Article
Chemistry, Multidisciplinary
Guixiang Xu, Xin Zhang, Shuyang Sun, Yangfan Zhou, Yongfeng Liu, Hangwang Yang, Zhenguo Huang, Fang Fang, Wenping Sun, Zijiang Hong, Mingxia Gao, Hongge Pan
Summary: A novel high-performance tricomponent composite solid electrolyte (CSE) comprising LLZTO-4LiBH(4)/xLi(3)BN(2)H(8) with ultrafast room-temperature ionic conductivity and ultrahigh Li-ion transference number was prepared by ball milling and hand milling. The electrolyte pellets exhibited low open porosity and high intrinsic ionic conductivity, resulting in excellent cycling stability and low overpotential in Li|Li symmetrical cells and Li|CSE|TiS2 full cells.
Review
Chemistry, Physical
Laiqiang Xu, Jiayang Li, Wentao Deng, Honglei Shuai, Shuo Li, Zhifeng Xu, Jinhui Li, Hongshuai Hou, Hongjian Peng, Guoqiang Zou, Xiaobo Ji
Summary: This article discusses the importance of all-solid-state lithium batteries in the field of energy storage, explores the challenges faced by garnet-type solid electrolytes, and proposes prospective developments and alternative approaches to solving the issues of solid-state electrolytes.
ADVANCED ENERGY MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Yushi Fujita, Atsushi Sakuda, Yuki Hasegawa, Minako Deguchi, Kota Motohashi, Ding Jiong, Hirofumi Tsukasaki, Shigeo Mori, Masahiro Tatsumisago, Akitoshi Hayashi
Summary: All-solid-state lithium-sulfur (Li/S) batteries show high capacities and long cycle lives. This study develops a Li2S-Li2O-LiI positive electrode with an active material dispersed in an amorphous matrix. The electrode exhibits high charge-discharge capacities and a high specific capacity at a 2 C rate and 25 degrees C, with nanoscale ion-conduction pathways provided by Li2O-LiI. Furthermore, a cell with a high areal capacity is successfully operated using this positive electrode.
Review
Chemistry, Multidisciplinary
Jinghua Wu, Sufu Liu, Fudong Han, Xiayin Yao, Chunsheng Wang
Summary: All-solid-state lithium batteries (ASSLBs) are considered the next generation electrochemical energy storage devices due to their high safety and energy density, along with simple packaging and wide operable temperature range. The sulfide electrolytes, with the highest ionic conductivity among solid-state electrolytes, face challenges such as narrow electrochemical stability window, unstable electrode/electrolyte interfaces, and lithium dendrite formation. Research on emerging sulfide electrolytes and preparation methods is ongoing, focusing on achieving required properties for stable electrochemical performance and compatible interfaces in ASSLBs.
ADVANCED MATERIALS
(2021)
Article
Chemistry, Multidisciplinary
Hoang Long Nguyen, Van Tung Luu, Manh Cuong Nguyen, Sung Hoon Kim, Quoc Hung Nguyen, Nungu Israel Nungu, Yun-Seok Jun, Wook Ahn
Summary: All-solid-state Li batteries (ASSLBs) are limited in their application due to their narrow operating temperature range, low ionic conductivity, poor stability, and complex production process. In this study, a simple method combining various battery candidates was employed to solve these limitations and a solid polymer electrolyte with high conductivity and excellent cycling stability was successfully prepared.
ADVANCED FUNCTIONAL MATERIALS
(2022)
Article
Chemistry, Multidisciplinary
Vittorio Marangon, Luca Minnetti, Edoardo Barcaro, Jusef Hassoun
Summary: A solid polymer electrolyte with high ionic conductivity and compatibility with different cathode materials has been developed and used in solid-state lithium-metal batteries. The electrolyte shows excellent electrochemical stability, minimal overvoltage, and low interphase resistance. The cells demonstrate reversible operation at room temperature and high capacity for various cathodes. This electrolyte has potential for application in room-temperature solid polymer cells.
CHEMISTRY-A EUROPEAN JOURNAL
(2023)
Article
Engineering, Environmental
Pingping Chen, Qinghui Zeng, Qingyuan Li, Ruihua Zhao, Zhenfeng Li, Xin Wen, Wen Wen, Yu Liu, Anqi Chen, Zengxi Li, Xiangfeng Liu, Liaoyun Zhang
Summary: In this study, a ketone-containing PAAA-based polymer electrolyte is designed and prepared for the first time, showing excellent ionic conductivity and mechanical integrity. By incorporating reduction-tolerant PEO polymer electrolytes as interlayers, hierarchical polymer electrolytes with wide electrochemical windows are developed to match high-voltage cathodes. This research enriches carbonyl-based polymer electrolytes and provides guidance for designing high-performance polymer electrolytes for practical applications.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Chemistry, Multidisciplinary
Chujun Zheng, Yan Lu, Qiang Chang, Zhen Song, Tongping Xiu, Jun Jin, Michael E. Badding, Zhaoyin Wen
Summary: A multifunctional composite interlayer is designed to promote interfacial Li+ transport and suppress detrimental lithium dendrites in solid-state lithium metal batteries. The interlayer consists of a scalable elastic skeleton and a photocrosslinkable polymer, which enhance Li+ migration and diffusion. In addition, the inclusion of perfluoropolyether helps regulate the formation of a LiF-rich interface, effectively suppressing the growth of lithium dendrites. The interlayer significantly improves the interfacial performance of the solid electrolyte/lithium interface and enhances the electrochemical performance of solid-state lithium metal batteries.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Review
Chemistry, Physical
Shulian Li, Weifeng Zhang, Jiafen Zheng, Mengyuan Lv, Huiyu Song, Li Du
Summary: Lithium-sulfur batteries have high theoretical specific capacity, but face challenges such as the polysulfide shuttle effect. To address this issue, researchers have developed functional coatings inhibiting the migration of polysulfides and solid-state electrolytes.
ADVANCED ENERGY MATERIALS
(2021)
Review
Engineering, Environmental
Qi Yang, Nanping Deng, Yixia Zhao, Lu Gao, Bowen Cheng, Weimin Kang
Summary: Replacing liquid electrolytes with all-solid-state electrolytes using one-dimensional materials has shown promise in improving the performance of lithium-ion batteries and lithium-sulfur batteries. This review provides a comprehensive overview of the preparation methods and applications of one-dimensional materials in electrolytes and electrodes, highlighting their benefits in enhancing ionic conductivity, reducing lithium dendrite growth, and improving electrode-electrolyte contact.
CHEMICAL ENGINEERING JOURNAL
(2023)
Review
Chemistry, Multidisciplinary
Shufeng Song, Ning Hu, Li Lu
Summary: This article introduces the development of solid-state Li/Na-metal batteries and the challenges and solutions for solid electrolytes. It discusses the synthetic approaches for garnet-type and NASICON-type electrolytes, the sintering strategy for dense nano-grained NASICON-type electrolytes, and the advancement of polymeric electrolytes.
CHEMICAL COMMUNICATIONS
(2022)
Article
Chemistry, Multidisciplinary
Tongjie Liu, Lenin W. Kum, Deependra Kumar Singh, Jitendra Kumar
Summary: The next generation of ASLIBs based on SSEs is closest to commercialization. Understanding their safety behavior in real-life situations is necessary for their commercialization. Preliminary evidence shows improved resistance to shorting at high temperatures, reduced heat generation, tolerable harmful gas generation, and high-voltage charge stability in SSE-ASLIBs compared to LE-LIBs. Additionally, SSEs can induce a fast and effective battery shut-down capability in ASLIBs, avoiding thermal runaway.
Review
Chemistry, Physical
Venkataraman Thangadurai, Bowen Chen
Summary: This paper pays tribute to Prof. John B. Goodenough on his 100th birthday and highlights his contributions to solid-state ionics in the early stages. The paper focuses on the development of advanced Li and Na batteries based on solid-state electrolytes, discussing their safety, high energy density, and design flexibility. It also explores the challenges of lower ionic conductivity and poor interface compatibility in most solid-state electrolytes and discusses attempts to improve these aspects through hybrid electrolytes and interfacial engineering methods.
CHEMISTRY OF MATERIALS
(2022)
Article
Chemistry, Physical
Yushi Fujita, Takashi Hakari, Minako Deguchi, Yusuke Kawasaki, Hirofumi Tsukasaki, Shigeo Mori, Masahiro Tatsumisago, Atsushi Sakuda, Akitoshi Hayashi
Summary: Lithium sulfur batteries are promising due to their high energy densities. This study investigates the charge-discharge mechanism of a Li2S-LiI solid solution in all-solid-state batteries, achieving high reversible capacity. The formation of an ionic conductive structure rich in LiI enables nearly fully solid phase S/Li2S reactions in all-solid-state batteries.
ACS APPLIED ENERGY MATERIALS
(2022)
Article
Chemistry, Physical
Mengxue He, Xia Li, Xiaofei Yang, Changhong Wang, Matthew Liu Zheng, Ruying Li, Pengjian Zuo, Geping Yin, Xueliang Sun
Summary: A novel electrolyte has been proposed in this study to effectively eliminate the shuttle effect in lithium-sulfur batteries, resulting in stable cycling performance. By utilizing a solid-phase reaction route and forming a compact cathode electrolyte interface film, the developed strategy shows promise for future development of Li-S batteries based on solid-phase conversion.
ADVANCED ENERGY MATERIALS
(2021)
Article
Engineering, Biomedical
Braden M. Li, Brandon L. Reese, Katherine Ingram, Mary E. Huddleston, Meghan Jenkins, Allison Zaets, Matthew Reuter, Matthew W. Grogg, M. Tyler Nelson, Ying Zhou, Beomjun Ju, Busra Sennik, Zachary J. Farrell, Jesse S. Jur, Christopher E. Tabor
Summary: This study presents a method of spray coating liquid metal nanoparticle systems onto textiles to create flexible and robust electrodes. The resulting electrodes, known as TILEs, exhibit comparable sensing capabilities and skin-electrode impedance to commercial wet electrodes, while also providing improved wearability. The biocompatibility of TILEs in a skin environment is demonstrated, and they outperform previously reported textile-based dry electrodes in terms of sensing performance.
ADVANCED HEALTHCARE MATERIALS
(2022)
Article
Chemistry, Physical
Yali Wang, Ruihui Gan, Sa Zhao, Wenjun Ma, Xiangwu Zhang, Yan Song, Chang Ma, Jingli Shi
Summary: This study developed a cost-effective and efficient bifunctional electrocatalyst for oxygen reduction and oxygen evolution reactions. The catalyst exhibited impressive performance and small potential gap due to the synergistic effect of B, N, and F heteroatoms, large specific surface area, and abundant defect sites. The liquid and solid-state zinc-air batteries assembled with the catalyst demonstrated high open circuit potential, large specific capacity, and satisfactory cycling stability, indicating potential application in flexible and wearable electronic devices.
APPLIED SURFACE SCIENCE
(2022)
Article
Materials Science, Textiles
Yi Xu, Kuanjun Fang, Weichao Chen, Xiangwu Zhang, Chunming Zhang
Summary: This paper presents a new clean production technology that combines atmospheric pressure plasma jets and nano-chitosan to improve the inkjet printing performance of antimicrobial silk fabrics. The results show that the plasma-chitosan treatment enhances the hydrophilicity of the silk surfaces, improves the antibleeding property and color fixation, and increases the antibacterial durability. The treated fabrics also demonstrate excellent inkjet printing effect even after multiple cycles of washing.
FIBERS AND POLYMERS
(2022)
Article
Chemistry, Physical
Chengbiao Wei, Yulan Han, Hao Liu, Ruihui Gan, Wenjun Ma, Haihui Liu, Yan Song, Xiangwu Zhang, Jingli Shi, Chang Ma
Summary: This study integrates sulfiphilic defective TiO2 nanoparticles into a lithiophilic N-doped porous carbon nanofiber membrane to construct an interlayer for catalyzing the conversion of lithium polysulfides. The resulting structure exhibits excellent cycling stability and specific capacity.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2022)
Article
Engineering, Environmental
Xu Han, Lei Chen, Meltem Yanilmaz, Xiaojie Lu, Ke Yang, Kairui Hu, Yong Liu, Xiangwu Zhang
Summary: Due to their rich, versatile, sustainable and inexpensive properties, cellulose-based materials show great prospects in improving the electrochemical performance and durability of zinc batteries by inhibiting zinc corrosion, preventing dendrite growth, providing greater mechanical properties, improving ionic conductivity and catalyzing chemical conversions.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Nanoscience & Nanotechnology
Nakarin Subjalearndee, Nanfei He, Hui Cheng, Panpanat Tesatchabut, Priew Eiamlamai, Somruthai Phothiphiphit, Orapan Saensuk, Pimpa Limthongkul, Varol Intasanta, Wei Gao, Xiangwu Zhang
Summary: This study investigates the fabrication of graphene oxide (GO) and manganese dioxide (MnO2) composite fibers and their application as fiber cathodes in Zn-ion batteries. The study examines the effects of MnO2 micromorphology and mass loading on the properties of the resulting composite fibers. The researchers find that thermal annealing under an argon atmosphere is the most effective method to avoid MnO2 dissolution and leaching.
ACS APPLIED MATERIALS & INTERFACES
(2023)
Review
Chemistry, Multidisciplinary
Yabin Zhang, Xiaohu Xia, Kaikai Ma, Gang Xia, Maoqi Wu, Yuk Ha Cheung, Hui Yu, Bingsuo Zou, Xiangwu Zhang, Omar K. Farha, John H. Xin
Summary: This feature article provides a comprehensive review of research activities in functional textiles with smart properties, discussing their fabrication, diverse functionality, and sustainable applications. The article highlights the potential of these evolved textiles for extensive applications in areas such as environmental monitoring, personal protection, and wearable power supply.
ADVANCED FUNCTIONAL MATERIALS
(2023)
Article
Energy & Fuels
Rui Wang, Mengmeng Zhu, Xiangwu Zhang, Hoang Pham
Summary: This study focuses on lithium-ion batteries and proposes a two-phase capacity degradation model with a dynamic change point, determined by binary segmentation. Uncertainties are considered using particle filtering to predict the remaining useful life (RUL) of batteries. Experimental results show that the proposed framework outperforms existing models in RUL prediction.
JOURNAL OF ENERGY STORAGE
(2023)
Article
Chemistry, Physical
Lei Chen, Yehui Yuan, Raphael Orenstein, Meltem Yanilmaz, Jin He, Jian Liu, Yong Liu, Xiangwu Zhang
Summary: Lithium-sulfur batteries, as promising next-generation energy storage devices, have a higher theoretical capacity and energy density compared to lithium-ion batteries. Carbon materials, with their adjustable structure and functionality, are well suited for building flexible components of lithium-sulfur batteries.
ENERGY STORAGE MATERIALS
(2023)
Article
Chemistry, Physical
Yi Liu, Chunxing Li, Chao Li, Zhenye Liang, Xueshan Hu, Hao Liu, Ze Zhang, Meng Cui, Gang Chen, Jiayu Wan, Xiangwu Zhang, Jinsong Tao
Summary: Traditional polyolefin-based separators have poor thermal stability and weak electrolyte wettability. In this study, a unique hydroxyapatite/cellulose nanofiber hybrid separator was fabricated using hydroxyapatite and cellulose nanofibers as raw materials. The hybrid separators showed excellent thermal properties, outstanding flame retardancy, and improved electrolyte wettability, resulting in better performance of the lithium-ion batteries.
ACS APPLIED ENERGY MATERIALS
(2023)
Review
Materials Science, Multidisciplinary
Xinwang Cao, Chang Ma, Lei Luo, Lei Chen, Hui Cheng, Raphael Simha Orenstein, Xiangwu Zhang
Summary: The addition of nanofiber materials to Li-ion batteries has been a significant advancement, as it provides unique structural features and enhances their electrochemical performance. This article discusses recent advancements in nanofiber materials for Li-ion batteries, including the synthesis, structure, and properties of nanofiber cathodes, anodes, separators, and electrolytes, as well as their applications. The challenges and prospects of nanofiber materials in Li-ion battery applications are also outlined.
ADVANCED FIBER MATERIALS
(2023)
Article
Chemistry, Physical
Lei Chen, Kairui Hu, Ke Yang, Meltem Yanilmaz, Xu Han, Yong Liu, Xiangwu Zhang
Summary: This study proposes a novel carbon fiber-based current collector for flexible zinc ion batteries (ZIBs). By modifying the properties of carbon fibers through activation and etching, a carbonized polypyrrole (CPPy) nanowire conductive network is constructed. This enables high energy storage in ZIBs. Experimental results demonstrate excellent cycle stability and specific capacity of the battery.
Article
Materials Science, Multidisciplinary
Yanmei Jin, Zhiquan Ai, Yan Song, Xiangwu Zhang, Jingli Shi, Chang Ma
Summary: In this work, hierarchical porous Si/C composite nanofibers with carbon coating and hollow Si/SiOx embedded (C-Si-CNF) were fabricated by hydrothermal deposition of polydopamine on electrospun Si/C nanofibers, followed by pyrolysis. The C-Si-CNF electrode exhibited high capacity, good rate performance, and excellent cycling stability, showing great potential as a binder-free and self-supporting anode for lithium-ion battery.
MATERIALS RESEARCH BULLETIN
(2023)
Article
Chemistry, Applied
Ruihui Gan, Yali Wang, Xiangwu Zhang, Yan Song, Jingli Shi, Chang Ma
Summary: In this study, a silica-assisted method was used to integrate numerous accessible edge Fe-Nx sites into porous graphitic carbon, achieving highly active and robust oxygen electrocatalysis. The Fe-N-G material exhibited a half-wave potential of 0.859 V in ORR and an overpotential of 344 mV at 10 mA cm-2 in OER. This work provides a novel strategy to obtain high-efficiency bifunctional oxygen electrocatalysts through space mediation.
JOURNAL OF ENERGY CHEMISTRY
(2023)
Article
Chemistry, Physical
Orkun Furat, Donal P. Finegan, Zhenzhen Yang, Matthias Neumann, Sangwook Kim, Tanvir R. Tanim, Peter Weddle, Kandler Smith, Volker Schmidt
Summary: The operating temperature has a significant impact on the degradation behavior of batteries. This study investigates the structural degradation of lithium-ion positive electrodes under different operating temperatures, and finds that particle porosity increases with higher cycling temperature, while particle surface area remains similar across different cycling-temperature aging conditions.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Junyan Li, Ming Lu, Weijia Zheng, Wei Zhang
Summary: MXenes are two-dimensional materials with unique structures and properties, which have attracted significant scientific interest. Ion intercalation, as an important mechanism, plays a crucial role in regulating the electronic and chemical properties of MXene materials. This review provides an overview of the interaction events between ions and MXenes, including advanced characterization techniques, influencing factors, mechanisms, and functionalization roles of ion intercalation.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Zhengtai Zha, Tianjiang Sun, Diantao Li, Tao Ma, Weijia Zhang, Zhanliang Tao
Summary: A novel zwitterion additive is developed to improve the electrochemical performance and cycling stability of aqueous zinc batteries. The zwitterion forms a stable solid electrolyte interphase on the electrode surface, isolating the zinc anode from the electrolytes and enabling fast zinc ion migration. The proposed electrolyte shows promising results in symmetric cells and full cells, with long cycling stability and high capacity retention.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Nyung Joo Kong, Myeong Seon Kim, Jae Hyun Park, Jongbok Kim, Jungho Jin, Hyun-Wook Lee, Seok Ju Kang
Summary: Polymeric conducting binders have significant research value as they can serve as both binders and conducting agents, increasing the proportion of active materials in batteries and the volumetric energy density. This study explores the potential of a composite of PEDOT:PSS and polyethylene glycol (PEG) as a high-performing binder for silicon anodes. The addition of PEG polymer enhances the conductivity of PEDOT:PSS and improves the mechanical properties of the silicon anode, resulting in extended cycle endurance. The use of operando optical microscopy allows for direct observation of the binder's operation. Consequently, the bifunctional PEDOT:PSS/PEG binder shows promise for high-performance lithium-ion battery binders.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Yangze Huang, Lixuan Zhang, Jiawen Ji, Chenyang Cai, Yu Fu
Summary: This study proposed a novel temperature-dependent viscoelastic liquid electrolyte and a hollow transition bi-metal selenide as the sulfur host material to address the issues in Li-S batteries. The experiments showed promising results in stabilizing the anode and improving cycling performance.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Ao Yu, Wei Zhang, Nimanyu Joshi, Yang Yang
Summary: This review provides a comprehensive overview of research progress in ZIB anodes, including protective coating layers on zinc surfaces and intercalated anode materials. By designing protective coating layers and selecting appropriate intercalated anode materials, the inherent limitations of zinc metal anode can be overcome, leading to improved reliability and performance of ZIBs.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Xin Wang, Yumiao Tian, Konghua Yang, Chenhui Ma, Wenqiang Lu, Xiaofei Bian, Nan Chen, Heng Jiang, Yan Li, Xing Meng, Pengyue Gao, Dong Zhang, Fei Du
Summary: Researchers developed a new sandwich deposition approach using boron nitride layer as a current collector, which enhances the performance of aqueous zinc-ion batteries.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Sang Jun Lee, Dongwoo Kang, Dong Yeol Hyeon, Dong Seok Kim, Suyoon Eom, Su Hwan Jeong, Dong Park Lee, Dawon Baek, Jou-Hyeon Ahn, Gyeong Hee Ryu, Kwi-Il Park, San Moon, Joo-Hyung Kim
Summary: This study utilizes the ice-templating method to create a self-supporting three-dimensional hierarchical porous structure, which effectively inhibits sodium dendrite growth and improves the performance and longevity of sodium-metal batteries.
ENERGY STORAGE MATERIALS
(2024)
Article
Chemistry, Physical
Yifan Yu, Meng Lei, Yangyang Liu, Keyi Chen, Chuanzhong Lai, Jiulin Hu, Chilin Li
Summary: Metal fluorides as conversion-reaction cathodes have advantages such as low cost, environmentally friendly, and high energy density. In this study, a hydroxyl-rich copper fluoride (Cu2(OH)3F) was proposed as a conversion cathode, coupled with an electrolyte additive engineering, to address the poor reversibility issue. The presence of OH in Cu2(OH)3F enables effective suppression of Cu+ dissolution, resulting in better reaction reversibility and kinetics.
ENERGY STORAGE MATERIALS
(2024)