Article
Chemistry, Multidisciplinary
Andrey Aslandukov, Pascal L. Jurzick, Maxim Bykov, Alena Aslandukova, Artem Chanyshev, Dominique Laniel, Yuqing Yin, Fariia I. Akbar, Saiana Khandarkhaeva, Timofey Fedotenko, Konstantin Glazyrin, Stella Chariton, Vitali Prakapenka, Fabrice Wilhelm, Andrei Rogalev, Davide Comboni, Michael Hanfland, Natalia Dubrovinskaia, Leonid Dubrovinsky
Summary: A series of isostructural Ln(3)O(2)(CN3) compounds were successfully synthesized under high-pressure high-temperature conditions. The crystal structure of these compounds was determined and confirmed using SCXRD, XANES measurements, and DFT calculations. It was also found that the unit cell volumes and compressibility of the compounds were influenced by the lanthanide contraction phenomenon. Additionally, the stabilization of the CN35- guanidinate anion at ambient conditions provides new opportunities in inorganic and organic synthetic chemistry.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Physics, Applied
C. V. Storm, J. D. McHardy, M. J. Duff, S. G. MacLeod, E. F. O'Bannon III, M. I. McMahon
Summary: We conducted diffraction studies on bismuth (Bi) up to 298 GPa using conventional and toroidal diamond anvil cells (DACs) to investigate its suitability as a pressure-transmitting medium (PTM). By utilizing microfocused x-ray beams, we determined the pressure dependence of the uniaxial stress component (t) in cubic Bi-V and found that at 298 GPa, t was 0.5 GPa. This indicates that Bi-V cannot support significant shear stresses, making it an excellent PTM. Additionally, we measured the compressibility of Bi-V compared to copper (Cu) and gold (Au), enabling its use as both a pressure marker and PTM.
JOURNAL OF APPLIED PHYSICS
(2023)
Article
Chemistry, Multidisciplinary
Lukas Bruening, Nityasagar Jena, Elena Bykova, Pascal L. Jurzick, Niko T. Flosbach, Mohamed Mezouar, Michael Hanfland, Nico Giordano, Timofey Fedotenko, Bjoern Winkler, Igor A. Abrikosov, Maxim Bykov
Summary: This study successfully synthesized antimony guanidinate under high pressure conditions and determined its crystal structure and properties. The discovery of the guanidinate anion marks a significant milestone in carbonitride chemistry and paves the way for the development of new inorganic nitridocarbonates.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2023)
Article
Chemistry, Multidisciplinary
Matteo Ceppatelli, Demetrio Scelta, Manuel Serrano-Ruiz, Kamil Dziubek, Marta Morana, Volodymyr Svitlyk, Gaston Garbarino, Tomasz Poreba, Mohamed Mezouar, Maurizio Peruzzini, Roberto Bini
Summary: Chemical reactivity between As and N-2 leads to the synthesis of crystalline arsenic nitride under high pressure and temperature conditions. X-ray diffraction provides evidence for the formation of a covalent compound of AsN stoichiometry. Additional data indicate the existence of AsN at room temperature in a wide pressure range, with implications for pnictogens chemistry and the synthesis of advanced materials.
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
(2022)
Article
Chemistry, Inorganic & Nuclear
Nishant N. Patel, Meenakshi Sunder
Summary: Results of high pressure Raman and ADXRD study on CsIBr2 show two phase transitions at 5 and 19 GPa, with bulk moduli of 10.9(8) GPa and 17.8(1) GPa for the orthorhombic and trigonal phases, respectively.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Multidisciplinary Sciences
Bianca Haberl, Malcolm Guthrie, Reinhard Boehler
Summary: Over the past 60 years, the diamond anvil cell (DAC) has become the preferred tool for high pressure science due to its ability to study materials at megabar pressures using X-ray and spectroscopic probes. However, the pressure range for neutron diffraction has been limited. In this study, a neutron DAC was introduced with improved mechanical stability, gem-quality synthetic diamonds, and improved collimation, allowing for breakthroughs in the previously limited pressure range. This development enables structural studies on low-Z materials that are difficult to characterize by X-rays.
SCIENTIFIC REPORTS
(2023)
Article
Materials Science, Multidisciplinary
Maxim Bykov, Elena Bykova, Chris J. Pickard, Miguel Martinez-Canales, Konstantin Glazyrin, Jesse S. Smith, Alexander F. Goncharov
Summary: The study identified the structure of the high-pressure phase of molecular methane using single-crystal synchrotron x-ray diffraction, Raman spectroscopy, and first principles calculations. It revealed the relationship between the high-pressure phase and the previously documented phase B, and determined the positions of hydrogen atoms through calculations. The study's findings differ from previous proposals of multiple high-pressure phases based solely on Raman spectroscopy results.
Review
Crystallography
Tingting Yan, Dongyang Xi, Qiuxue Fang, Ye Zhang, Junhai Wang, Xiaodan Wang
Summary: High-pressure polymorphism is a developing interdisciplinary field that utilizes pressure to explore the nature of structure-property relationships in hydrogen-bonded polymorphic systems. This review discusses the use of pressure in studying polymorphism and surveys the compounds studied at high pressures by the author's group. Insight gained from these studies has allowed for crystal engineering and the design of crystals with desired architectures through hydrogen-bonded networks. Experimental methods and techniques for analyzing high-pressure polymorphs are also briefly discussed.
Article
Materials Science, Ceramics
Abhinav Parakh, Mehrdad T. Kiani, Anabelle Colmenares, Andrew C. Lee, Guoyin Shen, Stella Chariton, Vitali B. Prakapenka, X. Wendy Gu
Summary: This study investigates the structural changes of Ni1-xBx metallic glass nanoparticles under high-pressure conditions using in situ high-pressure X-ray diffraction. The results show that the size and composition of the nanoparticles have an effect on their high-pressure behavior.
JOURNAL OF NON-CRYSTALLINE SOLIDS
(2022)
Article
Chemistry, Inorganic & Nuclear
Xuejing He, Hiroyuki Kagi, Kazuki Komatsu, Satoshi Nakano
Summary: In-situ high-pressure experiments were conducted on magnesium hydroxyfluoride using synchrotron X-ray diffraction and Fourier transform infrared absorption spectroscopy. The study showed that no phase transition occurred during compression, and the hydrogen bond did not strengthen under pressure.
JOURNAL OF SOLID STATE CHEMISTRY
(2021)
Article
Multidisciplinary Sciences
Evgenii Vasilev, Dmitry Popov, Maddury Somayazulu, Nenad Velisavljevic, Marko Knezevic
Summary: The mechanisms of HCP to BCC phase transformation in Mg single crystals under quasi-hydrostatic pressures were observed using polychromatic beam Laue diffraction and monochromatic beam powder diffraction techniques. Plastic deformation occurred in the crystals upon loading, accompanied by local misorientations. The onset of the transformation was determined to be at a pressure of 56.6 +/- 2 GPa, with a rapid decrease in intensity of Laue reflections from HCP crystals.
SCIENTIFIC REPORTS
(2023)
Article
Geochemistry & Geophysics
Melinda J. J. Rucks, Gregory J. J. Finkelstein, Dongzhou Zhang, Przemyslaw K. K. Dera, Thomas S. S. Duffy
Summary: In this study, the behavior of a natural fluorapatite crystal under compression was examined. The results showed that the apatite structure remained stable up to 32.4 GPa, and then transformed into a triclinic phase at 35.6 GPa. The study extended the pressure range over which fluorapatite has been examined, providing new insights into its structural response to high-pressure conditions.
AMERICAN MINERALOGIST
(2023)
Article
Chemistry, Physical
Camilla H. Kronbo, Francesca Menescardi, Davide Ceresoli, Martin Bremholm
Summary: The synthesis and high pressure behavior of three polymorphs of SrGeO3 were reported. Different compressibility and phase transitions were observed in the three polymorphs, with the perovskite polymorph exhibiting the highest bulk modulus. The experimental data were well-fitted by density functional theory calculations.
JOURNAL OF ALLOYS AND COMPOUNDS
(2021)
Article
Physics, Applied
Sathyan Sandeep, Theo Threard, Elton De Lima Savi, Nikolay Chigarev, Alain Bulou, Vincent Tournat, Andreas Zerr, Vitalyi E. Gusev, Samuel Raetz
Summary: Time-domain Brillouin scattering (TDBS) uses ultrashort laser pulses to generate coherent acoustic pulses in solid samples, allowing for high-resolution imaging of material inhomogeneities at nanometer scales. Compared to x-ray computed tomography and classical spectroscopic methods, TDBS has clear advantages in imaging transparency samples with unlimited lateral sizes and thicknesses.
JOURNAL OF APPLIED PHYSICS
(2021)
Article
Chemistry, Multidisciplinary
Saki Yamada, Ayumi Hirano, Yoko Tanaka, Ryohei Akiyoshi, Hirofumi Yoshikawa, Daisuke Tanaka
Summary: By controlling nucleation using microfluidic synthesis and metal mixing, MIL-68 containing trivalent metal ions was rapidly synthesized without HF addition, resulting in a product with high crystallinity.
CRYSTAL GROWTH & DESIGN
(2022)
Article
Crystallography
Daniel Tchon, Anna Makal, Matthias Gutmann, Krzysztof Wozniak
ZEITSCHRIFT FUR KRISTALLOGRAPHIE-CRYSTALLINE MATERIALS
(2018)
Article
Chemistry, Multidisciplinary
Daniel Tchon, Anna Makal
ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS
(2019)
Article
Chemistry, Inorganic & Nuclear
Michal Lomzik, Muhammad Hanif, Aleksandra Budniok, Andrzej Blauz, Anna Makal, Daniel M. Tchon, Barbara Lesniewska, Kelvin K. H. Tong, Sanam Movassaghi, Tilo Sohnel, Stephen M. F. Jamieson, Ayesha Zafar, Johannes Reynisson, Blazej Rychlik, Christian G. Hartinger, Damian Plazuk
INORGANIC CHEMISTRY
(2020)
Article
Chemistry, Physical
Damian Trzybinski, Agata Wrobel, Daniel Tchon, Malcolm A. Kelland, Krzysztof Wozniak
Summary: The crystal structures of three hexaalkylguanidinium halides have been revealed and reported for the first time. These compounds have potential applications in crystal engineering due to their structural features related to the length of the alkyl substituent and the size of the halide anion. The study found significant differences in the supramolecular architecture of ions in the crystals of different compounds.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Multidisciplinary
Guru Row Roman Gajda, Daniel Mariusz Tchon, Anna Makal
Summary: The crystal structure and intermolecular interactions of a luminescent pyrene-pyrazole-aldehyde (PPPcA) were analyzed using experimental charge density analysis, periodic DFT calculations, and high-pressure crystallography. The luminescent properties of PPPcA under pressure were reported, showing that a pair of C-H···O hydrogen bonds played a significant role. However, the presence of strong intermolecular interactions does not guarantee changes in luminescent properties.
CRYSTAL GROWTH & DESIGN
(2023)
Article
Materials Science, Multidisciplinary
Daniel Tchon, David Bowskill, Isaac Sugden, Piotr Piotrowski, Anna Makal
Summary: The study identified three additional polymorphs of 1,8-Diacetylpyrene with distinct optical properties, two of which were obtained under high pressure conditions. Utilizing single-crystal X-ray diffraction, DFT electronic structure calculations, Raman spectroscopy, and UV-vis fluorescence experiments, the impact of molecular arrangements on optical properties was elucidated. Crystal Structure Prediction (CSP) study indicated the potential for new functional materials, even for known moderate-size organic compounds, by combining CSP with electronic structure methods.
JOURNAL OF MATERIALS CHEMISTRY C
(2021)
Article
Chemistry, Multidisciplinary
Daniel Tchon, Damian Trzybinski, Anna Wrona-Piotrowicz, Anna Makal