Isotope Effects Reveal the Catalytic Mechanism of the Archetypical Suzuki-Miyaura Reaction

Heavy-Atom Kinetic Isotope Effects: Primary Interest or Zero Point?

(2021) Harvey J. A. Dale et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic and Kinetic Studies of the Ring Opening Metathesis Polymerization of Norbornenyl Monomers by a Grubbs Third Generation Catalyst

(2019) Michael G. Hyatt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The emergence of Pd-mediated reversible oxidative addition in cross coupling, carbohalogenation and carbonylation reactions

(2019) David J. Jones et al.   Nature Catalysis

Pd Metal Catalysts for Cross-Couplings and Related Reactions in the 21st Century: A Critical Review

(2018) Andrea Biffis et al.   CHEMICAL REVIEWS

Elucidating the Role of the Boronic Esters in the Suzuki–Miyaura Reaction: Structural, Kinetic, and Computational Investigations

(2018) Andy A. Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of the Ullmann Biaryl Ether Synthesis Catalyzed by Complexes of Anionic Ligands: Evidence for the Reaction of Iodoarenes with Ligated Anionic CuI Intermediates

(2018) Ramesh Giri et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides with Carbon Monoxide and Ammonia

(2018) Justin Y. Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Computational Study of the (Z)-Selective Formation of Trisubstituted Olefins and Benzo-Fused Oxacycles from the Ruthenium-Catalyzed Dehydrative C–H Coupling of Phenols with Ketones

(2018) Hanbin Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki–Miyaura Reaction

(2017) Andy A. Thomas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Generalized Picture of C–C Cross-Coupling

(2017) Michael Busch et al.   ACS Catalysis

Computational Studies of Versatile Heterogeneous Palladium-Catalyzed Suzuki, Heck, and Sonogashira Coupling Reactions

(2017) Pitchaimani Veerakumar et al.   ACS Sustainable Chemistry & Engineering

Measuring the kinetic isotope effect at natural isotopic abundances for discriminating between the homogeneous and heterogeneous catalytic mechanisms in the Heck and Suzuki reactions

(2016) A. A. Kurokhtina et al.   KINETICS AND CATALYSIS

Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link

(2016) A. A. Thomas et al.   SCIENCE

Computational Perspective on Pd-Catalyzed C–C Cross-Coupling Reaction Mechanisms

(2013) Max García-Melchor et al.   ACCOUNTS OF CHEMICAL RESEARCH

Transmetalation in the Suzuki-Miyaura Coupling: The Fork in the Trail

(2013) Alastair J. J. Lennox et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Additions of Aryl Halides to Palladium Proceed through the Monoligated Complex

(2013) Krista Vikse et al.   ChemCatChem

Mechanistic Origin of Antagonist Effects of Usual Anionic Bases (OH−, CO32−) as Modulated by their Countercations (Na+, Cs+, K+) in Palladium-Catalyzed Suzuki-Miyaura Reactions

(2012) Christian Amatore et al.   CHEMISTRY-A EUROPEAN JOURNAL

Kinetic Data for the Transmetalation/Reductive Elimination in Palladium-Catalyzed Suzuki-Miyaura Reactions: Unexpected Triple Role of Hydroxide Ions Used as Base

(2011) Christian Amatore et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Medicinal Chemist’s Toolbox: An Analysis of Reactions Used in the Pursuit of Drug Candidates

(2011) Stephen D. Roughley et al.   JOURNAL OF MEDICINAL CHEMISTRY

Distinguishing Between Pathways for Transmetalation in Suzuki−Miyaura Reactions

(2011) Brad P. Carrow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A computational study of phosphine ligand effects in Suzuki–Miyaura coupling☆

(2010) Jesús Jover et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

Transition-State Geometry Measurements from13C Isotope Effects. The Experimental Transition State for the Epoxidation of Alkenes with Oxaziridines

(2009) Jennifer S. Hirschi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Effect of Ligand Steric Properties and Halide Identity on the Mechanism for Oxidative Addition of Haloarenes to Trialkylphosphine Pd(0) Complexes

(2009) Fabiola Barrios-Landeros et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Exchange as the First Irreversible Step in the Nickel-Catalyzed Cross-Coupling Reaction of Grignard Reagents

(2008) Naohiko Yoshikai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY