Continuous Pyrolysis Microreactors: Hot Sources with Little Cooling? New Insights Utilizing Cation Velocity Map Imaging and Threshold Photoelectron Spectroscopy

On the absolute photoionization cross section and threshold photoelectron spectrum of two reactive ketenes in lignin valorization: fulvenone and 2-carbonyl cyclohexadienone

(2022) Zeyou Pan et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Low-temperature gas-phase formation of indene in the interstellar medium

(2021) Srinivas Doddipatla et al.   Science Advances

Five Birds with One Stone: Photoelectron Photoion Coincidence Unveils Rich Phthalide Pyrolysis Chemistry

(2021) Jordy Bouwman et al.   JOURNAL OF PHYSICAL CHEMISTRY A

An Aromatic Universe–A Physical Chemistry Perspective

(2021) Ralf I. Kaiser et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Direct Evidence on the Mechanism of Methane Conversion under Non‐oxidative Conditions over Iron‐modified Silica: The Role of Propargyl Radicals Unveiled

(2021) Allen Puente-Urbina et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoelectron Photoion Coincidence Spectroscopy Provides Mechanistic Insights in Fuel Synthesis and Conversion

(2021) Patrick Hemberger et al.   ENERGY & FUELS

Threshold Photoelectron Spectrum of Cyclobutadiene: Comparison with Time-Dependent Wavepacket Simulations

(2021) Lea Bosse et al.   Journal of Physical Chemistry Letters

Threshold photoelectron spectroscopy of iminoborane, HBNH

(2021) Domenik Schleier et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Operando Photoelectron Photoion Coincidence Spectroscopy Unravels Mechanistic Fingerprints of Propane Activation by Catalytic Oxyhalogenation

(2020) Guido Zichittella et al.   Journal of Physical Chemistry Letters

A Free‐Radical Prompted Barrierless Gas‐Phase Synthesis of Pentacene

(2020) Long Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Off the Beaten Path: Almost Clean Formation of Indene from the ortho-Benzyne + Allyl Reaction

(2020) Morgan N. McCabe et al.   Journal of Physical Chemistry Letters

On the Threshold Photoelectron Spectrum of Fulvenone, a Reactive Ketene Derivative in Lignin Valorization

(2020) Patrick Hemberger et al.   CHEMPHYSCHEM

Interstellar Formation of Biorelevant Pyruvic Acid (CH3COCOOH)

(2020) N. Fabian Kleimeier et al.   Chem

Halogen-Dependent Surface Confinement Governs Selective Alkane Functionalization to Olefins

(2019) Guido Zichittella et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Methane Functionalization via Oxyhalogenation over Supported Noble Metal Nanoparticles

(2019) Vladimir Paunovic et al.   ACS Catalysis

Synthesis of Polycyclic Aromatic Hydrocarbons by Phenyl Addition-Dehydrocyclization: The Third Way

(2019) Long Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular mass growth through ring expansion in polycyclic aromatic hydrocarbons via radical–radical reactions

(2019) Long Zhao et al.   Nature Communications

Decomposition of Picolyl Radicals at High Temperature: A Mass Selective Threshold Photoelectron Spectroscopy Study

(2019) Engelbert Reusch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrogen abstraction ratios: A systematic iPEPICO spectroscopic investigation in laminar flames

(2018) Dominik Krüger et al.   COMBUSTION AND FLAME

Boundary-Layer Model to Predict Chemically Reacting Flow within Heated, High-Speed, Microtubular Reactors

(2018) Peter J. Weddle et al.   INTERNATIONAL JOURNAL OF CHEMICAL KINETICS

Radical Thermometers, Thermochemistry, and Photoelectron Spectra: A Photoelectron Photoion Coincidence Spectroscopy Study of the Methyl Peroxy Radical

(2018) Krisztina Voronova et al.   Journal of Physical Chemistry Letters

Dissociative ionisation of adamantane: a combined theoretical and experimental study

(2018) Alessandra Candian et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Kinetics of the a-C3H5 + O2 reaction, investigated by photoionization using synchrotron radiation

(2018) D. Schleier et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

The fate of the OH radical in molecular beam sampling experiments

(2018) Dominik Krüger et al.   PROCEEDINGS OF THE COMBUSTION INSTITUTE

Functional Relationships between Kinetic, Flow, and Geometrical Parameters in a High-Temperature Chemical Microreactor

(2018) M. V. Zagidullin et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Experimental and theoretical investigation of the vibrational band structure of the 1 Πu5−1 Πg5 high-spin system of C2

(2017) P. Bornhauser et al.   JOURNAL OF CHEMICAL PHYSICS

Photodissociation dynamics of the ortho- and para-xylyl radicals

(2017) Kai Pachner et al.   JOURNAL OF CHEMICAL PHYSICS

CRF-PEPICO: Double velocity map imaging photoelectron photoion coincidence spectroscopy for reaction kinetics studies

(2017) Bálint Sztáray et al.   JOURNAL OF CHEMICAL PHYSICS

The HITRAN2016 molecular spectroscopic database

(2017) I.E. Gordon et al.   JOURNAL OF QUANTITATIVE SPECTROSCOPY & RADIATIVE TRANSFER

A vacuum ultraviolet laser pulsed field ionization-photoion study of methane (CH4): determination of the appearance energy of methylium from methane with unprecedented precision and the resulting impact on the bond dissociation energies of CH4 and CH4+

(2017) Yih-Chung Chang et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Advances in threshold photoelectron spectroscopy (TPES) and threshold photoelectron photoion coincidence (TPEPICO)

(2017) Tomas Baer et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Measuring flow profiles in heated miniature reactors with X-ray fluorescence spectroscopy

(2017) Robert S. Tranter et al.   PROCEEDINGS OF THE COMBUSTION INSTITUTE

On the absolute photoionization cross section and dissociative photoionization of cyclopropenylidene

(2016) Fabian Holzmeier et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

An optically accessible pyrolysis microreactor

(2016) J. H. Baraban et al.   REVIEW OF SCIENTIFIC INSTRUMENTS

Electronic spectra of linear HC5H and cumulene carbene H2C5

(2015) Mathias Steglich et al.   JOURNAL OF CHEMICAL PHYSICS

Probing cis-trans isomerization in the S1 state of C2H2 via H-atom action and hot band-pumped IR-UV double resonance spectroscopies

(2015) P. Bryan Changala et al.   JOURNAL OF CHEMICAL PHYSICS

Threshold Photoelectron Spectra of Combustion Relevant C4H5 and C4H7 Isomers

(2015) Melanie Lang et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Threshold photoelectron spectrum of the benzyl radical

(2015) John D. Savee et al.   MOLECULAR PHYSICS

The ionisation energy of cyclopentadienone: a photoelectron–photoion coincidence study

(2015) Thomas K. Ormond et al.   MOLECULAR PHYSICS

Laboratory confirmation of C60+ as the carrier of two diffuse interstellar bands

(2015) E. K. Campbell et al.   NATURE

Assignment of high-lying bending mode levels in the threshold photoelectron spectrum of NH2: a comparison between pyrolysis and fluorine-atom abstraction radical sources

(2015) F. Holzmeier et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

On the formation of cyclopentadiene in the C3H5˙ + C2H2 reaction

(2015) Jordy Bouwman et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Hydrogen Abstraction/Acetylene Addition Revealed

(2014) Dorian S. N. Parker et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Elucidating the Thermal Decomposition of Dimethyl Methylphosphonate by Vacuum Ultraviolet (VUV) Photoionization: Pathways to the PO Radical, a Key Species in Flame-Retardant Mechanisms

(2014) Shuyu Liang et al.   CHEMISTRY-A EUROPEAN JOURNAL

The properties of a micro-reactor for the study of the unimolecular decomposition of large molecules

(2014) Qi Guan et al.   INTERNATIONAL REVIEWS IN PHYSICAL CHEMISTRY

Isomer-Specific Product Detection of Gas-Phase Xylyl Radical Rearrangement and Decomposition Using VUV Synchrotron Photoionization

(2014) Patrick Hemberger et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Chirped-Pulse Fourier Transform Microwave Spectroscopy Coupled with a Flash Pyrolysis Microreactor: Structural Determination of the Reactive Intermediate Cyclopentadienone

(2014) Nathanael M. Kidwell et al.   Journal of Physical Chemistry Letters

Chirped-pulse millimeter-wave spectroscopy for dynamics and kinetics studies of pyrolysis reactions

(2014) Kirill Prozument et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

On the protonation of water

(2014) A. Bodi et al.   Chemical Science

Photoionisation of the tropyl radical

(2013) Kathrin H Fischer et al.   Beilstein Journal of Organic Chemistry

H2CN+ and H2CNH+: New insight into the structure and dynamics from mass-selected threshold photoelectron spectra

(2013) Fabian Holzmeier et al.   JOURNAL OF CHEMICAL PHYSICS

Biomass pyrolysis: Thermal decomposition mechanisms of furfural and benzaldehyde

(2013) AnGayle K. Vasiliou et al.   JOURNAL OF CHEMICAL PHYSICS

Direct Observation of para-Xylylene as the Decomposition Product of the meta-Xylyl Radical Using VUV Synchrotron Radiation

(2013) Patrick Hemberger et al.   Journal of Physical Chemistry Letters

Carbocations Generated under Stable Conditions by Ionization of Matrix-Isolated Radicals: The Allyl and Benzyl Cations

(2013) Vladimir Mišić et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

DELICIOUS III: A multipurpose double imaging particle coincidence spectrometer for gas phase vacuum ultraviolet photodynamics studies

(2013) G. A. Garcia et al.   REVIEW OF SCIENTIFIC INSTRUMENTS

Vibrationally induced inversion of photoelectron forward-backward asymmetry in chiral molecule photoionization by circularly polarized light

(2013) Gustavo A. Garcia et al.   Nature Communications

Unimolecular thermal decomposition of phenol and d5-phenol: Direct observation of cyclopentadiene formation via cyclohexadienone

(2012) Adam M. Scheer et al.   JOURNAL OF CHEMICAL PHYSICS

Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I with O2

(2012) O. Welz et al.   SCIENCE

Thermal Decomposition Mechanisms of the Methoxyphenols: Formation of Phenol, Cyclopentadienone, Vinylacetylene, and Acetylene

(2011) Adam M. Scheer et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Dissociation dynamics of energy-selected acetic acid ions: The gas phase heat of formation of the acetyl ion

(2010) Nicholas S. Shuman et al.   INTERNATIONAL JOURNAL OF MASS SPECTROMETRY

Modeling unimolecular reactions in photoelectron photoion coincidence experiments

(2010) Bálint Sztáray et al.   JOURNAL OF MASS SPECTROMETRY

Self-Consistent Heats of Formation for the Ethyl Cation, Ethyl Bromide, and Ethyl Iodide from Threshold Photoelectron Photoion Coincidence Spectroscopy

(2010) Sampada Borkar et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Threshold Photoelectron Spectroscopy of the Methyl Radical Isotopomers, CH3, CH2D, CHD2and CD3: Synergy between VUV Synchrotron Radiation Experiments and Explicitly Correlated Coupled Cluster Calculations†

(2010) Bárbara K. Cunha de Miranda et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Single-photon and resonance-enhanced multiphoton threshold ionization of the allyl radical

(2009) Michael Gasser et al.   JOURNAL OF CHEMICAL PHYSICS

Heat of Formation of the Allyl Ion by TPEPICO Spectroscopy

(2009) Nicholas S. Shuman et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Photoionization of Three Isomers of the C9H7Radical†

(2009) Patrick Hemberger et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Vibronic Structure of the 3s and 3p Rydberg States of the Allyl Radical†

(2009) Michael Gasser et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Determination of the Absolute Photoionization Cross Sections of CH3and I Produced from a Pyrolysis Source, by Combined Synchrotron and Vacuum Ultraviolet Laser Studies†

(2009) Bérenger Gans et al.   JOURNAL OF PHYSICAL CHEMISTRY A

The B 1B1 State of Cyclopropenylidene, c-C3H2

(2009) Patrick Hemberger et al.   Journal of Physical Chemistry Letters

Vacuum ultraviolet beamline at the Swiss Light Source for chemical dynamics studies

(2009) Melanie Johnson et al.   NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION A-ACCELERATORS SPECTROMETERS DETECTORS AND ASSOCIATED EQUIPMENT

The photoionisation of two phenylcarbenes and their diazirine precursors investigated using synchrotron radiation

(2009) Bastian Noller et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Imaging photoelectron photoion coincidence spectroscopy with velocity focusing electron optics

(2009) Andras Bodi et al.   REVIEW OF SCIENTIFIC INSTRUMENTS

Matrix Isolation and EPR Spectroscopy of Septet 3,5-Difluoropyridyl-2,4,6-trinitrene

(2008) Sergei V. Chapyshev et al.   JOURNAL OF ORGANIC CHEMISTRY

Specific Rate Constantsk(E) of the Dissociation of the Halobenzene Ions: Analysis by Statistical Unimolecular Rate Theories

(2008) William Stevens et al.   JOURNAL OF PHYSICAL CHEMISTRY A

“Imaging” combustion chemistry via multiplexed synchrotron-photoionization mass spectrometry

(2007) Craig A. Taatjes et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS