Uniting biological and chemical strategies for selective CO2 reduction

Ligand Field Inversion as a Mechanism to Gate Bioorganometallic Reactivity: Investigating a Biochemical Model of Acetyl CoA Synthase Using Spectroscopy and Computation

(2021) Effie C. Kisgeropoulos et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Importance of Acid–Base Equilibria in Bicarbonate Electrolytes for CO2 Electrochemical Reduction and CO Reoxidation Studied on Au(hkl) Electrodes

(2021) Giulia Marcandalli et al.   LANGMUIR

Tuning the Microenvironment in Gas-Diffusion Electrodes Enables High-Rate CO2 Electrolysis to Formate

(2021) Zhuo Xing et al.   ACS Energy Letters

Inhibiting the Hydrogen Evolution Reaction (HER) with Proximal Cations: A Strategy for Promoting Selective Electrocatalytic Reduction

(2021) Jeffrey M. Barlow et al.   ACS Catalysis

Electric Fields at Metal–Surfactant Interfaces: A Combined Vibrational Spectroscopy and Capacitance Study

(2020) Sohini Sarkar et al.   JOURNAL OF PHYSICAL CHEMISTRY B

First-Principles Calculations on Ni,Fe-Containing Carbon Monoxide Dehydrogenases Reveal Key Stereoelectronic Features for Binding and Release of CO2 to/from the C-Cluster

(2020) Raffaella Breglia et al.   INORGANIC CHEMISTRY

Electrocatalytic Volleyball: Rapid Nanoconfined Nicotinamide Cycling for Organic Synthesis in Electrode Pores

(2019) Clare Megarity et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Thermodynamic Considerations for Optimizing Selective CO2 Reduction by Molecular Catalysts

(2019) Jeffrey M. Barlow et al.   ACS Central Science

A Biochemical Nickel(I) State Supports Nucleophilic Alkyl Addition: A Roadmap for Methyl Reactivity in Acetyl Coenzyme A Synthase

(2019) Anastasia C. Manesis et al.   INORGANIC CHEMISTRY

Modulating the mechanism of electrocatalytic CO2 reduction by cobalt phthalocyanine through polymer coordination and encapsulation

(2019) Yingshuo Liu et al.   Nature Communications

Modulating the Electrode–Electrolyte Interface with Cationic Surfactants in Carbon Dioxide Reduction

(2019) Soumyodip Banerjee et al.   ACS Catalysis

Interplay of Homogeneous Reactions, Mass Transport, and Kinetics in Determining Selectivity of the Reduction of CO2 on Gold Electrodes

(2019) Benjamin A. Zhang et al.   ACS Central Science

Acid-Assisted Hydrogenation of CO2 to Methanol in a Homogeneous Catalytic Cascade System

(2019) Wan-Yi Chu et al.   ACS Catalysis

Reversible and Selective CO2 to HCO2 − Electrocatalysis near the Thermodynamic Potential

(2019) Drew W. Cunningham et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mono- and dinuclear Ni(i) products formed upon bromide abstraction from the Ni(i) ring-expanded NHC complex [Ni(6-Mes)(PPh3)Br]

(2018) William J. M. Blackaby et al.   DALTON TRANSACTIONS

Sequential catalysis controls selectivity in electrochemical CO2 reduction on Cu

(2018) Yanwei Lum et al.   Energy & Environmental Science

Activation of Co(I) State in a Cobalt-Dithiolato Catalyst for Selective and Efficient CO2 Reduction to CO

(2018) Subal Dey et al.   INORGANIC CHEMISTRY

Polymeric coatings for applications in electrocatalytic and photoelectrosynthetic fuel production

(2018) B. L. Wadsworth et al.   Journal of Materials Chemistry A

Improved Electrocatalytic CO2 Reduction with Palladium bis(NHC) Pincer Complexes Bearing Cationic Side Chains

(2018) Emile E. DeLuca et al.   ORGANOMETALLICS

Directing the reactivity of metal hydrides for selective CO2 reduction

(2018) Bianca M. Ceballos et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Molybdenum and tungsten-containing formate dehydrogenases: Aiming to inspire a catalyst for carbon dioxide utilization

(2017) Luisa B. Maia et al.   INORGANICA CHIMICA ACTA

Multielectron Chemistry within a Model Nickel Metalloprotein: Mechanistic Implications for Acetyl-CoA Synthase

(2017) Anastasia C. Manesis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrocatalytic CO2 Reduction by Imidazolium-Functionalized Molecular Catalysts

(2017) Siyoung Sung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Controlling Proton Delivery through Catalyst Structural Dynamics

(2016) Allan Jay P. Cardenas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Capture of CO2 from Ambient Air

(2016) Eloy S. Sanz-Pérez et al.   CHEMICAL REVIEWS

Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion

(2016) Iban Azcarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration

(2016) Min Liu et al.   NATURE

Electric Field Effects in Electrochemical CO2 Reduction

(2016) Leanne D. Chen et al.   ACS Catalysis

How the [NiFe4S4] Cluster of CO Dehydrogenase Activates CO2and NCO−

(2015) Jochen Fesseler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrochemical, Spectroscopic, and Density Functional Theory Characterization of Redox Activity in Nickel-Substituted Azurin: A Model for Acetyl-CoA Synthase

(2015) Anastasia C. Manesis et al.   INORGANIC CHEMISTRY

Spectroscopic and Kinetic Properties of the Molybdenum-containing, NAD+-dependent Formate Dehydrogenase fromRalstonia eutropha

(2015) Dimitri Niks et al.   JOURNAL OF BIOLOGICAL CHEMISTRY

Investigations by Protein Film Electrochemistry of Alternative Reactions of Nickel-Containing Carbon Monoxide Dehydrogenase

(2015) Vincent C.-C. Wang et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Hydrogens detected by subatomic resolution protein crystallography in a [NiFe] hydrogenase

(2015) Hideaki Ogata et al.   NATURE

Standard electrode potentials involving radicals in aqueous solution: inorganic radicals (IUPAC Technical Report)

(2015) David A. Armstrong et al.   PURE AND APPLIED CHEMISTRY

Structure, Function, and Mechanism of the Nickel Metalloenzymes, CO Dehydrogenase, and Acetyl-CoA Synthase

(2014) Mehmet Can et al.   CHEMICAL REVIEWS

Bioinorganic modeling chemistry of carbon monoxide dehydrogenases: description of model complexes, current status and possible future scopes

(2014) Amit Majumdar   DALTON TRANSACTIONS

Protonation of Nickel–Iron Hydrogenase Models Proceeds after Isomerization at Nickel

(2014) Mioy T. Huynh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Interconversion of CO2 and Formate by a Molybdenum-Containing Formate Dehydrogenase

(2014) Arnau Bassegoda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pendant Acid–Base Groups in Molecular Catalysts: H-Bond Promoters or Proton Relays? Mechanisms of the Conversion of CO2 to CO by Electrogenerated Iron(0)Porphyrins Bearing Prepositioned Phenol Functionalities

(2014) Cyrille Costentin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

(2013) Aaron M. Appel et al.   CHEMICAL REVIEWS

Energy and environment policy case for a global project on artificial photosynthesis

(2013) Thomas A. Faunce et al.   Energy & Environmental Science

Understanding Trends in the Electrocatalytic Activity of Metals and Enzymes for CO2 Reduction to CO

(2013) Heine A. Hansen et al.   Journal of Physical Chemistry Letters

A Metal–Metal Bond in the Light-Induced State of [NiFe] Hydrogenases with Relevance to Hydrogen Evolution

(2013) Mario Kampa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Elucidation of the Selectivity of Proton-Dependent Electrocatalytic CO2 Reduction by fac-Re(bpy)(CO)3Cl

(2013) John A. Keith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Cations on the Electrochemical Conversion of CO2to CO

(2012) Michael R. Thorson et al.   JOURNAL OF THE ELECTROCHEMICAL SOCIETY

Carbon Monoxide Dehydrogenase Reaction Mechanism: A Likely Case of Abnormal CO2Insertion to a Ni−H−Bond

(2011) Patricia Amara et al.   INORGANIC CHEMISTRY

Cascade Catalysis for the Homogeneous Hydrogenation of CO2to Methanol

(2011) Chelsea A. Huff et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A dinuclear nickel complex modeling of the Nid(ii)-Nip(i) state of the active site of acetyl CoA synthase

(2010) Tsuyoshi Matsumoto et al.   DALTON TRANSACTIONS

Two Separate One-Electron Steps in the Reductive Activation of the A Cluster in Subunit β of the ACDS Complex inMethanosarcina thermophila†

(2008) Simonida Gencic et al.   BIOCHEMISTRY

Binuclear Complexes Containing a Methylnickel Moiety: Relevance to Organonickel Intermediates in Acetyl Coenzyme A Synthase Catalysis

(2008) William G. Dougherty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY