Journal
JOURNAL OF PHASE EQUILIBRIA AND DIFFUSION
Volume 43, Issue 6, Pages 640-647Publisher
SPRINGER
DOI: 10.1007/s11669-022-00951-y
Keywords
Irreversible transport processes; Thermodynamics; Entropy production; Frame of reference; Onsager relations; Diffusion; Kolrausch's law
Categories
Funding
- Royal Institute of Technology
Ask authors/readers for more resources
The Onsager relations are discussed, suggesting that they should be interpreted in a frame of reference where all transport processes are independent. The concepts are illustrated using isobarothermal diffusion in both simple metallic phases and complex ionic systems. The transformation from a lattice-fixed frame of reference to a number-fixed frame is shown to result in the Kirkendall effect as a cross effect.
The Onsager relations are discussed and it is suggested that they should be interpreted as there is a frame of reference where all the transport processes are independent. The concepts are illustrated with isobarothermal diffusion in simple metallic phases as well as complex ionic systems. A transformation from lattice-fixed frame of reference to number-fixed frame gives the Kirkendall effect as a cross effect.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
