The road to industrialization of fine chemical carboxylation reactions

Direct Carboxylation with Carbon Dioxide via Cooperative Photoredox and Transition‐Metal Dual Catalysis

(2021) Guodong Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Photocatalyzed, β-Selective Hydrocarboxylation of α,β-Unsaturated Esters with CO2 under Flow for β-Lactone Synthesis

(2021) Guowei Kang et al.   ACS Catalysis

Synthetic Enzyme‐Catalyzed CO 2 Fixation Reactions

(2021) Godwin A. Aleku et al.   ChemSusChem

Fast Carbon Isotope Exchange of Carboxylic Acids Enabled by Organic Photoredox Catalysis

(2021) Duanyang Kong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photochemical Strategy for Carbon Isotope Exchange with CO2

(2021) Victor Babin et al.   ACS Catalysis

Radical Carboxylative Cyclizations and Carboxylations with CO2

(2021) Jian-Heng Ye et al.   ACCOUNTS OF CHEMICAL RESEARCH

Nickel‐Catalyzed Asymmetric Reductive Carbo‐Carboxylation of Alkenes with CO 2

(2021) Xiao‐Wang Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective CO 2 Fixation Via a Heck‐Coupling/Carboxylation Cascade Catalyzed by Nickel

(2021) Alessandro Cerveri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dicarboxylation of alkenes, allenes and (hetero)arenes with CO2 via visible-light photoredox catalysis

(2021) Tao Ju et al.   Nature Catalysis

Photoinduced Hydrocarboxylation via Thiol-Catalyzed Delivery of Formate Across Activated Alkenes

(2021) Sara N. Alektiar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical Chain Reduction via Carbon Dioxide Radical Anion (CO2•–)

(2021) Cecilia M. Hendy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent progress and challenges in carboxylation with CO2

(2021) Chuan-Kun Ran et al.   Current Opinion in Green and Sustainable Chemistry

Exploration of New Biomass‐Derived Solvents: Application to Carboxylation Reactions

(2020) Ashot Gevorgyan et al.   ChemSusChem

Harnessing Applied Potential: Selective β-Hydrocarboxylation of Substituted Olefins

(2020) Anas Alkayal et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of the Ruthenium-Catalyzed Synthesis of Acrylate Salt from Ethylene and CO2

(2020) Kohei Takahashi et al.   ORGANOMETALLICS

Transition‐Metal‐Free Carbon Isotope Exchange of Phenyl Acetic Acids

(2020) Gianluca Destro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Umpolung Difunctionalization of Carbonyls via Visible-Light Photoredox Catalytic Radical-Carbanion Relay

(2020) Shun Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Driven Reductive Carboarylation of Styrenes with CO2 and Aryl Halides

(2020) Hao Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

To Bind or Not to Bind: Mechanistic Insights into C–CO2 Bond Formation with Late Transition Metals

(2020) Diego García-López et al.   ORGANOMETALLICS

Ni(I)–Alkyl Complexes Bearing Phenanthroline Ligands: Experimental Evidence for CO2 Insertion at Ni(I) Centers

(2020) Rosie J. Somerville et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct reversible decarboxylation from stable organic acids in dimethylformamide solution

(2020) Duanyang Kong et al.   SCIENCE

Ruthenium‐Catalyzed Coupling Reactions of CO2 with C2H4 and Hydrosilanes towards Silyl Esters

(2020) Evgueni Kirillov et al.   CHEMISTRY-A EUROPEAN JOURNAL

Electroreductive Carbofunctionalization of Alkenes with Alkyl Bromides via a Radical-Polar Crossover Mechanism

(2020) Wen Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Visible-Light-Driven Anti-Markovnikov Hydrocarboxylation of Acrylates and Styrenes with CO 2

(2020) He Huang et al.   CCS Chemistry

Direct Carbon Isotope Exchange through Decarboxylative Carboxylation

(2019) Cian Kingston et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Development of an Improved System for the Carboxylation of Aryl Halides through Mechanistic Studies

(2019) David J. Charboneau et al.   ACS Catalysis

A Catalytic Decarboxylation/Carboxylation Platform for Accessing Isotopically-Labeled Carboxylic Acids

(2019) Andreu Tortajada Navarro et al.   ACS Catalysis

(Xantphos)Ni(I)-Alkyl Mediated Insertion of CO2

(2019) Justin Diccianni et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photocarboxylation of Benzylic C–H Bonds

(2019) Qing-Yuan Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Opportunities and Challenges for Catalysis in Carbon Dioxide Utilization

(2019) Michael D. Burkart et al.   ACS Catalysis

Highly Selective and Catalytic Generation of Acyclic Quaternary Carbon Stereocenters via Functionalization of 1,3-Dienes with CO2

(2019) Xiao-Wang Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carboxylation of Benzylic and Aliphatic C–H Bonds with CO2 Induced by Light/Ketone/Nickel

(2019) Naoki Ishida et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition metal-catalyzed carboxylation reactions with carbon dioxide

(2018) Ruben Martin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New trends and applications in carboxylation for isotope chemistry

(2018) Ryan A. Bragg et al.   JOURNAL OF LABELLED COMPOUNDS & RADIOPHARMACEUTICALS

Carbon-carbon bonds with CO 2 : Insights from computational studies

(2018) Marc Obst et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Ligand-Controlled Regioselective Hydrocarboxylation of Styrenes with CO2 by Combining Visible Light and Nickel Catalysis

(2018) Qing-Yuan Meng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Site-Selective Dicarboxylation of 1,3-Dienes with CO2

(2018) Andreu Tortajada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Enhancement of Proton Induced CO2 Cleavage: Bond Weakening and Ligand Residence Time Effects

(2018) Joshua A. Buss et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Mediated Coupling of Carbon Dioxide and Ethylene: Macrocyclic Metallalactones Enable Access to Various Carboxylates

(2018) Stephan M. Rummelt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Carbon Isotope Exchange of Pharmaceuticals with Labeled CO2

(2018) Gianluca Destro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct β-Selective Hydrocarboxylation of Styrenes with CO2 Enabled by Continuous Flow Photoredox Catalysis

(2017) Hyowon Seo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water

(2017) Morgane Gaydou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio- and Enantioselective Copper-Catalyzed Reductive Hydroxymethylation of Styrenes and 1,3-Dienes with CO2

(2017) Yong-Yuan Gui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Carboxylation of Hydroborated Disubstituted Alkenes and Terminal Alkynes with Cesium Fluoride

(2017) Martin Juhl et al.   ACS Catalysis

Enantioselective Incorporation of CO2: Status and Potential

(2017) Janakiram Vaitla et al.   ACS Catalysis

Synthesis of Acrylic Acid Derivatives from CO 2 and Ethylene

(2017) Xiao Wang et al.   Chem

Rhodium-Catalyzed Hydrocarboxylation of Olefins with Carbon Dioxide

(2016) Shingo Kawashima et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Carboxyzincation Employing Carbon Dioxide and Zinc Powder: Cobalt-Catalyzed Multicomponent Coupling Reactions with Alkynes

(2016) Keisuke Nogi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoredox activation of carbon dioxide for amino acid synthesis in continuous flow

(2016) Hyowon Seo et al.   Nature Chemistry

Capture of CO2 in air for 4,5-disubstituted furan-2(5H)-ones

(2016) Fei-Hu Cui et al.   Organic Chemistry Frontiers

Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

(2015) S. Chantal E. Stieber et al.   CHEMICAL COMMUNICATIONS

Structurally simple complexes of CO2

(2015) Luke J. Murphy et al.   CHEMICAL COMMUNICATIONS

Electrocarboxylation: towards sustainable and efficient synthesis of valuable carboxylic acids

(2014) Roman Matthessen et al.   Beilstein Journal of Organic Chemistry

The crucial roles of MgCl2 as a non-innocent additive in the Ni-catalyzed carboxylation of benzyl halide with CO2

(2014) Fareed Bhasha Sayyed et al.   CHEMICAL COMMUNICATIONS

Carbon Dioxide Capture and Use: Organic Synthesis Using Carbon Dioxide from Exhaust Gas

(2013) Seung Hyo Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbon dioxide utilization with C–N bond formation: carbon dioxide capture and subsequent conversion

(2012) Zhen-Zhen Yang et al.   Energy & Environmental Science

Biomimetic in situ Regeneration of Cofactors NAD(P)+ and NAD(P)H Models Hantzsch Esters and Dihydrophenanthridine

(2012) Zhengkun Yu et al.   SYNLETT

Carboxylation of Alkylboranes by N-Heterocyclic Carbene Copper Catalysts: Synthesis of Carboxylic Acids from Terminal Alkenes and Carbon Dioxide

(2011) Takeshi Ohishi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carbon Dioxide Recycling: Emerging Large-Scale Technologies with Industrial Potential

(2011) Elsje Alessandra Quadrelli et al.   ChemSusChem

Transition-Metal-Free Carboxylation of Organozinc Reagents Using CO2in DMF Solvent

(2009) Koji Kobayashi et al.   ORGANIC LETTERS

Super-Electron Donors:  Bis-pyridinylidene Formation by Base Treatment of Pyridinium Salts

(2008) John A. Murphy et al.   ORGANIC LETTERS