4.7 Article

Thermal runaway as a new high-performance method of desorption of hydrogen from hydrides

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 41, Issue 33, Pages 14813-14819

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2016.07.050

Keywords

Thermal runaway; Hydride; Hydrogen desorption; Kinetic parameter; Gravimetric capacity

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In this investigation by experiments, it was proved that the thermal runaway can be used as a new high-performance method of desorption of hydrogen from metal-hydrides. On its kinetic and thermodynamic parameters, this method is considerably superior to requirements established by US Department of Energy for onboard hydrogen storage systems. For its processing, the thermal runaway does not require any certain temperature or pressure. It can work at any temperature and pressure of ambiance. The hydrogen desorption by the method of the thermal runaway runs with aid of electrochemical reactions. This is why this process is easily controllable by electrotechnical methods and hence it is far less inertial than the thermal processes used in the traditional thermochemical method of the hydrogen desorption from the metal-hydrides. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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