4.7 Article

Expanded Polytetrafluoroethylene/Mxene Nanosheet Composites with Hydrophilicity and Lipophilicity for Purification of Oil Spills and Wastewater

Journal

ACS APPLIED NANO MATERIALS
Volume 5, Issue 2, Pages -

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsanm.1c04166

Keywords

nanosheet composites; expanded polytetrafluoroethylene (ePTFE); Mxene; water/oil purification; oil absorption; oil spill and recovery

Funding

  1. National Center for International Research of Micro-Nano Molding Technology of Zhengzhou University in China
  2. Key Science & Technology Project for Institutions of Higher Education of Henan Province [19A430003]
  3. Zhengzhou Major Scientific and Technological Innovation Project [2020CXZX0057]

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In this study, ePTFE/Mxene nanosheet composites with nanoscale double pore structures were constructed, which improved the hydrophilicity, oil absorption capacity, and oil-water separation performance of the material. The ePTFE/Mxene composites showed potential for practical applications in oil spill remediation and water separation/remediation.
The frequent occurrence of oil leaks and air pollution has had devastating and long-term impacts on the aquatic environment. Therefore, it is urgent to effectively address water sources and environments polluted by oil leaks. In this study, expanded polytetrafluoroethylene (ePTFE)/Mxene nanosheet composites with nanoscale double pore structures were constructed by combining PTFE particles with Mxene nanosheets, which improved the hydrophilicity, oil absorption capacity, and oil-water separation performance of the material, which relied on the degree of expansion and the Mxene content. The composition of the ePTFE/Mxene composites was confirmed by Fourier transform infrared spectroscopy, and the microstructure and morphology of the composites were examined by scanning electron microscopy. Oil and water contact angle tests showed that the ePTFE/Mxene composites have good hydrophilicity and lipophilicity. Oil absorption tests showed that ePTFE/ Mxene has good oil absorption capacity and reusability. Due to their amphiphilic nature and their efficient oil absorption capacities, the ePTFE/Mxene nanosheet composites with dual pore structures exhibited good potential for practical applications in oil spill remediation and water separation/remediation.

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