A self-healing catalyst for electrocatalytic and photoelectrochemical oxygen evolution in highly alkaline conditions

While self-healing catalysts may survive the harsh environments used for oxygen evolution, understanding how to develop such electrocatalysts remains a challenge. Here, authors find cobalt to promote the self-healing of leached iron centers in borate-intercalated nickel-iron-cobalt oxyhydroxides. While self-healing is considered a promising strategy to achieve long-term stability for oxygen evolution reaction (OER) catalysts, this strategy remains a challenge for OER catalysts working in highly alkaline conditions. The self-healing of the OER-active nickel iron layered double hydroxides (NiFe-LDH) has not been successful due to irreversible leaching of Fe catalytic centers. Here, we investigate the introduction of cobalt (Co) into the NiFe-LDH as a promoter for in situ Fe redeposition. An active borate-intercalated NiCoFe-LDH catalyst is synthesized using electrodeposition and shows no degradation after OER tests at 10 mA cm(-2) at pH 14 for 1000 h, demonstrating its self-healing ability under harsh OER conditions. Importantly, the presence of both ferrous ions and borate ions in the electrolyte is found to be crucial to the catalyst's self-healing. Furthermore, the implementation of this catalyst in photoelectrochemical devices is demonstrated with an integrated silicon photoanode. The self-healing mechanism leads to a self-limiting catalyst thickness, which is ideal for integration with photoelectrodes since redeposition is not accompanied by increased parasitic light absorption.

Automated summary

The study finds that cobalt can promote the self-healing of leached iron centers in borate-intercalated nickel-iron-cobalt oxyhydroxides, leading to the synthesis of an active borate-intercalated NiCoFe-LDH catalyst with self-healing ability under harsh OER conditions. The presence of both ferrous ions and borate ions in the electrolyte is crucial to the catalyst's self-healing, demonstrating its potential for integration into photoelectrochemical devices.