4.7 Article

High-efficiency removal of benzene vapor using activated carbon from Althaea officinalis L. biomass as a lignocellulosic precursor

Journal

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
Volume 29, Issue 44, Pages 66728-66740

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s11356-022-20579-2

Keywords

Adsorbent; Biomass; Benzene removal; Chemical synthesis; Lignocellulosic precursors

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This study aimed to evaluate the use of biowaste material for the production of activated carbon and its adsorption capacity for benzene vapor. The results showed that activated carbon produced from Althaea officinalis L. biomass had a high surface area and yield, and exhibited good adsorption capacity for benzene. The findings suggest the potential application of low-cost activated carbon produced from waste biomass materials for the removal of airborne pollutants.
Benzene is a primary air pollutant commonly found widespread in the indoor environment. It has always been a research focus on the environment due to the causes of significant human health concerns. It has been widely utilized in the synthesis of solvent production, which can rarely be found in high concentrations in outdoor air or high amounts in indoor air, depending on its sources. It is aimed to remove different initial benzene concentrations (from 5 to 1500 ppm) with the production of activated carbon as an excellent adsorbent with a high surface area to be used in these situations. Lignocellulosic wastes have great potential for activated carbon for their advantages (abundant, recycled, and low-cost materials, etc.). This study aimed to evaluate biowaste material for activated carbon production from Althaea officinalis L. biomass by chemical activation (H2SO4, LiOH, and ZnCL2) at temperatures between 500 and 900 degrees C. Newly developed powdered activated carbons (AoACs) are also tabulated as Ao-AC1-45 for easy reference. Benzene vapor was collected into Tenax TA (R) tubes by automatic thermal desorption in conjunction with a capillary gas chromatography-mass spectrometry (TD-GC/MS). The significant surface area and production yield of Ao-ACs were obtained at 1424 m(2)/g (Ao-AC43) and up to 40.32%, respectively. The maximum gas-phase benzene adsorption capacity was 140 mg/g at 270 min. This research has focused on adsorption gasphase benzene removal onto Ao-ACs as a low-cost adsorbent from the Althaea officinalis L. biomass. Conspicuously, more study is needed to perform the enhanced adsorption of airborne pollutants capacity with inexpensive activated carbon from waste biomass materials.

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