Carbon-coated mesoporous silicon shell-encapsulated silicon nano-grains for high performance lithium-ion batteries anode

Silicon is considered to be a promising anode material because of its higher theoretical specific capacity. However, the huge volume change in cycles leads to a severe pulverization of active silicon and thus rapid capacity fade. Herein, to address this issue, we report a novel hollow-structured Si/C (HeSiNS/C) nanocomposite fabricated via a simple, facile approach. In the composite, lots of tiny Si nano-grains are encapsulated by a thin mesoporous Si shell, which is further coated by a carbon layer. The mesoporous Si shell with abundant internal voids can effectively accommodate the volume changes and relieve the mechanical stress during repeated (de)lithiation processes. Besides, the carbon layer can function as the hard physical-mechanical support to further confine the internal Si shell expansion/contraction, guaranteeing the whole particle structural integrity. Moreover, the conductive framework constructed by the carbon layer favors the electrode reaction kinetics as well as the uniform volume variation of Si. As a result, the HeSiNS/C nanocomposite displays a high reversible capacity (0.1 A g(-1): similar to 1670 mAh g(-1)), an excellent rate capability (2 A g(-1): >1150 mAh g(-1)) with a high average Coulombic efficiency (similar to 99.8%), and a superior cycling stability. (C) 2022 Elsevier Ltd. All rights reserved.

Automated summary

In this study, a novel hollow-structured Si/C nanocomposite was developed to address the issue of volume change and capacity fade in silicon anode materials. The composite, consisting of tiny Si nano-grains encapsulated by a mesoporous Si shell and coated with a carbon layer, exhibited high reversible capacity, excellent rate capability, and superior cycling stability.