Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 896, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.162810
Keywords
N-doped C/ZnO composites; Zinc-based acrylate resins; Strong reflection loss; Broad effective absorption bandwidth
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Funding
- National Key Research and Development Project [2019YFC0312101]
- Scientific research project of Sanya Yazhou Bay Science and Technology City Administration [SKJC-2020-01-015]
- Hainan Provincial Key Research and Development Project [ZDYF2021GXJS029]
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This study successfully designed and synthesized N-doped C/ZnO composites using temperature-controllable processing, and achieved the best electromagnetic wave absorption performance by altering the composition and calcination temperature.
The chemical doping of carbon and heteroatoms is expected to be a promising strategy for enhancing the absorption properties of electromagnetic waves. In this work, N-doped C/ZnO composites (CN/ZnOx-Ts) were originally designed and synthesized by using temperature-controllable calcination engineering with zinc-based acrylate resins containing N atoms as precursors. The best electromagnetic wave absorption (EMWA) performance for the composites was obtained by changing the composition and calcination temperature of the acrylate resin precursor. A CN/ZnO0.064-900 composite prepared using a precursor containing acrylonitrile (0.4 mol) and ZnO (0.064 mol) calcined at 900 degrees C showed a minimum reflection loss (RLmin) of - 43.15 dB at 3.0 mm and 9.68 GHz, with an effective absorption bandwidth (EAB) ranging from 5.1 GHz to 18 GHz achieved by adjusting the thickness of the absorber. This method for preparing novel N-doped carbon-based materials provides the possibility for the mass production of highly efficient absorbers. (C) 2021 Published by Elsevier B.V.
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