Catalytic lignin valorisation by depolymerisation, hydrogenation, demethylation and hydrodeoxygenation: mechanism, chemical reaction kinetics and transport phenomena

Mass Transport Limitations and Kinetic Consequences of Corn Stover Deacetylation

(2022) Nicholas E. Thornburg et al.   Frontiers in Energy Research

Modelling the kraft pulping process on a fibre scale by considering the intrinsic heterogeneous nature of the lignocellulosic feedstock

(2022) Nicolaus Bijok et al.   CHEMICAL ENGINEERING JOURNAL

Assessment of a detailed biomass pyrolysis kinetic scheme in multiscale simulations of a single-particle pyrolyzer and a pilot-scale entrained flow pyrolyzer

(2021) Xi Gao et al.   CHEMICAL ENGINEERING JOURNAL

Bridging Scales in Bioenergy and Catalysis: A Review of Mesoscale Modeling Applications, Methods, and Future Directions

(2021) Peter N. Ciesielski et al.   ENERGY & FUELS

The Promotor and Poison Effects of the Inorganic Elements of Kraft Lignin during Hydrotreatment over NiMoS Catalyst

(2021) Joby Sebastian et al.   Catalysts

Pore-scale investigation on multiphase reactive transport for the conversion of levulinic acid to γ-valerolactone with Ru/C catalyst

(2021) Xiangqian Wei et al.   CHEMICAL ENGINEERING JOURNAL

High-solid ethylenediamine pretreatment to fractionate new lignin streams from lignocellulosic biomass

(2021) Li Xu et al.   CHEMICAL ENGINEERING JOURNAL

Hydrogen solubility equilibria in bio-based Guaiacol or Levulinic acid/water mixture as lignin or cellulose depolymerization model solutions

(2021) Ljudmila Fele Zilnik et al.   FLUID PHASE EQUILIBRIA

Catalytic Lignin Depolymerization to Aromatic Chemicals

(2020) Chaofeng Zhang et al.   ACCOUNTS OF CHEMICAL RESEARCH

A sustainable wood biorefinery for low–carbon footprint chemicals production

(2020) Yuhe Liao et al.   SCIENCE

Mesoscale Reaction–Diffusion Phenomena Governing Lignin‐First Biomass Fractionation

(2020) Nicholas E. Thornburg et al.   ChemSusChem

Kinetics of Secondary Reactions Affecting Organosolv Lignin Structure

(2020) James R. Meyer et al.   ChemSusChem

Unlocking Structure−Reactivity Relationships for Catalytic Hydrogenolysis of Lignin into Phenolic Monomers

(2020) Ling-Ping Xiao et al.   ChemSusChem

Product‐oriented direct cleavage of chemical linkages in lignin: A review

(2020) Xiaojun Shen et al.   ChemSusChem

Recent Advances in the Catalytic Depolymerization of Lignin towards Phenolic Chemicals: A Review

(2020) Xudong Liu et al.   ChemSusChem

Development of ‘Lignin-First’ Approaches for the Valorization of Lignocellulosic Biomass

(2020) Tamás I. Korányi et al.   MOLECULES

Acid-catalysed α-O-4 aryl-ether bond cleavage in methanol/(aqueous) ethanol: understanding depolymerisation of a lignin model compound during organosolv pretreatment

(2020) Edita Jasiukaitytė-Grojzdek et al.   Scientific Reports

Hydrodeoxygenation of Lignin-Derived Aromatic Oxygenates Over Pd-Fe Bimetallic Catalyst: A Mechanistic Study of Direct C–O Bond Cleavage and Direct Ring Hydrogenation

(2020) Jianghao Zhang et al.   CATALYSIS LETTERS

High-quality and phenolic monomer-rich bio-oil production from lignin in supercritical ethanol over synergistic Ru and Mg-Zr-oxide catalysts

(2020) Susan Olivia Limarta et al.   CHEMICAL ENGINEERING JOURNAL

The cornerstone of realizing lignin value-addition: Exploiting the native structure and properties of lignin by extraction methods

(2020) Danlian Huang et al.   CHEMICAL ENGINEERING JOURNAL

Kinetic modeling of the continuous hydrothermal base catalyzed depolymerization of pine wood based kraft lignin in pilot scale

(2020) Justin J. Bernhardt et al.   INDUSTRIAL CROPS AND PRODUCTS

Kraft Lignin Solubility and Its Chemical Modification in Deep Eutectic Solvents

(2020) Filipe H. B. Sosa et al.   ACS Sustainable Chemistry & Engineering

Improved conversion efficiency of Lignin-to-Fuel conversion by limiting catalyst deactivation

(2020) Tianyu Ren et al.   CHEMICAL ENGINEERING JOURNAL

Hydrogen solubility in bio-based furfural and furfuryl alcohol at elevated temperatures and pressures relevant for hydrodeoxygenation

(2020) Gorica Ivaniš et al.   FUEL

Multi-scale simulation of reaction, transport and deactivation in a SBA-16 supported catalyst for the conversion of ethanol to butadiene

(2019) Vivek S. Bharadwaj et al.   CATALYSIS TODAY

Reductive catalytic fractionation: state of the art of the lignin-first biorefinery

(2019) Tom Renders et al.   CURRENT OPINION IN BIOTECHNOLOGY

Catalytic depolymerization of organosolv lignin to phenolic monomers and low molecular weight oligomers

(2019) Xudong Liu et al.   FUEL

Breaking the Limit of Lignin Monomer Production via Cleavage of Interunit Carbon–Carbon Linkages

(2019) Lin Dong et al.   Chem

Hydrodeoxygenation of isoeugenol over Ni-SBA-15: Kinetics and modelling

(2019) Sebastiano Tieuli et al.   APPLIED CATALYSIS A-GENERAL

Kinetic modeling of lignin catalytic hydroconversion in a semi-batch reactor

(2019) Junjie Pu et al.   CHEMICAL ENGINEERING JOURNAL

Reaction Kinetics and Characterization of Species in Renewable Crude from Hydrothermal Liquefaction of Mixtures of Polymer Compounds To Represent Organic Fractions of Biomass Feedstocks

(2019) Reem Obeid et al.   ENERGY & FUELS

A Review on Lignin Liquefaction: Advanced Characterization of Structure and Microkinetic Modeling

(2019) Evan Terrell et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Recent advances in oxidative valorization of lignin

(2018) Ruoshui Ma et al.   CATALYSIS TODAY

Controllable production of guaiacols and phenols from lignin depolymerization using Pd/C catalyst cooperated with metal chloride

(2018) Riyang Shu et al.   CHEMICAL ENGINEERING JOURNAL

Catalytic hydrogenation and hydrodeoxygenation of lignin-derived model compound eugenol over Ru/C: Intrinsic microkinetics and transport phenomena

(2018) Ana Bjelić et al.   CHEMICAL ENGINEERING JOURNAL

Bright Side of Lignin Depolymerization: Toward New Platform Chemicals

(2018) Zhuohua Sun et al.   CHEMICAL REVIEWS

Chemicals from lignin: an interplay of lignocellulose fractionation, depolymerisation, and upgrading

(2018) W. Schutyser et al.   CHEMICAL SOCIETY REVIEWS

Coupled Structural and Kinetic Model of Lignin Fast Pyrolysis

(2018) Abraham J. Yanez et al.   ENERGY & FUELS

Promising bulk production of a potentially benign bisphenol A replacement from a hardwood lignin platform

(2018) S.-F. Koelewijn et al.   GREEN CHEMISTRY

An uncondensed lignin depolymerized in the solid state and isolated from lignocellulosic biomass: a mechanistic study

(2018) Ning Li et al.   GREEN CHEMISTRY

Solubility and fractionation of Indulin AT kraft lignin in ethanol-water media

(2018) Werner Marcelo Goldmann et al.   SEPARATION AND PURIFICATION TECHNOLOGY

Kinetic Studies of Lignin Solvolysis and Reduction by Reductive Catalytic Fractionation Decoupled in Flow-Through Reactors

(2018) Eric M. Anderson et al.   ACS Sustainable Chemistry & Engineering

Kinetics of Hydrothermal Furfural Production from Organosolv Hemicellulose and D-Xylose

(2018) Jakob Köchermann et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Catalytic Hydrogenation, Hydrodeoxygenation, and Hydrocracking Processes of a Lignin Monomer Model Compound Eugenol over Magnetic Ru/C–Fe2O3 and Mechanistic Reaction Microkinetics

(2018) Ana Bjelić et al.   Catalysts

Comparison of kinetics and activity of Ni-based catalysts for benzyl phenyl ether catalytic hydrogenolysis

(2018) Chen Zhu et al.   Energy Technology

Catalytic Upgrading of Biomass Model Compounds: Novel Approaches and Lessons Learnt from Traditional Hydrodeoxygenation - a Review

(2018) Wei Jin et al.   ChemCatChem

The multi-scale challenges of biomass fast pyrolysis and bio-oil upgrading: Review of the state of art and future research directions

(2018) Mahdi Sharifzadeh et al.   PROGRESS IN ENERGY AND COMBUSTION SCIENCE

Hydrogenation and hydrodeoxygenation of aromatic lignin monomers over Cu/C, Ni/C, Pd/C, Pt/C, Rh/C and Ru/C catalysts: Mechanisms, reaction micro-kinetic modelling and quantitative structure-activity relationships

(2018) A. Bjelić et al.   CHEMICAL ENGINEERING JOURNAL

Lignin-first biomass fractionation: the advent of active stabilisation strategies

(2017) T. Renders et al.   Energy & Environmental Science

Phenolic acetals from lignins of varying compositions via iron(iii) triflate catalysed depolymerisation

(2017) Peter J. Deuss et al.   GREEN CHEMISTRY

Lignin transformations for high value applications: towards targeted modifications using green chemistry

(2017) S. Gillet et al.   GREEN CHEMISTRY

Enhanced Solubility of Lignin Monomeric Model Compounds and Technical Lignins in Aqueous Solutions of Deep Eutectic Solvents

(2017) Belinda Soares et al.   ACS Sustainable Chemistry & Engineering

Mathematical Modeling of Fast Biomass Pyrolysis and Bio-Oil Formation. Note I: Kinetic Mechanism of Biomass Pyrolysis

(2017) Eliseo Ranzi et al.   ACS Sustainable Chemistry & Engineering

Catalytic hydroprocessing of lignin β-O-4 ether bond model compound phenethyl phenyl ether over ruthenium catalysts

(2017) B. Gomez-Monedero et al.   Biomass Conversion and Biorefinery

Lignin Valorization through Catalytic Lignocellulose Fractionation: A Fundamental Platform for the Future Biorefinery

(2016) Maxim V. Galkin et al.   ChemSusChem

A Stochastic Method to Generate Libraries of Structural Representations of Lignin

(2016) Abraham J. Yanez et al.   ENERGY & FUELS

Application of a detailed biomass pyrolysis kinetic scheme to hardwood and softwood torrefaction

(2016) Andrés Anca-Couce et al.   FUEL

A Review of Kinetic Modeling Methodologies for Complex Processes

(2016) Luís P. de Oliveira et al.   Oil & Gas Science and Technology-Revue d IFP Energies nouvelles

The synthesis and analysis of lignin-bound Hibbert ketone structures in technical lignins

(2016) Daniel M. Miles-Barrett et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Two-Step, Catalytic C–C Bond Oxidative Cleavage Process Converts Lignin Models and Extracts to Aromatic Acids

(2016) Min Wang et al.   ACS Catalysis

Phenomena Affecting Catalytic Reactions at Solid–Liquid Interfaces

(2016) Carsten Sievers et al.   ACS Catalysis

Catalytic depolymerisation of isolated lignin to fine chemicals: part 2 – process optimisation

(2016) Ashley McVeigh et al.   Catalysis Science & Technology

High-Resolution Particle-Scale Simulation of Biomass Pyrolysis

(2016) Qingang Xiong et al.   ACS Sustainable Chemistry & Engineering

Estimation of Heat Transfer Coefficients for Biomass Particles by Direct Numerical Simulation Using Microstructured Particle Models in the Laminar Regime

(2016) M. Brennan Pecha et al.   ACS Sustainable Chemistry & Engineering

Catalytic hydrodeoxygenation and hydrocracking of Alcell ® lignin in alcohol/formic acid mixtures using a Ru/C catalyst

(2015) Arjan Kloekhorst et al.   BIOMASS & BIOENERGY

Kinetic model of homogeneous lignocellulosic biomass solvolysis in glycerol and imidazolium-based ionic liquids with subsequent heterogeneous hydrodeoxygenation over NiMo/Al2O3 catalyst

(2015) M. Grilc et al.   CATALYSIS TODAY

Conversion of Lignin to Phenol-Rich Oil Fraction under Supercritical Alcohols in the Presence of Metal Catalysts

(2015) Jae-Young Kim et al.   ENERGY & FUELS

Automatic Mechanism and Kinetic Model Generation for Gas- and Solution-Phase Processes: A Perspective on Best Practices, Recent Advances, and Future Challenges

(2015) Ruben Van de Vijver et al.   INTERNATIONAL JOURNAL OF CHEMICAL KINETICS

Ab Initio Screening Approach for the Discovery of Lignin Polymer Breaking Pathways

(2015) Brendan D. Mar et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Catalytic Hydrotreatment of Alcell Lignin Using Supported Ru, Pd, and Cu Catalysts

(2015) Arjan Kloekhorst et al.   ACS Sustainable Chemistry & Engineering

Heterogeneous Catalyst Deactivation and Regeneration: A Review

(2015) Morris Argyle et al.   Catalysts

Application of Solubility Parameter Theory to Organosolv Extraction of Lignin from Enzymatically Hydrolyzed Cornstalks

(2014) Yueyuan Ye et al.   BioResources

Lignin depolymerisation strategies: towards valuable chemicals and fuels

(2014) Chunping Xu et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Depolymerization of Lignin in Supercritical Ethanol

(2014) Xiaoming Huang et al.   ChemSusChem

Biomass Particle Models with Realistic Morphology and Resolved Microstructure for Simulations of Intraparticle Transport Phenomena

(2014) Peter N. Ciesielski et al.   ENERGY & FUELS

Kinetic Modelling of Hydrothermal Lignin Depolymerisation

(2014) Daniel Forchheim et al.   Waste and Biomass Valorization

Dry torrefaction of biomass – Torrefied products and torrefaction kinetics using the distributed activation energy model

(2013) A. Sarvaramini et al.   CHEMICAL ENGINEERING JOURNAL

Hydrodeoxygenation of 4-Propylguaiacol (2-Methoxy-4-propylphenol) in a Microreactor: Performance and Kinetic Studies

(2013) Narendra Joshi et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Single-Event MicroKinetics: Catalyst design for complex reaction networks

(2013) J.W. Thybaut et al.   JOURNAL OF CATALYSIS

Fluid flow and convective heat transfer to fluids at supercritical pressure

(2013) J.D. Jackson   NUCLEAR ENGINEERING AND DESIGN

A pore-hindered diffusion and reaction model can help explain the importance of pore size distribution in enzymatic hydrolysis of biomass

(2012) Jeremy S. Luterbacher et al.   BIOTECHNOLOGY AND BIOENGINEERING

Modeling the Lignin Degradation Kinetics in a Ethanol/Formic Acid Solvolysis Approach. Part 2. Validation and Transfer to Variable Conditions

(2012) Daniel Forchheim et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Reaction Kinetics of the Lignin Conversion in Supercritical Water

(2012) Tau Len-Kelly Yong et al.   INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH

Heterogeneous studies in pulping of wood: Modelling mass transfer of dissolved lignin

(2011) João P.F. Simão et al.   CHEMICAL ENGINEERING JOURNAL

Modelling intra-particle phenomena of biomass pyrolysis

(2011) Anthony Dufour et al.   CHEMICAL ENGINEERING RESEARCH & DESIGN

Towards Quantitative Catalytic Lignin Depolymerization

(2011) Virginia. M. Roberts et al.   CHEMISTRY-A EUROPEAN JOURNAL

Computational Study of Bond Dissociation Enthalpies for a Large Range of Native and Modified Lignins

(2011) Seonah Kim et al.   Journal of Physical Chemistry Letters

Theoretical Study of the Remarkably Diverse Linkages in Lignin

(2011) R. Parthasarathi et al.   Journal of Physical Chemistry Letters

Hydrodeoxygenation of guaiacol with CoMo catalysts. Part I: Promoting effect of cobalt on HDO selectivity and activity

(2010) Van Ngoc Bui et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Hydrodeoxygenation of guaiacol

(2010) Van Ngoc Bui et al.   APPLIED CATALYSIS B-ENVIRONMENTAL

Organosolv extraction of lignin from hydrolyzed almond shells and application of the δ-value theory

(2010) Joaquín Quesada-Medina et al.   BIORESOURCE TECHNOLOGY

Detailed kinetic modeling of the thermal degradation of lignins

(2009) T. Faravelli et al.   BIOMASS & BIOENERGY