4.5 Article

Underwater gas self-transportation along femtosecond laser-written open superhydrophobic surface microchannels (<100 μm) for bubble/gas manipulation

Journal

Publisher

IOP Publishing Ltd
DOI: 10.1088/2631-7990/ac466f

Keywords

femtosecond laser; gas transportation; superhydrophobicity; underwater superaerophilicity; water; gas separation

Funding

  1. National Science Foundation of China [61875158, 61805192]
  2. National Key Research and Development Program of China [2017YFB1104700]
  3. International Joint Research Laboratory for Micro/Nano Manufacturing and Measurement Technologies
  4. Fundamental Research Funds for the Central Universities

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In this study, we report a method to achieve self-transportation of gas in water through laser-induced superhydrophobic microchannels. This technique has potential applications in manipulating gas at the microscopic level.
Underwater transportation of bubbles and gases has essential applications in manipulating and using gas, but achieving this function at the microscopic level remains a significant challenge. Here, we report a strategy to self-transport gas in water along a laser-induced open superhydrophobic microchannel with a width less than 100 mu m. The femtosecond laser can directly write superhydrophobic and underwater superaerophilic microgrooves on the polytetrafluoroethylene (PTFE) surfaces. In water, the single laser-induced microgroove and water medium generate a hollow microchannel. When the microchannel connects two superhydrophobic regions in water, the gas spontaneously travels from the small region to the large area along this hollow microchannel. Gas self-transportation can be extended to laser-drilled microholes through a thin PTFE sheet, which can even achieve anti-buoyancy unidirectional penetration. The gas can overcome the bubble's buoyance and spontaneously travel downward. The Laplace pressure difference drives the processes of spontaneous gas transportation and unidirectional bubble passage. We believe the property of gas self-transportation in the femtosecond laser-structured open superhydrophobic and underwater superaerophilic microgrooves/microholes has significant potential applications related to manipulating underwater gas.

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