4.7 Article

Facile synthesis of MnO/carbon composites by a single-step nitrate-cellulose combustion synthesis for Li ion battery anode

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 689, Issue -, Pages 931-937

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2016.08.054

Keywords

Li ion battery; Anode; MnO; Composite; Cellulose; Combustion synthesis

Funding

  1. Yashima Environment Technology Foundation
  2. Grants-in-Aid for Scientific Research [15K18325] Funding Source: KAKEN

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In this paper, a novel method is proposed to produce MnO/carbon composites, in which the MnO nanoparticles were embedded into a porous carbon matrix, by a single-step nitrate-cellulose combustion synthesis. The composition, structure and morphology of the composites were characterized by X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, thermogravimetric analysis, and scanning/transmission electron microscopy. The composites were used as lithium ion battery anodes to evaluate their electrochemical properties. The MnO/carbon composite with a proper carbon content showed enhanced cycling performance and capacity retention, which delivered a reversible capacity of 561 mAh g(-1) after 90 cycles at 0.2 A g(-1). The easy production and good electrochemical properties enables the composite to be a possible candidate as an anode alternative for high-performance lithium ion battery. (C) 2016 Elsevier B.V. All rights reserved.

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