Journal
ACS APPLIED NANO MATERIALS
Volume 4, Issue 11, Pages 12335-12345Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acsanm.1c02816
Keywords
SnxPy/RGO; rational design; multiphase synergistic effect; lithium storage mechanism; reaction dynamics
Funding
- National Natural Science Foundation of China [51872162, 11890700]
- Key R&D Innovation Program of Shandong Province-Major Innovation Project [2019TSLH0116]
Ask authors/readers for more resources
The tin phosphide nanoplate with multiphase grown on reduced graphene oxide (SnxPy/RGO) was synthesized through the phosphorization process, with different structures obtained by controlling the heating rate and phosphorus source. The multiphase synergistic effect improved the structural stability of SnxPy/RGO and promoted the reversibility of conversion reactions, leading to superior lithium and sodium storage capacities with great cyclability.
To obtain high reversible capacity and long-term cycling performance in Sn-based phosphide anodes for lithium-/sodium-ion batteries (LIBs/SIBs), the tin phosphide nanoplate with the multiphase grown on reduced graphene oxide (SnxPy/RGO) has been synthesized through the phosphorization process. SnP0.94/RGO and SnxPy/RGO can be accurately obtained by controlling the heating rate and the amount of the phosphorus source. Benefiting from the multiphase synergistic effect, the structural stability of SnxPy/RGO was improved, along with the high reversibility of conversion reactions in Sn4P3 being promoted. As a result, the SnxPy/RGO electrode delivers a superior Li storage capacity (713.5 mA h g(-1) after 1400 cycles at 2.0 A g(-1)), which demonstrates the greatest cyclability reported so far on Sn-based phosphide anodes for LIBs, and a superior Na storage capacity (421.8 mA h g(-1) after 100 cycles at 500 mA g(-1)). The multiphase hybrid design strategy can promote the practical application of Sn-based phosphides in LIBs/SIBs or catalysis.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available