Pre-oxidation induced in situ interface strengthening in biodegradable Zn/nano-SiC composites prepared by selective laser melting

Introduction: Nano-SiC has attracted great attention as ceramic reinforcement in metal matrix composites, but the weak interface bonding between them remains a bottleneck for efficient strengthening. Objective: In this study, pre-oxidation treatments and selective laser melting (SLM) were employed to prepare Zn/nano-SiC biocomposites with strengthened interface bonding via in situ reaction. Methods: Nano-SiC and Zn powders were pre-oxidized respectively, and then used to prepare Zn/nanoSiC biocomposites via SLM. The powder microstructure, and the interface characteristics and mechanical properties of the biocomposites were investigated. The degradation properties and cell response were analyzed to evaluate their feasibility for orthopedic applications. Results: The results indicated that the pre-oxidation treatments generated a uniform oxide layer on the surface of both nano-SiC and Zn particles and the thickness of the oxide layer increased with pre-oxidation temperature. During the SLM process, the oxide layers not only improved the metal-ceramic wettability by reducing interface energy, but also induced in situ reaction to form chemical bonding between the Zn matrix and nano-SiC, thereby improving the interface bonding. Consequently, the Zn biocomposite reinforced by nano-SiC with a pre-oxidation temperature of 1000 degrees C (ZS1000 biocomposite) exhibited more transgranular fracture and significantly enhanced compressive yield strength of 171.5 MPa, which was 31.6% higher than that of the Zn biocomposite reinforced by nano-SiC without pre-oxidation. Moreover, the ZS1000 biocomposite presented slightly accelerated degradation which might be ascribed to the facilitated electron transfer by the interface product (Zn2SiO4). In addition, the ZS1000 biocomposite also showed appropriate biocompatibility for MG-63 cell adhesion, growth, and proliferation. Conclusion: This study shows the potential practical applicability for the preparation of Zn-based biocomposites with strong interface bonding and mechanical properties for orthopedic applications. (C) 2022 The Authors. Published by Elsevier B.V. on behalf of Cairo University.

Automated summary

In this study, Zn/nano-SiC biocomposites with strengthened interface bonding were prepared through pre-oxidation treatments and selective laser melting. The oxide layers generated by pre-oxidation not only improved the wettability and interface bonding, but also induced in situ reaction between Zn matrix and nano-SiC, resulting in enhanced mechanical properties. The optimized biocomposite exhibited higher compressive yield strength and appropriate degradation behavior and biocompatibility, showing potential practical applicability for orthopedic applications.