4.6 Article

Electrocatalytic Degradation of Levofloxacin, a Typical Antibiotic in Hospital Wastewater

Journal

MATERIALS
Volume 14, Issue 22, Pages -

Publisher

MDPI
DOI: 10.3390/ma14226814

Keywords

titanium suboxide electrode; levofloxacin; response surface methodology (RSM); degradation mechanisms and pathways

Funding

  1. National Natural Science Foundation of China [52100072]
  2. Dalian Science and Technology Innovation Fund Project [2019J12SN69]
  3. Youth Innovation Promotion Association CAS [2020190]
  4. Strategic Priority Research Program of the Chinese Academy of Sciences [XDA21021101]
  5. National Key Research and Development Program of China [2019YFA0705803]
  6. Scientific Research Common Program of Beijing Municipal Commission of Education [KM202010017006]
  7. Beijing Natural Science Foundation [8214056]

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In the context of the novel coronavirus pneumonia epidemic, overuse of antibiotics in hospitals has put heavy pressure on wastewater treatment processes. Developing stable, safe, and efficient hospital wastewater treatment equipment is crucial. A bench-scale electrooxidation equipment was used to evaluate the removal effect of the antibiotic LVX in hospital wastewater, achieving a 41% TOC removal rate at the best reaction conditions.
Presently, in the context of the novel coronavirus pneumonia epidemic, several antibiotics are overused in hospitals, causing heavy pressure on the hospital's wastewater treatment process. Therefore, developing stable, safe, and efficient hospital wastewater treatment equipment is crucial. Herein, a bench-scale electrooxidation equipment for hospital wastewater was used to evaluate the removal effect of the main antibiotic levofloxacin (LVX) in hospital wastewater using response surface methodology (RSM). During the degradation process, the influence of the following five factors on total organic carbon (TOC) removal was discussed and the best reaction condition was obtained: current density, initial pH, flow rate, chloride ion concentration, and reaction time of 39.6 A/m(2), 6.5, 50 mL/min, 4 parts per thousand, and 120 min, respectively. The TOC removal could reach 41% after a reaction time of 120 min, which was consistent with the result predicted by the response surface (40.48%). Moreover, the morphology and properties of the electrode were analyzed. The degradation pathway of LVX was analyzed using high-performance liquid chromatography-mass spectrometry (LC-MS). Subsequently, the bench-scale electrooxidation equipment was changed into onboard-scale electrooxidation equipment, and the onboard-scale equipment was promoted to several hospitals in Dalian.

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