4.7 Article

Acid-Doped Biopolymer Nanocoatings for Flame-Retardant Polyurethane Foam

Journal

ACS APPLIED POLYMER MATERIALS
Volume 4, Issue 3, Pages 1983-1990

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsapm.1c01843

Keywords

flame retardant; polyelectrolyte complex; polyurethane foam; acid-doped; bio-based

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Soft furnishing fires contribute to a significant percentage of fire causalities and property damage in the United States annually. A study found that adding acid salts can improve the flame retardancy of polyurethane foam in soft furnishings and significantly reduce the risk of fires.
Soft furnishing fires contribute to 29% of fire causalities and $8.7 billion in direct property damage annually in the United States. Polyurethane foam (PUF), a common component in soft furnishings known for its comfort and flexibility, can emit toxic gases and propagate fires due to melt dripping when ignited. Various acid salts were added to a layer-by-layer assembled nanocoating, consisting of chitosan and carboxymethyl cellulose, to improve PUF flame retardancy and to understand the influence of salt-doping on flammability. The 20-bilayer phosphoric acid-doped coating exhibits a self-extinguishing behavior, with a 67% reduction in peak heat release rate while maintaining the structural integrity of the foam. By depositing this completely environmentally sourced coating on PUF, the inherent danger of soft furnishing fires can be significantly reduced in a nontoxic manner.

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