4.6 Article

A green composite hydrogel based on xylan and lignin with adjustable mechanical properties, high swelling, excellent UV shielding, and antioxidation properties

Journal

JOURNAL OF APPLIED POLYMER SCIENCE
Volume 139, Issue 28, Pages -

Publisher

WILEY
DOI: 10.1002/app.52520

Keywords

anti-oxidant performance; composite hydrogel; high swelling; UV shielding

Funding

  1. Natural Science Foundation of Shandong [ZR2020MC156]
  2. National Natural Science Foundation of China [31971605, 22108136]
  3. Shandong Key RD Program [2019JZZY010407, 2019JZZY010304]
  4. Special Foundation for National Science and Technology Basic Research Program of China [2019FY100902]
  5. National Key RD Program [2020YFC1910302]

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This study successfully prepared a novel green composite hydrogel with adjustable mechanical properties, high swelling, excellent UV shielding, and antioxidation performance. The addition of lignin significantly improved the mechanical properties and swelling ratio of the hydrogel. Moreover, the hydrogel exhibited excellent UV shielding and antioxidation performance. The use of cost-effective lignin as a raw material and the simplicity of the production process make this hydrogel favorable for medical-biological applications.
This study successfully prepared a novel green composite hydrogel based on carboxymethyl xylan and lignin with adjustable mechanical properties, high swelling, excellent UV shielding, and antioxidation performance. The structure and morphology of the hydrogel were characterized by Fourier transform infrared spectra, scanning electron microscopy, thermogravimetric analysis, rheological analysis, and swelling ratio. Results showed that lignin could significantly improve the mechanical properties of composite hydrogels. The compression stress and toughness of the composite hydrogel contained lignin increased by 39% and 60%, respectively, and the compressive deformation reached 90%. In addition, the addition of lignin increased the swelling ratio of the composite hydrogel reached 79.9 g/g. In addition, the composite hydrogel exhibited excellent UV shielding and antioxidation performance. The removal ratio of UV and free radicals is as high as 80% and 90%, respectively. The simple procedure and cost-effective lignin as raw material for hydrogel with adjustable properties are favorable for medical-biological applications.

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