C–C Bond Fluorination via Manganese Catalysis

Recent Advances in the Application of Selectfluor as a “Fluorine‐free” Functional Reagent in Organic Synthesis

(2020) Ke Yang et al.   Chemistry-An Asian Journal

Utility of Organoboron Reagents in Arylation of Cyclopropanols via Chelated Pd(II) Catalysis: Chemoselective Access to β-Aryl Ketones

(2020) Thangeswaran Ramar et al.   JOURNAL OF ORGANIC CHEMISTRY

Carbonyl-Directed Aliphatic Fluorination: A Special Type of Hydrogen Atom Transfer Beats Out Norrish II

(2020) Fereshte Ghorbani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Radical‐Promoted Distal C‐H Functionalization of C(sp3) Centers with Fluorinated Moieties

(2020) Enzo Nobile et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Current Contributions of Organofluorine Compounds to the Agrochemical Industry

(2020) Yuta Ogawa et al.   iScience

Manganese-catalyzed ring-opening carbonylation of cyclobutanol derivatives

(2019) Tim Meyer et al.   TETRAHEDRON LETTERS

The fluorination of C-H bonds: developments and perspectives

(2019) Veronique Gouverneur et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Cyclopropanol Ring-Opening C(sp3)–C(sp2) Cross-Couplings with Aryl Sulfoxides

(2019) Dengfeng Chen et al.   ORGANIC LETTERS

Manganese-Catalyzed Ring-Opening Coupling Reactions of Cyclopropanols with Enones

(2019) Yong-Hui Zhang et al.   ORGANIC LETTERS

Manganese-Catalyzed Electrochemical Deconstructive Chlorination of Cycloalkanols via Alkoxy Radicals

(2019) Benjamin D. W. Allen et al.   ORGANIC LETTERS

Highly Regioselective C–H Alkylation of Alkenes Through an Aryl to Vinyl 1,4-Palladium Migration/C–C Cleavage Cascade

(2019) Quannan Wang et al.   ACS Catalysis

Sensitized Aliphatic Fluorination Directed by Terpenoidal Enones: A “Visible Light” Approach

(2018) Desta Doro Bume et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Enhanced Ring Opening of Cycloalkanols Enabled by Brønsted Base-Tethered Acyloxy Radical Induced Hydrogen Atom Transfer-Electron Transfer

(2018) Rong Zhao et al.   ORGANIC LETTERS

Catalytic Cyclopropanol Ring Opening for Divergent Syntheses of γ-Butyrolactones and δ-Ketoesters Containing All-Carbon Quaternary Centers

(2018) Zhishi Ye et al.   ACS Catalysis

Tandem Oxidative Ring-Opening/Cyclization Reaction in Seconds in Open Atmosphere for the Synthesis of 1-Tetralones in Water–Acetonitrile

(2018) Jingxian Fang et al.   ORGANIC LETTERS

C-C Bond Formation by Oxidative Ring-Opening Homocoupling of Cyclobutanols

(2017) Huiying Zeng et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Multiple Enone-Directed Reactivity Modes Lead to the Selective Photochemical Fluorination of Polycyclic Terpenoid Derivatives

(2017) Cody Ross Pitts et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ketones as directing groups in photocatalytic sp3 C–H fluorination

(2017) Desta Doro Bume et al.   Chemical Science

C−C Bond-Forming Strategy by Manganese-Catalyzed Oxidative Ring-Opening Cyanation and Ethynylation of Cyclobutanol Derivatives

(2016) Rongguo Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photocatalytic C−C Bond Cleavage and Amination of Cycloalkanols by Cerium(III) Chloride Complex

(2016) Jing-Jing Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Manganese-catalyzed regiospecific sp3 C–S bond formation through C–C bond cleavage of cyclobutanols

(2016) Rongguo Ren et al.   CHEMICAL COMMUNICATIONS

Manganese-Promoted Ring-Opening Hydrazination of Cyclobutanols: Synthesis of Alkyl Hydrazines

(2016) Dongping Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Hydrogen Bonding to Hexafluoroisopropanol Controls the Oxidative Strength of Hypervalent Iodine Reagents

(2016) Ignacio Colomer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Synthesis of Carbonyl-Containing Alkyl Chlorides via Silver-Catalyzed Ring-Opening Chlorination of Cycloalkanols

(2016) Feng-Qing Huang et al.   ORGANIC LETTERS

Silver-mediated oxidative trifluoromethylthiolation of cycloalkanols by C–C bond cleavage: a regioselective approach to distally trifluoromethylthiolated ketones

(2016) Feng-Qing Huang et al.   RSC Advances

Manganese-catalyzed ring-opening chlorination of cyclobutanols: regiospecific synthesis of γ-chloroketones

(2016) Leitao Huan et al.   Organic Chemistry Frontiers

Manganese-Catalyzed Oxidative Azidation of Cyclobutanols: Regiospecific Synthesis of Alkyl Azides by CC Bond Cleavage

(2015) Rongguo Ren et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Targeted Fluorination with the Fluoride Ion by Manganese-Catalyzed Decarboxylation

(2015) Xiongyi Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Monofluorination of Organic Compounds: 10 Years of Innovation

(2015) Pier Alexandre Champagne et al.   CHEMICAL REVIEWS

Ring-opening Fluorination of Cyclobutanols and Cyclopropanols Catalyzed by Silver

(2015) Naoki Ishida et al.   CHEMISTRY LETTERS

Site-Selective Approach to β-Fluorination: Photocatalyzed Ring Opening of Cyclopropanols

(2015) Steven Bloom et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Study of Silver-Catalyzed Decarboxylative Fluorination

(2015) Niki R. Patel et al.   JOURNAL OF ORGANIC CHEMISTRY

Silver-Catalyzed Ring-Opening Strategy for the Synthesis of β- and γ-Fluorinated Ketones

(2015) Huijun Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron- or silver-catalyzed oxidative fluorination of cyclopropanols for the synthesis of β-fluoroketones

(2015) Shichao Ren et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Alkynylation of Tertiary Cycloalkanols via Radical C–C Bond Cleavage: A Route to Distal Alkynylated Ketones

(2015) Shun Wang et al.   ORGANIC LETTERS

Mild and selective α-fluorination of carbonyl compounds (ketones, 1,3-diketones, β-ketoesters, α-nitroketones, and β-ketonitriles) with Selectfluor (F-TEDA-BF4) in imidazolium ILs [BMIM/PF6 or BMIM/NTf2] with Brønsted-acidic IL [PMIM(SO3H)/OTf] as promoter

(2015) A. Srinivas Reddy et al.   TETRAHEDRON LETTERS

Fluorine-18 Radiochemistry, Labeling Strategies and Synthetic Routes

(2014) Orit Jacobson et al.   BIOCONJUGATE CHEMISTRY

Silver-Catalyzed Radical Fluorination of Alkylboronates in Aqueous Solution

(2014) Zhaodong Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Late-Stage Fluorination: From Fundamentals to Application

(2014) Michael G. Campbell et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Late-stage [18F]fluorination: new solutions to old problems

(2014) Allen F. Brooks et al.   Chemical Science

Formal fluorine atom transfer radical addition: silver-catalyzed carbofluorination of unactivated alkenes with ketones in aqueous solution

(2014) Lin Zhu et al.   Organic Chemistry Frontiers

Manganese-Catalyzed Oxidative Benzylic C-H Fluorination by Fluoride Ions

(2013) Wei Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The electrochemical behavior of cerium(III/IV) complexes: Thermodynamics, kinetics and applications in synthesis

(2013) Nicholas A. Piro et al.   COORDINATION CHEMISTRY REVIEWS

Silver-Catalyzed Radical Aminofluorination of Unactivated Alkenes in Aqueous Media

(2013) Zhaodong Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Radical Phosphonofluorination of Unactivated Alkenes

(2013) Chengwei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

18F Labeling of Arenes

(2012) Matthew Tredwell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine Transfer to Alkyl Radicals

(2012) Montserrat Rueda-Becerril et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silver-Catalyzed Decarboxylative Fluorination of Aliphatic Carboxylic Acids in Aqueous Solution

(2012) Feng Yin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Accelerated Pd-Catalyzed Ketone γ-Arylation via C–C Cleavage with Aryl Chlorides

(2012) Asraa Ziadi et al.   ORGANIC LETTERS

Oxidative Aliphatic C-H Fluorination with Fluoride Ion Catalyzed by a Manganese Porphyrin

(2012) W. Liu et al.   SCIENCE

Organic fluorine compounds: a great opportunity for enhanced materials properties

(2011) Ricarda Berger et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective Organocatalytic α-Fluorination of Cyclic Ketones

(2011) Piotr Kwiatkowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalysis for fluorination and trifluoromethylation

(2011) Takeru Furuya et al.   NATURE

Phenyliodine diacetate-mediated oxidative cleavage of cyclobutanols leading to γ-hydroxy ketones

(2011) Hiromichi Fujioka et al.   TETRAHEDRON LETTERS

Carbon-Fluorine Bond Formation for the Synthesis of Aryl Fluorides

(2010) Tobias Ritter et al.   SYNTHESIS-STUTTGART

Selective difluoromethylation and monofluoromethylation reactions

(2009) Jinbo Hu et al.   CHEMICAL COMMUNICATIONS

Synthesis of γ-halogenated ketones via the Ce(IV)-mediated oxidative coupling of cyclobutanols and inorganic halides

(2009) Brian M. Casey et al.   TETRAHEDRON LETTERS

Fluorine in medicinal chemistry

(2007) Sophie Purser et al.   CHEMICAL SOCIETY REVIEWS