A comparison of RAFT and ATRP methods for controlled radical polymerization

PET-RAFT Polymerization: Mechanistic Perspectives for Future Materials

(2021) Michael L. Allegrezza et al.   ACS Macro Letters

100th Anniversary of Macromolecular Science Viewpoint: Achieving Ultrahigh Molecular Weights with Reversible Deactivation Radical Polymerization

(2020) Zesheng An   ACS Macro Letters

A Simple and Versatile Method for the Construction of Nearly Ideal Polymer Networks

(2020) Xin Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

p‐Substituted Tris(2‐pyridylmethyl)amines as Ligands for Highly Active ATRP Catalysts: Facile Synthesis and Characterization

(2020) Krzysztof Matyjaszewski et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom Transfer Radical Polymerization of Acrylic and Methacrylic Acids: Preparation of Acidic Polymers with Various Architectures

(2020) Francesca Lorandi et al.   ACS Macro Letters

Ultrahigh Molecular Weight Hydrophobic Acrylic and Styrenic Polymers through Organic-Phase Photoiniferter-Mediated Polymerization

(2020) R. Nicholas Carmean et al.   ACS Macro Letters

Chemical recycling to monomer for an ideal, circular polymer economy

(2020) Geoffrey W. Coates et al.   Nature Reviews Materials

Tailoring Polymer Dispersity by RAFT Polymerization: A Versatile Approach

(2020) Richard Whitfield et al.   Chem

Monodisperse Macromolecules by Self-Interrupted Living Polymerization

(2020) Marian N. Holerca et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Toward Electrochemically Mediated Reversible Addition–Fragmentation Chain-Transfer (eRAFT) Polymerization: Can Propagating Radicals Be Efficiently Electrogenerated from RAFT Agents?

(2019) Francesca Lorandi et al.   MACROMOLECULES

Mechanistically Guided Predictive Models for Ligand and Initiator Effects in Copper-Catalyzed Atom Transfer Radical Polymerization (Cu-ATRP)

(2019) Cheng Fang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Solution processable liquid metal nanodroplets by surface-initiated atom transfer radical polymerization

(2019) Jiajun Yan et al.   Nature Nanotechnology

Tuning Dispersity by Photo-Induced ATRP: Monomodal Distributions with ppm Copper Concentration

(2019) Richard Whitfield et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Effect of solvents on the RAFT polymerization of N-(2-hydroxypropyl) methacrylamide

(2019) Xiangyu Pan et al.   EUROPEAN POLYMER JOURNAL

Exploitation of the Nanoreactor Concept for Efficient Synthesis of Multiblock Copolymers via MacroRAFT-Mediated Emulsion Polymerization

(2019) Glenn K. K. Clothier et al.   ACS Macro Letters

A Versatile 3D and 4D Printing System through Photocontrolled RAFT Polymerization

(2019) Zhiheng Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A pH-responsive nanoparticle targets the neurokinin 1 receptor in endosomes to prevent chronic pain

(2019) Paulina D. Ramírez-García et al.   Nature Nanotechnology

Block Copolymer Sequence Inversion through Photoiniferter Polymerization

(2019) Charles P. Easterling et al.   ACS Macro Letters

Designing with Light: Advanced 2D, 3D, and 4D Materials

(2019) Kenward Jung et al.   ADVANCED MATERIALS

Copper-Mediated Reversible Deactivation Radical Polymerization in Aqueous Media

(2018) Glen R. Jones et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Characterization of the Most Active Copper ATRP Catalyst Based on Tris[(4-dimethylaminopyridyl)methyl]amine

(2018) Thomas G. Ribelli et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Random heteropolymers preserve protein function in foreign environments

(2018) Brian Panganiban et al.   SCIENCE

Benefits of Catalyzed Radical Termination: High-Yield Synthesis of Polyacrylate Molecular Bottlebrushes without Gelation

(2018) Guojun Xie et al.   MACROMOLECULES

Industrial development of reversible-deactivation radical polymerization: is the induction period over?

(2018) Mathias Destarac   Polymer Chemistry

Precise Polymer Synthesis by Autonomous Self-Optimizing Flow Reactors

(2018) Maarten Rubens et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Established and emerging strategies for polymer chain-end modification

(2017) David J. Lunn et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Rise and Fall: Poly(phenyl vinyl ketone) Photopolymerization and Photodegradation under Visible and UV Radiation

(2017) Jennifer A. Reeves et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Disproportionation or Combination? The Termination of Acrylate Radicals in ATRP

(2017) Thomas G. Ribelli et al.   MACROMOLECULES

50th Anniversary Perspective: RAFT Polymerization—A User Guide

(2017) Sébastien Perrier   MACROMOLECULES

Engineering live cell surfaces with functional polymers via cytocompatible controlled radical polymerization

(2017) Jia Niu et al.   Nature Chemistry

Controlled radical polymerization of vinyl ketones using visible light

(2017) In-Hwan Lee et al.   Polymer Chemistry

End group modification of poly(acrylates) obtained via ATRP: a user guide

(2017) Athina Anastasaki et al.   Polymer Chemistry

Ultra-High Molecular Weights via Aqueous Reversible-Deactivation Radical Polymerization

(2017) R. Nicholas Carmean et al.   Chem

Cytocompatible Polymer Grafting from Individual Living Cells by Atom-Transfer Radical Polymerization

(2016) Ji Yup Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atom Transfer Radical Polymerization of Methacrylic Acid: A Won Challenge

(2016) Marco Fantin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Versatile and Scalable Strategy to Discrete Oligomers

(2016) Jimmy Lawrence et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Ligand Structure on the CuII–R OMRP Dormant Species and Its Consequences for Catalytic Radical Termination in ATRP

(2016) Thomas G. Ribelli et al.   MACROMOLECULES

50th Anniversary Perspective: Block Polymers—Pure Potential

(2016) Christopher M. Bates et al.   MACROMOLECULES

Mechanically controlled radical polymerization initiated by ultrasound

(2016) Hemakesh Mohapatra et al.   Nature Chemistry

Sequence-controlled methacrylic multiblock copolymers via sulfur-free RAFT emulsion polymerization

(2016) Nikolaos G. Engelis et al.   Nature Chemistry

Organocatalyzed atom transfer radical polymerization driven by visible light

(2016) J. C. Theriot et al.   SCIENCE

The limits of precision monomer placement in chain growth polymerization

(2016) Guillaume Gody et al.   Nature Communications

Cu(0)-Mediated Living Radical Polymerization: A Versatile Tool for Materials Synthesis

(2015) Athina Anastasaki et al.   CHEMICAL REVIEWS

Stereo-, Temporal and Chemical Control through Photoactivation of Living Radical Polymerization: Synthesis of Block and Gradient Copolymers

(2015) Sivaprakash Shanmugam et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalyst-Free and Blue Light-Induced RAFT Polymerization of Vinyl Acetate at Ambient Temperature

(2015) Chunlai Ding et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Enzyme-Initiated Reversible Addition–Fragmentation Chain Transfer Polymerization

(2015) Baohua Zhang et al.   MACROMOLECULES

The effect of Z-group modification on the RAFT polymerization of N-vinylpyrrolidone controlled by “switchable” N-pyridyl-functional dithiocarbamates

(2015) Sarah J. Stace et al.   Polymer Chemistry

Preparation of complex multiblock copolymers via aqueous RAFT polymerization at room temperature

(2015) Liam Martin et al.   Polymer Chemistry

ATRP-based polymers with modular ligation points under thermal and thermomechanical stress

(2015) Ozcan Altintas et al.   Polymer Chemistry

Rapid synthesis of ultrahigh molecular weight and low polydispersity polystyrene diblock copolymers by RAFT-mediated emulsion polymerization

(2015) Nghia P. Truong et al.   Polymer Chemistry

Explaining Unexpected Data via Competitive Equilibria and Processes in Radical Reactions with Reversible Deactivation

(2014) Dominik Konkolewicz et al.   ACCOUNTS OF CHEMICAL RESEARCH

Polymerization of Ethylene through Reversible Addition-Fragmentation Chain Transfer (RAFT)

(2014) Cédric Dommanget et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Atom Transfer Radical Polymerization

(2014) Nicolas J. Treat et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Polymerization-Induced Self-Assembly of Block Copolymer Nano-objects via RAFT Aqueous Dispersion Polymerization

(2014) Nicholas J. Warren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Robust and Versatile Photoinduced Living Polymerization of Conjugated and Unconjugated Monomers and Its Oxygen Tolerance

(2014) Jiangtao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

How are Radicals (Re)Generated in Photochemical ATRP?

(2014) Thomas G. Ribelli et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functional Degradable Polymers by Xanthate-Mediated Polymerization

(2014) Guillaume G. Hedir et al.   MACROMOLECULES

Photoinduced sequence-control via one pot living radical polymerization of acrylates

(2014) Athina Anastasaki et al.   Chemical Science

RAFT Polymerization of Vinyl Esters: Synthesis and Applications

(2014) Simon Harrisson et al.   Polymers

Fabrication of Complex Three-Dimensional Polymer Brush Nanostructures through Light-Mediated Living Radical Polymerization

(2013) Justin E. Poelma et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A guide to the synthesis of block copolymers using reversible-addition fragmentation chain transfer (RAFT) polymerization

(2013) Daniel J. Keddie   CHEMICAL SOCIETY REVIEWS

Aqueous Copper-Mediated Living Polymerization: Exploiting Rapid Disproportionation of CuBr with Me6TREN

(2013) Qiang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(II)/Tertiary Amine Synergy in Photoinduced Living Radical Polymerization: Accelerated Synthesis of ω-Functional and α,ω-Heterofunctional Poly(acrylates)

(2013) Athina Anastasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Improving the “Livingness” of ATRP by Reducing Cu Catalyst Concentration

(2013) Yu Wang et al.   MACROMOLECULES

Rapid and quantitative one-pot synthesis of sequence-controlled polymers by radical polymerization

(2013) Guillaume Gody et al.   Nature Communications

External Regulation of Controlled Polymerizations

(2012) Frank A. Leibfarth et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of high molecular weight and narrow molecular weight distribution poly(acrylonitrile) via RAFT polymerization

(2012) Shaogan Niu et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

Aqueous ARGET ATRP

(2012) Antonina Simakova et al.   MACROMOLECULES

Visible Light and Sunlight Photoinduced ATRP with ppm of Cu Catalyst

(2012) Dominik Konkolewicz et al.   ACS Macro Letters

Adding Spatial Control to Click Chemistry: Phototriggered Diels-Alder Surface (Bio)functionalization at Ambient Temperature

(2011) Thomas Pauloehrl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High molecular weight polyacrylamides by atom transfer radical polymerization: Enabling advancements in water-based applications

(2011) Eric A. Appel et al.   JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY

High-Order Multiblock Copolymers via Iterative Cu(0)-Mediated Radical Polymerizations (SET-LRP): Toward Biological Precision

(2011) Alexander H. Soeriyadi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Additive-Free Clicking for Polymer Functionalization and Coupling by Tetrazine–Norbornene Chemistry

(2011) Claire F. Hansell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Combining RAFT Radical Polymerization and Click/Highly Efficient Coupling Chemistries: A Powerful Strategy for the Preparation of Novel Materials

(2011) M. Alyse Harvison et al.   MACROMOLECULAR RAPID COMMUNICATIONS

Mechanism of Halogen Exchange in ATRP

(2011) Chi-How Peng et al.   MACROMOLECULES

Spatial and temporal control of the alkyne–azide cycloaddition by photoinitiated Cu(II) reduction

(2011) Brian J. Adzima et al.   Nature Chemistry

Aqueous RAFT/MADIX polymerisation of N-vinyl pyrrolidone at ambient temperature

(2011) Aymeric Guinaudeau et al.   Polymer Chemistry

Electrochemically Mediated Atom Transfer Radical Polymerization

(2011) A. J. D. Magenau et al.   SCIENCE

ATRP under Biologically Relevant Conditions: Grafting from a Protein

(2011) Saadyah Averick et al.   ACS Macro Letters

Synthesis of high molecular weight polystyrene using AGET ATRP under high pressure

(2010) Laura Mueller et al.   EUROPEAN POLYMER JOURNAL

Facile conversion of RAFT polymers into hydroxyl functional polymers: a detailed investigation of variable monomer and RAFT agent combinations

(2010) Mathias Dietrich et al.   Polymer Chemistry

Ultrafast Click Conjugation of Macromolecular Building Blocks at Ambient Temperature

(2009) Andrew J. Inglis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Universal (Switchable) RAFT Agents

(2009) Massimo Benaglia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid, Selective, and Reversible Nitroxide Radical Coupling (NRC) Reactions at Ambient Temperature

(2009) Jakov Kulis et al.   MACROMOLECULES

End group removal and modification of RAFT polymers

(2009) Helen Willcock et al.   Polymer Chemistry

Synthesis of Functional Polymers by Post-Polymerization Modification

(2008) Marc A. Gauthier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Development of a novel endosomolytic diblock copolymer for siRNA delivery

(2008) Anthony J. Convertine et al.   JOURNAL OF CONTROLLED RELEASE

Design and Use of Organic Nanoparticles Prepared from Star-Shaped Polymers with Reactive End Groups

(2008) Lieven M. Van Renterghem et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding Atom Transfer Radical Polymerization: Effect of Ligand and Initiator Structures on the Equilibrium Constants

(2008) Wei Tang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Temperature-Regulated Activity of Responsive Polymer−Protein Conjugates Prepared by Grafting-from via RAFT Polymerization

(2008) Priyadarsi De et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ab Initio Evaluation of the Thermodynamic and Electrochemical Properties of Alkyl Halides and Radicals and Their Mechanistic Implications for Atom Transfer Radical Polymerization

(2008) Ching Yeh Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Surface Modification of Divinylbenzene Microspheres via a Combination of RAFT and Hetero Diels-Alder Chemistry

(2008) Leena Nebhani et al.   MACROMOLECULAR RAPID COMMUNICATIONS

High Molecular Weight Polymethacrylates by AGET ATRP under High Pressure

(2008) Piotr Kwiatkowski et al.   MACROMOLECULES

Reversible Addition Fragmentation Chain Transfer (RAFT) and Hetero-Diels−Alder Chemistry as a Convenient Conjugation Tool for Access to Complex Macromolecular Designs

(2008) Andrew J. Inglis et al.   MACROMOLECULES