4.7 Article

Sono-photo hybrid process for the synergistic degradation of levofloxacin by FeVO4/BiVO4: Mechanisms and kinetics

Journal

ENVIRONMENTAL RESEARCH
Volume 204, Issue -, Pages -

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.envres.2021.112032

Keywords

Sonophotocatalysis; Synergistic effect; FeVO4; BiVO4 heterojunction; Levofloxacin; Sono-photo hybrid process

Funding

  1. National Natural Science Foundation of China [51778146]
  2. Outstanding Youth Fund of Fujian Province in China [2018J06013]
  3. Open Project Program of National Engineering Research Center for Environmental Photocatalysis [NERCEP-201901]
  4. Open Fund of Fujian Key Laboratory of Electrochemcial Energy Storage Materials [2021CN08]

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A novel FeVO4/BiVO4 heterojunction photocatalyst was synthesized and characterized, showing better degradation efficiency for levofloxacin than other methods and maintained stability after 5 cycles. The study proposed a potential application of sono-photo hybrid process in wastewater treatment field.
A novel FeVO4/BiVO4 heterojunction photocatalyst was synthesized by hydrothermal method. The FeVO4/BiVO4 nanostructures were characterized by XRD, SEM, XPS, UV-vis, and photoluminescence spectroscopy. The effects of catalyst dosage, contaminant concentration, initial hydrogen peroxide (H2O2) concentration, and pH value on the degradation of levofloxacin were investigated and several repeated experiments were conducted to evaluate the stability and reproducibility. The optimized process parameters were used for mineralization experiments. Reactive oxygen species, degradation intermediates, and possible catalytic mechanisms were also investigated. The results showed that the sonophotocatalytic performance of the FeVO4/BiVO4 heterojunction catalyst was better than that of sonocatalysis and photocatalysis. In addition, the Type II heterojunction formed by the material still had good stability in the degradation of levofloxacin after 5 cycles. The possible degradation pathway and mechanism of levofloxacin by sonophotocatalysis were put forward. This work develops new sono-photo hybrid process for potential application in the field of wastewater treatment.

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