Article
Chemistry, Physical
Zhiqiang Liu, Aihua Li, Yanling Qiu, Qingyu Zhao, Yuxue Zhong, Liang Cui, Wenrong Yang, Joselito M. Razal, Colin J. Barrow, Jingquan Liu
Summary: In this work, MgCo2O4@NiMn layered double hydroxide core-shell structured nanocomposites on Ni foam are synthesized and exhibit excellent electrochemical performance and potential applications in energy storage devices.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2021)
Article
Energy & Fuels
Yu Tang, Xilong Liu, Yang Chen, Leiyun Han, Dianfeng Dai, Liangyu Liu, Chongtai Wang, Yingjie Hua, Xudong Zhao, Xiaoyang Liu
Summary: This study successfully synthesized NiCo2S4@MoS2 core/shell nanorod arrays and demonstrated their excellent charge storage capacitance and rate performance. The electrode material has high mass loading, can operate at high current density, and exhibits good cycling stability.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Energy & Fuels
Zihao Wang, Kai Zhao, Lei Wang, Miao Tian, Yuesheng Sun, Chunxiao Wang, Xiaolin Sun, Jingquan Liu
Summary: Researchers have successfully constructed hierarchical CuCo2O4@NiMn-layered double hydroxides (CCO@NM-LDH) core-shell heterostructures, which provide a large specific surface area and numerous active sites, improving the capacitive performance of the material. By modulating the reaction time of NiMn-LDH, the CCO@NM-LDH-2 electrode exhibits the best capacitance and retention of capacitance, and the assembled CCO@NM-LDH-2//AC asymmetric supercapacitor (ASC) shows high energy density and power density.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Materials Science, Ceramics
Yaning Guo, Chen Hao, Xiaokun Wang, Ying Yang, Xiaohong Wang, Jingbo Wu, Yutang Shen
Summary: The ternary composite CoNi-Layered Double Hydroxide (LDH)/NiCo2S4/Reduced Graphene Oxide (RGO) was synthesized successfully through simple hydrothermal deposition. The resulting material has a unique structure with dispersed NiCo2S4 nanoparticles and uniform coverage of CoNi-LDH nanowire arrays on the RGO sheet, creating abundant pore structures for rapid transfer of charged particles. The material exhibits high specific capacitance and excellent cycle performance, making it a promising electrode material for all-solid-state asymmetric supercapacitors.
CERAMICS INTERNATIONAL
(2022)
Article
Chemistry, Multidisciplinary
Wenhua Zhao, Xingliang Xu, Niandu Wu, Xiaodie Zhao, Jiangfeng Gong
Summary: Dandelion-like CuCo2O4 nanoflowers with ultrathin NiMn layered double hydroxide shells were fabricated via a two-step hydrothermal method. The prepared CuCo2O4@NiMn LDH core/shell nanoflowers possessed a high specific surface area and exhibited typical battery-type electrode material characteristics. An asymmetric supercapacitor with CuCo2O4@NiMn LDH nanoflowers//activated carbon showed outstanding capacitance and cycling stability.
Article
Chemistry, Physical
Xiaoyu Huang, Yuan Yang, Jialu Zhao, Yin Huang, Xiuhua Wang
Summary: In this study, a dual-core layer hollow structure Co3S4@NiCo2S4 nanocages supercapacitor electrode material was successfully synthesized using an appropriate ion-exchange strategy and subsequent vulcanization treatment of MOFs. The Co3S4@NiCo2S4 electrode exhibited a specific capacitance of 1202 F g-1 at 1 A g-1 and retained 80% of its initial capacity at 10 A g-1. The integrated Co3S4@NiCo2S4//AC asymmetric supercapacitor achieved an energy density of 58 Wh kg-1 at a power density of 750 W kg-1. It also showed a capacitance retention of 81.8% after 10,000 galvanostatic charge-discharge cycles. The individual nanostructure and excellent electrochemical properties of Co3S4@NiCo2S4 nanocages provide a rational strategy for developing high-energy-density supercapacitor electrode materials based on MOFs derivatives.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Energy & Fuels
Yi Jiang, Bin Cai, Ying Yang, Fei Yu, Yilai Sun, Xin Qi, Liying Wang, Xuesong Li, Xijia Yang
Summary: Supercapacitors, as efficient energy storage devices, have demonstrated excellent charge storage capacity and stable cycling performance. In this study, a core-shell structure of NiCoSe2@NiCo-LDH was synthesized and used as electrode material for supercapacitors, showing significantly improved specific capacitance and cycling stability. Furthermore, the NiCoSe2@NiCo-LDH composite and activated carbon materials were assembled into an asymmetric supercapacitor, confirming its potential for practical applications.
JOURNAL OF ENERGY STORAGE
(2022)
Article
Chemistry, Physical
Ge Gao, Kang Wang, Xitao Wang
Summary: Developing high-performance non-precious metal electrocatalysts for the oxygen evolution reaction (OER), particularly for the production of green hydrogen fuel, is highly significant. In this study, ultrathin NiMn LDH nanosheets were grown on FeCo2O4 nanoflakes to form a 2D/2D core/shell structure on a nickel foam (NF) as an effective catalyst for OER. The FeCo2O4 @NiMn LDH/NF electrode exhibited desirable characteristics, such as a small Tafel slope, low overpotential, and good stability, indicating its potential as a promising material for OER.
JOURNAL OF ALLOYS AND COMPOUNDS
(2023)
Article
Energy & Fuels
Xian Huang, Rui Yang, Huiqun Yin, Yiyan Mo, Xiuyan Shi, Wangsheng Li, Shuge Dai, Aimiao Qin, Kaiyou Zhang
Summary: In this study, a composite material of CuO nanowires and NiCo-LDH nanoplates was fabricated using wet chemistry and hydrothermal methods, resulting in a three-dimensional core-shell structure with high specific surface area. The composite exhibited excellent electrochemical performance and bending performance.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Chemistry, Physical
Jinhe Wei, Fei Hu, Xiong Shen, Bingkun Chen, Lin Chen, Zhongming Wang, Chenglong Lv, Qiuyun Ouyang
Summary: The vertically oriented NiCo2S4/MnO2 core-shell nanocomposites, activated by oxygen vacancy engineering, show enhanced electrochemical performance. The hierarchical core-shell nanostructures increase conductivity and provide redox chemical reactions. The NiCo2S4/MnO2-60 electrode delivers appreciable areal capacity and rate capability, and can be used in solid-state hybrid supercapacitors with high energy density and cyclic stability.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Kun Zheng, Leiping Liao, Yu Zhang, Hua Tan, Jingquan Liu, Chenwei Li, Dedong Jia
Summary: A unique hierarchical core/shell homostructure of LDH material with high capacitance, good rate performance, and cyclic stability has been constructed through in-situ growth and conversion process. The designed supercapacitor also exhibits high energy density.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Chemistry, Analytical
Shan Zhao, Yu Zhang, Jiaying Wu, Chengshuang Ling, Xin Tang, Yun Xing, Huimin Yu, Ke Huang, Zhirong Zou, Xiaoli Xiong
Summary: The researchers constructed a structure composed of a loofah-like Co(OH)F and NiMn-LDH composite grown on a cloth substrate using a simple two-step hydrothermal method combined with morphological regulation. The structure exhibits excellent sensing performance in the field of electrochemical detection.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Physical
Sangeeta Adhikari, Gi-Hyeok Noh, Do-Heyoung Kim
Summary: Core-shell designed electrode architectures with favorable material components, specifically FeCo2O4@Ni(OH)2, were successfully grown on a Ni-foam substrate. These core-shell arrays exhibited improved electrochemical performance, with a high specific capacitance of 1944 F g-1 and better performance than individual FeCo2O4 and Ni(OH)2. The improved performance was attributed to the synergistic effects of the core-shell array architectures and enhanced electrical conductivity through electroactive sites.
APPLIED SURFACE SCIENCE
(2023)
Article
Nanoscience & Nanotechnology
Jiahui Zhu, Yan Wang, Xubin Zhang, Wangfeng Cai
Summary: The ZnCo2O4@NiCo2S4@PPy core-shell nanosheets material with a special structure formed by MOF-derived ZnCo2O4, NiCo2S4, and PPy shows enhanced capacitive performance, improved contact between electrode and electrolyte, increased active sites, and accelerated electron/ion transfer. The electrode exhibits excellent areal capacitance, specific capacitance, and capacitance retention rate. Additionally, a coin-type hybrid supercapacitor assembled with this material demonstrates a high energy density and good cycling performance.
Article
Nanoscience & Nanotechnology
Jiahui Li, Lili Wang, Yuying Yang, Bing Wang, Cunpeng Duan, Linlin Zheng, Rulin Li, Yujia Wei, Junqing Xu, Zhen Yin
Summary: The study demonstrates that a multi-metal synergy and rationally designed core-shell structure are critical to the electrochemical performance of bifunctional electrodes.
Article
Chemistry, Inorganic & Nuclear
Leiyun Han, Xilong Liu, Zheng Cui, Yang Chen, Zijia Wang, Yu Tang, Yingjie Hua, Chongtai Wang, Haijiao Xie, Xudong Zhao, Xiaoyang Liu
Summary: In this work, Ni2P@PANI hollow nanotubes were developed as a positive electrode material for supercapacitors using a template-assisted method. The strong interaction between PANI and Ni2P was found to improve the capacitive properties. Additionally, Fe2O3@PNCT hollow nanotubes were used as the negative electrode, implementing a two-in-one strategy. The assembled quasi-solid-state asymmetric supercapacitor exhibited high energy density and cycle stability.
INORGANIC CHEMISTRY FRONTIERS
(2022)
Article
Chemistry, Inorganic & Nuclear
Leiyun Han, Xilong Liu, Zheng Cui, Yingjie Hua, Chongtai Wang, Xudong Zhao, Xiaoyang Liu
Summary: In this study, hierarchical copper cobalt sulfide nanobelt array structures with well-defined morphology control were successfully synthesized as high energy density electrode materials for asymmetric supercapacitors. By controlling the reaction time and sulfide ion concentration during the sulfidation reactions, saturated sulfidation was achieved while maintaining the morphology, structural integrity, and stability of the precursor. The CuCo2S4 electrode exhibited a high specific capacity, excellent cycling stability, and high energy density in an aqueous asymmetric device, showing potential for use in high-performance energy storage devices.
INORGANIC CHEMISTRY FRONTIERS
(2021)
Article
Chemistry, Physical
J. Zamora, T. Bautista, N. S. Portillo-Velez, A. Reyes-Montero, H. Pfeiffer, F. Sanchez-Ochoa, H. A. Lara-Garcia
Summary: Experimental and DFT studies were conducted on the structural, magnetic, and optical properties of RFeO3 perovskites. The perovskites exhibited an orthorhombic crystal structure and weak ferromagnetic behavior. They were confirmed to be semiconductors with a bandgap of approximately 2.1 eV.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xianxiang Lv, Jing Jin, Weiguang Yang
Summary: By depositing TiN and TiO2 surface layers on AlSi films, the electrochemical performance of silicon-based anodes can be significantly improved, suppressing volume expansion and promoting the formation of a stable SEI layer.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Sharafat Ali, Haider Ali, Syedul Hasnain Bakhtiar, Sajjad Ali, Muhammad Zahid, Ahmed Ismail, Pir Muhammad Ismail, Amir Zada, Imran Khan, Huahai Shen, Rizwan Ullah, Habib Khan, Mohamed Bououdina, Xiaoqiang Wu, Fazal Raziq, Liang Qiao
Summary: The construction and optimization of redox-heterojunctions using a bifunctional phosphate as an electron-bridge demonstrated significant improvements in photo catalytic activity, including enhanced dispersion, reduced interfacial migration resistance, and increased abundance of active-sites.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ren-Ni Luan, Na Xu, Chao-Ran Li, Zhi-Jie Zhang, Yu-Sheng Zhang, Jun Nan, Shu-Tao Wang, Yong-Ming Chai, Bin Dong
Summary: Extensive research has revealed that oxygen evolution reaction (OER) in alkaline conditions involves dynamic surface restructuring. The development and design of sulfide/oxide pre-catalysts can reasonably adjust the composition and structure after surface reconstruction, which is crucial for OER. This study utilized a simple two-step hydrothermal method to achieve in situ S leaching and doping, inducing the composition change and structure reconstruction of CoFe oxides. The transformed FeOOH and CoOOH exhibited excellent OER activity and could be easily mass-produced using low-cost iron based materials and simple methods.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jun'an Lai, Daofu Wu, Peng He, Kang An, Yijia Wang, Peng Feng, WeiWei Chen, Zixian Wang, Linfeng Guo, Xiaosheng Tang
Summary: Zero-dimensional organic-inorganic metal halides (OMHs) are gaining attention in the fabrication of light-emitting diodes due to their broad emission band and high photoluminescence quantum yield. This work synthesized a zero-dimensional organic tetraphenylphosphonium bismuth chloride (TBC) that showed efficient blue light emission, with the emission mechanism attributed to the transition of Bi3+ ions. White light-emitting diodes (WLEDs) were fabricated using TBC, along with green-emitting and red-emitting single crystals, achieving single-component white emissions. These findings demonstrate the different emission mechanism of ns2 ions-based OMHs and highlight the potential of bismuth-based OMHs in WLEDs applications.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xuewei Liang, Yunhai Su, Taisen Yang, Zhiyong Dai, Yingdi Wang, Xingping Yong
Summary: The revolutionary design concept of high-entropy alloys has brought new opportunities and challenges to the development of advanced metal materials. In this work, AlCrCuFe2NiTix high-entropy flux cored wires were prepared by combining the design idea of a high-entropy alloy with the characteristics of flux cored wire. AlCr-CuFe2NiTix high-entropy surfacing alloys were prepared using gas metal arc welding technology. The wear properties of the alloys were analyzed, and the phase composition, microstructure, strengthening mechanism, and wear mechanism were discussed. The results show that the alloys exhibit a dendritic microstructure with BCC/B2 + FCC phases. Increasing Ti content leads to the precipitation of Laves phase. The alloys show improved microhardness and wear resistance due to the precipitation of coherent B2 and Laves phases. However, excessive Ti addition results in the increase of Laves phase and reduced wear resistance of the alloys.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
M. Vadivel, M. Senthil Pandian, P. Ramasamy, Qiang Jing, Bo Liu
Summary: This work presents the enhanced photocatalytic and electrochemical performance of g-C3N4 assisted PAA on CoFe2O4 ternary nanocomposites. The incorporation of PAA and g-C3N4 improves the separation efficiency of photogenerated charge carriers, resulting in superior photocatalytic degradation and high specific capacitance values.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Vibhu T. Sivanandan, Ramany Revathy, Arun S. Prasad
Summary: In this study, pure and doped cobalt ferrite nanoparticles were prepared using the sol-gel auto-combustion method with the aid of lemon juice as eco-fuel. The crystal structure, lattice parameter, crystallite size, microstrain, optical parameters, and room temperature magnetic properties of the samples were analyzed. The effect of doping on the magnetic properties was also investigated.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qing Guo, Bowen Zhang, Benzhe Sun, Yang Qi
Summary: This study prepared ZnO films with various nonpolar preferred orientations using conventional chemical bath deposition method and characterized their growth process and mechanism. It was found that the type and concentration of nitrate could control the preferred orientation and surface roughness of ZnO films. Additionally, ZnO films with different preferred orientations exhibited different optical properties.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Chong Zhang, Yan Liu, Zhaoyan Wang, Hang Yang
Summary: In this study, six bimetallic FeCo particles were synthesized via the hydrothermal method at different Fe:Co ratios. The Fe:Co ratio not only modulates the composition of the particles but also influences their structure and magnetic properties. The FeCo alloys showed a transformation from an Fe-based structure to a Co-based structure with increasing Co content. The Fe:Co ratio of 1:1 and 3:1 resulted in particles with the highest and lowest saturation magnetization, respectively.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Jianning Zhang, Jing Li, Yiren Wang, Xiaodong Mao, Yong Jiang
Summary: We conducted a study on the formation of ultra-fine Y-Ti-Ta-O nano-oxides in Ta+B micro-alloyed 13CrWTi-ODS alloys using electron microscopy and first-principles calculations. The Y-Ti-Ta-O nano-oxides were found to be mainly Y2(Ti,Ta)2O7, with an average size of 7 nm and a number density of 6.8 x 1023 m-3. Excess boron was found to enhance the adhesion of some low-sigma grain boundaries but weaken the Fe/Y2Ti2O7 interface, while excess tantalum enhanced the Fe/Y2Ti2O7 interface but caused serious degradation of grain boundaries.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Yirong Fang, Pei Cheng, Hang Yuan, Hao Zhao, Lishu Zhang
Summary: A new composite system of nitrogen-doped reduced graphene oxide and black phosphorus quantum dots has been developed for tumor therapy, showing improved electrochemical properties and stability. The system generates hydrogen peroxide and hydroxyl radical to effectively kill tumor cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Xiufang Qin, Yuanli Ma, Hui Zhang, Ting Zhang, Fang Wang, Xiaohong Xu
Summary: The structure and magnetism of cobalt ferrites after Mn2+-Tb3+ co-doping were studied. Co-doped samples exhibited cubic spinel structure and spherical shape of ferrite nanoparticles. The redistribution of Co2+ and Fe3+ ions between octahedral and tetrahedral sites was observed due to Mn2+-Tb3+ co-doping. The coercivity and magnetization saturation of co-doped samples were significantly improved, leading to a maximum energy product that is 190% higher than that of the un-doped sample.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Ho Yeon Lee, Wonjong Yu, Yoon Ho Lee
Summary: Recently, there has been an increasing interest in developing ultra-fine nanostructured electrodes with extensive reaction areas to enhance the performance and low-temperature operation of solid oxide fuel cells. The use of a refined approach involving co-sputtering metal alloys and oxide targets has demonstrated the feasibility of nano-columnar structures in perovskite-based electrodes, expanding the temperature range of thin film electrodes. This study systematically examines the effects of chamber pressure control in the co-sputtering process and identifies the intricate relationship between sputtering pressure and film structure. By fine-tuning the columnar growth in the electrode, significant improvements in performance and thermo-mechanical properties were achieved, resulting in high-performance all-sputtered solid oxide fuel cells.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)
Article
Chemistry, Physical
Qianyun Bai, Xiaoxiao Yan, Da Liu, Kang Xiang, Xin Tu, Yanhui Guo, Renbing Wu
Summary: This study proposes a simple method to develop a non-precious transition metal-based electrocatalyst with high catalytic activity and robustness for the hydrogen evolution reaction. The as-synthesized electrode exhibits a low overpotential and high current density, indicating its potential in energy conversion.
JOURNAL OF ALLOYS AND COMPOUNDS
(2024)