4.6 Article

Cerium-Based, Intermetallic-Strengthened Aluminum Casting Alloy: High-Volume Co-product Development

Journal

JOM
Volume 68, Issue 7, Pages 1940-1947

Publisher

SPRINGER
DOI: 10.1007/s11837-016-1943-9

Keywords

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Funding

  1. Critical Materials Institute, an Energy Innovation Hub - U.S. Department of Energy, Office of Energy Efficiency and Renewable Energy, Advanced Manufacturing Office
  2. U.S. Department of Energy
  3. Lawrence Livermore National Laboratory [DE-AC52-07NA27344]
  4. Oak Ridge National Laboratory under U.S. Department of Energy [DE-AC05-00OR22725]
  5. Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy [DE-AC02-05CH11231]
  6. Oak Ridge National Laboratory Directed Research and Development funds

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Several rare earth elements are considered by-products to rare earth mining efforts. By using one of these by-product elements in a high-volume application such as aluminum casting alloys, the supply of more valuable rare earths can be globally stabilized. Stabilizing the global rare earth market will decrease the long-term criticality of other rare earth elements. The low demand for Ce, the most abundant rare earth, contributes to the instability of rare earth extraction. In this article, we discuss a series of intermetallic-strengthened Al alloys that exhibit the potential for new high-volume use of Ce. The castability, structure, and mechanical properties of binary, ternary, and quaternary Al-Ce based alloys are discussed. We have determined Al-Ce based alloys to be highly castable across a broad range of compositions. Nanoscale intermetallics dominate the microstructure and are the theorized source of the high ductility. In addition, room-temperature physical properties appear to be competitive with existing aluminum alloys with extended high-temperature stability of the nanostructured intermetallic.

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