, Zhijie Li
Summary: This study successfully addresses the cycling stability issue of aqueous Zn-ion batteries by preparing a fractal structure anode called ZZCC. The ZZCC anode can regulate the zinc plating process, inhibit dendritic growth and side effects, and exhibits excellent cycling performance.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2024)
Article
Chemistry, Multidisciplinary
Yan Xu, Xinhua Zheng, Jifei Sun, Weiping Wang, Mingming Wang, Yuan Yuan, Mingyan Chuai, Na Chen, Hanlin Hu, Wei Chen
Summary: A nucleophilic interfacial layer (NIL) was developed to achieve a stable Zn anode for aqueous Zn batteries, resulting in improved performance and extended lifespan.
Article
Nanoscience & Nanotechnology
Neng Yu, Yanpeng Li, Wenhao She, Hanbin Li, Haoxiong Chen, Wenchong Cheng, Jinxue Chen, Haiyuan Liu, Yunliang Tu, Zhengkai Huang, Yinpeng Wan, Lixia Zou, Xing Zhong, Junming Luo, Kai Guo
Summary: The research successfully developed a robust sodium zinc phosphate layer (Zn@NZP) on zinc metal foil anode via facile electrodeposition, which effectively alleviates dendrite formation and corrosion issues on the anode of aqueous zinc batteries, leading to improved cycle life and battery performance.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Engineering, Multidisciplinary
Hou ZhenHua, Tao HuaChao, Wang JiaXu, Zhang LuLu, Yang XueLin
Summary: A simple in-situ growth strategy was applied to fabricate a Zn anode with a ZnO protective layer, which successfully lengthened the cycle life and inhibited the dendrite growth and side reactions. The Zn/ZnO anode showed excellent performance in symmetrical cells and composite cells.
SCIENCE CHINA-TECHNOLOGICAL SCIENCES
(2022)
Article
Chemistry, Physical
Qiang Hu, Jisong Hu, Yuanxia Li, Xinyi Zhou, Shixiang Ding, Qiaoji Zheng, Dunmin Lin, Jingxin Zhao, Bingang Xu
Summary: This study investigates the corrosion mechanism of Zn metal in slightly acidic electrolytes and proposes a method for co-modification of the Zn anode using ZnO@Cu solid solution interface and TS additive. Experimental results show that the modified Zn anode exhibits low polarization and high cycling stability.
JOURNAL OF MATERIALS CHEMISTRY A
(2022)
Article
Nanoscience & Nanotechnology
Murali Bissannagari, Mahammad Rafi Shaik, Kuk Young Cho, Jihoon Kim, Sukeun Yoon
Summary: This study demonstrates a new strategy to stabilize metal-based batteries by using bimodal dielectric particles as artificial layers to suppress dendrite formation. The artificial layer induces electric polarization and sequentially moves zinc ions towards the zinc anode, effectively inhibiting zinc dendrite growth and significantly improving the electrochemical performance of zinc anodes.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Multidisciplinary
Hong Zhang, Bin Song, Weiwei Zhang, Bowen An, Lin Fu, Songtao Lu, Yingwen Cheng, Qianwang Chen, Ke Lu
Summary: In this study, core-shell structured composite matrixes were used to achieve nearly fully reversible cycling of sulfur cathodes for Na-S batteries. The bidirectional tandem electrocatalysis enabled successive reversible conversion of both long- and short-chain polysulfides, while Fe2O3 and redox-active Fe(CN)(6)(4-)-doped polypyrrole shell facilitated specific conversions. The electrochemically reactive Na2S could be readily charged back to sulfur, and stable cycling of a Na-S pouch cell with high reversible capacity was demonstrated.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Nanoscience & Nanotechnology
Lei Zhao, Shirong Sun, Jinxin Lin, Lei Zhong, Liheng Chen, Jing Guo, Jian Yin, Husam N. Alshareef, Xueqing Qiu, Wenli Zhang
Summary: Amorphous carbons with high heteroatom doping were prepared from renewable lignin biomacromolecule precursors. The nitrogen/sulfur co-doped lignin-derived porous carbons exhibited abundant defective active sites, resulting in high reversible capacity and cycling stability. The potassium-ion hybrid capacitors assembled with NSLPC anodes showed excellent cycling stability and high energy density.
NANO-MICRO LETTERS
(2023)
Article
Chemistry, Physical
Fuwang Wen, Yuan Yan, Shirong Sun, Xu Li, Xing He, Qingwei Meng, Jefferson Zhe Liu, Xueqing Qiu, Wenli Zhang
Summary: Nitrogen doping enhances the capacitive performance of zinc-ion hybrid supercapacitor by promoting pseudocapacitive reactions through lowering the energy barrier for the change of oxidation states of carbonyl moieties. The as-constructed zinc-ion hybrid supercapacitors, with nitrogen/oxygen dopants and 3D interconnected hierarchical porous carbon matrix, exhibit high gravimetric capacitance and excellent rate capability.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Multidisciplinary
Jinwei Tu, Huigang Tong, Peichen Wang, Dongdong Wang, Yang Yang, Xiangfu Meng, Lin Hu, Hui Wang, Qianwang Chen
Summary: Due to the deficiency and uneven distribution of lithium resources, potassium-ion batteries have attracted more attention as viable alternatives to lithium-ion batteries. This study shows that the unique anti-spinel structure of magnetite can serve as K+ storage sites, and carbon-coated Fe3O4@C nanoparticles exhibit high reversible capacity and hyper stable cycling performance in potassium-ion batteries.
Article
Multidisciplinary Sciences
Dongdong Wang, Jiawei Liu, Changlai Wang, Weiyun Zhang, Guangbao Yang, Yun Chen, Xiaodong Zhang, Yinglong Wu, Long Gu, Hongzhong Chen, Wei Yuan, Xiaokai Chen, Guofeng Liu, Bin Gao, Qianwang Chen, Yanli Zhao
Summary: Cancer immunotherapy is revolutionizing oncology and the combination of nanotechnology and immunotherapy provides an opportunity to enhance antitumor immune response. This study presents a mitochondria-targeting nanoplatform, MiBaMc, which consists of Prussian blue nanoparticles derived from bacteria and shows enhanced tumor inhibition in mouse models. The findings demonstrate the potential of targeted nanoparticles in boosting antitumor immunity.
NATURE COMMUNICATIONS
(2023)
Article
Materials Science, Composites
Junli Chen, Jianhui Ma, Bowen Liu, Ziyan Li, Xiaojun Zhang, Shirong Sun, Ke Lu, Jian Yin, Suli Chen, Xihong Zu, Zejie Zhang, Xueqing Qiu, Yanlin Qin, Wenli Zhang
Summary: Rechargeable aqueous zinc-ion batteries based on manganese-based cathode materials face issues such as low conductivity and dissolution, leading to instability. This study proposes a method of in situ reaction between hydroxyethylene-1,1,diphosphonic acid and manganese dioxide to create a phosphorylated manganese dioxide (PMO) cathode. This strategy improves the stability of the cathode and provides a general design concept for manganese-based cathode materials in aqueous zinc-ion batteries.
COMPOSITES COMMUNICATIONS
(2023)
Article
Chemistry, Multidisciplinary
Yuanjian Li, Eryang Mao, Zhiwen Min, Zhao Cai, Zihe Chen, Lin Fu, Xiangrui Duan, Lingyue Wang, Chang Zhang, Ziheng Lu, Wei Liu, Zhi Wei Seh, Yongming Sun
Summary: In this study, a new concept of functional interphase design is proposed to improve the electrochemical reaction kinetics of low-temperature lithium metal anodes. The hybrid polymer-alloy-fluoride (PAF) interphase not only exhibits superior lithiophilicity, but also provides abundant pathways for fast and homogeneous Li+ transport. The designed PAF-Li anode shows stable performance with low voltage hysteresis and dendrite-free morphology in cold temperatures.
Article
Green & Sustainable Science & Technology
Jiahao Zhu, Xueqing Qiu, Shirong Sun, Tao Huang, Zongyi Huang, Lei Zhao, Xihong Zu, Wenli Zhang
Summary: A sustainable production process for the co-production of porous carbon and calcium chloride was proposed using renewable lignin as the carbon precursor. Homogeneous mixing of lignin precursors and CaO facilitated the creation of porous carbons, and high purity carbon dioxide and value-added CaCl2 were obtained through subsequent processes. The formation mechanism of the pore structure evolution of LPC was elucidated, and the obtained porous carbons showed excellent electrochemical performances. This combined sustainable production process has the potential to be developed as a practical method for producing calcium chloride and porous carbons.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Chemistry, Physical
Qingwei Meng, Binyi Chen, Wenbin Jian, Xiaoshan Zhang, Shirong Sun, Tiejun Wang, Wenli Zhang
Summary: This study reports the preparation of hard carbons with different pore structures by carbonizing different lignin precursors, and investigates the relationship between their microstructures and sodium-ion storage performance. Hard carbon prepared from corn cob lignin shows the highest closed pore volume, resulting in the highest plateau capacity. The formation of closed pores is attributed to the transformation of micropores at high carbonization temperatures. The study proposes a method for calculating the closed pore volume and finds a positive correlation between plateau capacity and closed pore volume.
JOURNAL OF POWER SOURCES
(2023)
Article
Chemistry, Physical
Lei Zhong, Xueqing Qiu, Shunsheng Yang, Shirong Sun, Liheng Chen, Wenli Zhang
Summary: Biomass-derived carbons are promising anodes in potassium-ion hybrid capacitors due to their tunable structure and competitive cost-effectiveness. Nitrogen-doping strategy could enhance the K-ion storage performance by surface capacitive adsorption mechanism. This study proposed a supermolecule-regulated strategy to achieve highly nitrogen-doped carbon anodes with superior performances.
ENERGY STORAGE MATERIALS
(2023)
Article
Electrochemistry
Zhonggang Liu, Xi Liu, Bingchun Wang, Xinying Wang, Dongzhen Lu, Dijun Shen, Zhefei Sun, Yongchang Liu, Wenli Zhang, Qiaobao Zhang, Yunyong Li
Summary: A highly dense dual-encapsulated nano-architecture consisting of Ti3C2Tx MXene and graphene has been designed for the anode of potassium-ion batteries. This architecture exhibits high conductivity, compact encapsulation, large volumetric and areal capacity, long-term stable lifespan, and good electrolyte penetration. The findings of this study provide a feasible strategy for achieving high areal and volumetric capacity energy storage using ultra-thick, dense alloy-type electrodes.
Article
Electrochemistry
Xin Xiao, Shirong Sun, Yi Qi, Shuhua Hao, Wenli Zhang, Xueqing Qiu
Summary: By using Pt@CeO2 catalyst loaded with a small amount of noble metal, the electrooxidation of lignin through cleavage of C(OH)-C bond is triggered, leading to the highly selective synthesis of carboxylic acid compounds. This process generates more reactive oxygen species and promotes the cleavage of C(OH)-C bond and oxidation of benzaldehyde.
ELECTROCHIMICA ACTA
(2023)
Article
Chemistry, Multidisciplinary
Weiwei Zhang, Mingli Wang, Hong Zhang, Lin Fu, Wenli Zhang, Yupeng Yuan, Ke Lu
Summary: This study proposes a bidirectional catalysis concept based on a core-shell structured composite cathode design to regulate the Fe-I-2 electrochemical reactions. The composite cathode exhibits excellent reversible Fe2+ storage capability and stability.
Article
Chemistry, Physical
Yanlin Qin, Yunzhen Chen, Xuezhi Zeng, Yingchun Liu, Xuliang Lin, Wenli Zhang, Xueqing Qiu
Summary: In this study, carboxymethylated enzymatic hydrolysis lignin (EHL) was used as a biomacromolecule frame to improve the electrocatalytic activity and stability of molybdenum nickel alloy. The results showed that the MoNi4-NiO heterojunction improved the overpotentials and stability of the hydrogen evolution reaction. This work provided an effective strategy for improving the performance of noble-metal-free electrocatalysts.
GREEN ENERGY & ENVIRONMENT
(2023)
Article
Chemistry, Physical
Tianyu Chen, Zhibin Lu, Guangjin Zeng, Yongmin Xie, Jie Xiao, Zhifeng Xu
Summary: The study introduces a high-performance LSGM electrolyte-supported tubular DC-SOFC stack for portable applications, which shows great potential in developing into high-performing, efficient, and environmentally friendly portable power sources for distributed applications.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Wenbin Tong, Yili Chen, Shijie Gong, Shaokun Zhu, Jie Tian, Jiaqian Qin, Wenyong Chen, Shuanghong Chen
Summary: In this study, a three-dimensional porous NiO interface layer with enhanced anode dynamics is fabricated, forming a Schottky contact with the zinc substrate, allowing rapid and uniform zinc plating both inside and below the interface layer. The resulting NiO@Zn exhibits exceptional stability and high capacity retention.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yafeng Bai, Kaidi Li, Liying Wang, Yang Gao, Xuesong Li, Xijia Yang, Wei Lu
Summary: In this study, a flexible zinc ion supercapacitor with gel electrolytes, porous alpha-MnO2@reduced graphene oxide cathode, and activated carbon/carbon cloth anode was developed. The device exhibits excellent electrochemical performance and stability, even at low temperatures, with a high cycle retention rate after 5000 cycles.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Anmol Jnawali, Matt D. R. Kok, Francesco Iacoviello, Daniel J. L. Brett, Paul R. Shearing
Summary: This article presents the results of a systematic study on the electrochemical performance and mechanical changes in two types of commercial batteries with different anode chemistry. The study reveals that the swelling of anode layers in batteries with silicon-based components causes deformations in the jelly roll structure, but the presence of a small percentage of silicon does not significantly impact the cycling performance of the cells within the relevant state-of-health range for electric vehicles (EVs). The research suggests that there is room for improving the cell capacities by increasing the silicon loading in composite anodes to meet the increasing demands on EVs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yohandys A. Zulueta, My Phuong Pham-Ho, Minh Tho Nguyen
Summary: Advanced atomistic simulations were used to study ion transport in the Na- and K-doped lithium disilicate Li2Si2O5. The results showed that Na and K doping significantly enhanced Li ion diffusion and conduction in the material.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Zongying Han, Hui Dong, Yanru Yang, Hao Yu, Zhibin Yang
Summary: An efficient phase inversion-impregnation approach is developed to fabricate BaO-decorated Ni8 mol% YSZ anode-supported tubular solid oxide fuel cells (SOFCs) with anti-coking properties. BaO nanoislands are successfully introduced inside the Ni-YSZ anode, leading to higher peak power densities and improved stability in methane fuel. Density functional theory calculations suggest that the loading of BaO nanoislands facilitates carbon elimination by capturing and dissociating H2O molecules to generate OH.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Suresh Mamidi, Dan Na, Baeksang Yoon, Henu Sharma, Anil D. Pathak, Kisor Kumar Sahu, Dae Young Lee, Cheul-Ro Lee, Inseok Seo
Summary: Li-CO2 batteries, which utilize CO2 and have a high energy density, are hindered in practical applications due to slow kinetics and safety hazards. This study introduces a stable and highly conductive ceramic-based solid electrolyte and a metal-organic framework catalyst to improve the safety and performance of Li-CO2 batteries. The optimized Li-CO2 cell shows outstanding specific capacity and cycle life, and the post-cycling analysis reveals the degradation mechanism of the electrodes. First-principles calculations based on density functional theory are also performed to understand the interactions between the catalyst and the host electrode. This research demonstrates the potential of MOF cathode catalyst for stable operation in Li-CO2 batteries.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Ganghua Xiang, Zhihuan Qiu, Huilong Fei, Zhigang Liu, Shuangfeng Yin, Yuen Wu
Summary: In this study, a CeFeOx-supported Pt single atoms and subnanometric clusters catalyst was developed, which exhibits enhanced catalytic activity and stability for the preferential oxidation of CO in H2-rich stream through synergistic effect.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Dimitrios Chatzogiannakis, Marcus Fehse, Maria Angeles Cabanero, Natalia Romano, Ashley Black, Damien Saurel, M. Rosa Palacin, Montse Casas-Cabanas
Summary: By coupling electrochemical testing to operando synchrotron based X-ray absorption and powder diffraction experiments, blended positive electrodes consisting of LiMn2O4 spinel (LMO) and layered LiNi0.5Mn0.3Co0.2O2 (NMC) were studied to understand their redox mechanism. It was found that blending NMC with LMO can enhance energy density at high rates, with the blend containing 25% LMO showing the best performance. Testing with a special electrochemical setup revealed that the effective current load on each blend component can vary significantly from the nominal rate and also changes with SoC. Operando studies allowed monitoring of the oxidation state evolution and changes in crystal structure, in line with the expected behavior of individual components considering their electrochemical current loads.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Chiara Cementon, Daniel Dewar, Thrinathreddy Ramireddy, Michael Brennan, Alexey M. Glushenkov
Summary: This Perspective discusses the specific power and power density of lithium-ion capacitors, highlighting the fact that their power characteristics are often underestimated. Through analysis, it is found that lithium-ion capacitors can usually achieve power densities superior to electrochemical supercapacitors, making them excellent alternatives to supercapacitors.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Weihao Wang, Hao Yu, Li Ma, Youquan Zhang, Yuejiao Chen, Libao Chen, Guichao Kuang, Liangjun Zhou, Weifeng Wei
Summary: This study achieved an improved electrolyte with excellent low-temperature and high-voltage performance by regulating the Li+ solvation structure and highly concentrating it. The electrolyte exhibited outstanding oxidation potential and high ionic conductivity under low temperature and high voltage conditions, providing a promising approach for the practical application of high-voltage LIBs.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Martin Bures, Dan Gotz, Jiri Charvat, Milos Svoboda, Jaromir Pocedic, Juraj Kosek, Alexandr Zubov, Petr Mazur
Summary: Vanadium redox flow battery is a promising energy storage solution with long-term durability, non-flammability, and high overall efficiency. Researchers have developed a mathematical model to simulate the charge-discharge cycling of the battery, and found that hydraulic connection of electrolyte tanks is the most effective strategy to reduce capacity losses, achieving a 69% reduction.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
M. Rodriguez-Gomez, J. Campo, A. Orera, F. de La Fuente, J. Valenciano, H. Fricke, D. S. Hussey, Y. Chen, D. Yu, K. An, A. Larrea
Summary: In this study, we analysed the operando performance of industrial lead cells using neutron diffraction experiments. The experiments revealed the evolution of different phases in the positive electrode, showed significant inhomogeneity of phase distribution inside the electrode, and estimated the energy efficiency of the cells.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Jiawei Liu, Chenpeng Wang, Yue Yao, Hao Ye, Yinglong Liu, Yingli Liu, Xiaoru Xu, Zhicong Chen, Huazheng Yang, Gang Wu, Libin Lei, Chao Wang, Bo Liang
Summary: The study focuses on utilizing double conductive Ni-pads as anode collectors in micro-tubular solid oxide fuel cells. The simulation results show excellent performance and stability of DCNPs, and also highlight the potential applications in various fields.
JOURNAL OF POWER SOURCES
(2024)
Article
Chemistry, Physical
Yang Wang, Kangjie Zhou, Lang Cui, Jiabing Mei, Shengnan Li, Le Li, Wei Fan, Longsheng Zhang, Tianxi Liu
Summary: This study presents a polyimide sandwiched separator (s-PIF) for improving the cycling stability of Li-metal batteries. The s-PIF separator exhibits superior mechanical property, electrolyte adsorption/retention and ion conductivity, and enables dendrite-free Li plating/stripping process.
JOURNAL OF POWER SOURCES
(2024)