The inversion of tetrahedral p-block element compounds: general trends and the relation to the second-order Jahn–Teller effect

Elusive Magnetic Compounds Originated from Planar Tetracoordinate Silicon, a Theoretical Prediction

(2021) Congjie Zhang et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Main Group Redox Catalysis of Organopnictogens: Vertical Periodic Trends and Emerging Opportunities in Group 15

(2021) Jeffrey M. Lipshultz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Planar Hexacoordinate Carbons: Half Covalent, Half Ionic

(2021) Luis Leyva‐Parra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Not Carbon s–p Hybridization, but Coordination Number Determines C−H and C−C Bond Length

(2021) Pascal Vermeeren et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lewis Superacidic Catecholato Phosphonium Ions: Phosphorus–Ligand Cooperative C–H Bond Activation

(2021) Daniel Roth et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding chemical reactivity using the activation strain model

(2020) Pascal Vermeeren et al.   Nature Protocols

Planar Hypercoordinate Motifs in Two-Dimensional Materials

(2020) Yu Wang et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metal‐Ligand Cooperativity of the Calix[4]pyrrolato Aluminate: Triggerable C‐C Bond Formation and Rate Control in Catalysis

(2020) Fabian Ebner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tackling the Inertness of CO2: Facile Activation and Electroreduction on the Metal-Free SiN4C4 Monolayer Sheet

(2020) Lei Fang et al.   Journal of Physical Chemistry C

Understanding the Uniqueness of the 2p‐Elements in the Periodic Table

(2020) Zhenling Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Planar Tetracoordinate Silicons in Organic Molecules As Carbenoid‐Type Amphoteric Centers: A Computational Study

(2020) Yuwei Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Nature and Strength of Lewis Acid/Base Interaction in Boron and Nitrogen Trihalides

(2020) Daniela Rodrigues Silva et al.   Chemistry-An Asian Journal

Syntheses of Square Planar Gallium Complexes and a Proton NMR Correlation Probing Metalloaromaticity

(2020) Thomas M. Bass et al.   INORGANIC CHEMISTRY

DFT ‐D4 counterparts of leading meta‐ generalized‐gradient approximation and hybrid density functionals for energetics and geometries

(2020) Asim Najibi et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Jahn–Teller and Pseudo-Jahn–Teller Effects: From Particular Features to General Tools in Exploring Molecular and Solid State Properties

(2020) Isaac B. Bersuker   CHEMICAL REVIEWS

Planar Tetracoordinated Silicon (ptSi): Room-Temperature Stable Compounds Containing Anti-van’t Hoff/Le Bel Silicon

(2020) Priyabrata Ghana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Validating the Biphilic Hypothesis of Nontrigonal Phosphorus(III) Compounds

(2019) Kyounghoon Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Si3C2H2 isomers with a planar tetracoordinate carbon or silicon atom(s)

(2019) Venkatesan S. Thimmakondu et al.   Computational and Theoretical Chemistry

Pushing the Lewis Acidity Boundaries of Boron Compounds With Non-Planar Triarylboranes Derived from Triptycenes

(2019) Ali Ben Saida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Calix[4]pyrrole Aluminate: A Planar Tetracoordinate Aluminum(III) Anion and Its Unusual Lewis Acidity

(2019) Fabian Ebner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Revitalizing the concept of bond order through delocalization measures in real space

(2018) Carlos Outeiral et al.   Chemical Science

Planar pentacoordinate carbons

(2018) Valentin Vassilev-Galindo et al.   Nature Reviews Chemistry

Stabilization of planar tetra-coordinate silicon in a 2D-layered extended system and design of a high-capacity anode material for Li-ion batteries

(2018) Ming-Jun Sun et al.   Nanoscale

Is the Inversion of Phosphorus Trihalides (PF3, PCl3, PBr3, and PI3) a Diradical Process?

(2018) Zoltan Varga et al.   JOURNAL OF PHYSICAL CHEMISTRY A

The Structure of the Carbene Stabilized Si2H2 May Be Equally Well Described with Coordinate Bonds as with Classical Double Bonds

(2016) Chandrajeet Mohapatra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound

(2015) Thomas P. Robinson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Perspectives in Chemistry-Aspects of Adaptive Chemistry and Materials

(2015) Jean-Marie Lehn   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Square-Planar Aluminum(III) Complexes

(2014) Emily J. Thompson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Physical Meaning of Virtual Kohn–Sham Orbitals and Orbital Energies: An Ideal Basis for the Description of Molecular Excitations

(2014) R. van Meer et al.   Journal of Chemical Theory and Computation

Pentaatomic planar tetracoordinate silicon with 14 valence electrons: A large-scale global search of SiXnYmq (n + m = 4;q = 0, ±1, −2; X, Y = main group elements from H to Br)

(2014) Jing Xu et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Why edge inversion? Theoretical characterization of the bonding in the transition states for inversion in F n NH(3−n) and FnPH(3−n) (n = 0–3)

(2014) Lu T. Xu et al.   THEORETICAL CHEMISTRY ACCOUNTS

Planar tetracoordinate Si and Ge in π-aromatic (X=Si, Ge) cations

(2014) Jin-Chang Guo et al.   Computational and Theoretical Chemistry

Pseudo Jahn–Teller origin of instability of planar configurations of hexa-heterocycles C4N2H4X2 (X=H, F, Cl, Br)

(2014) Willian Hermoso et al.   Computational and Theoretical Chemistry

Pseudo-Jahn–Teller Effect—A Two-State Paradigm in Formation, Deformation, and Transformation of Molecular Systems and Solids

(2013) Isaac B. Bersuker   CHEMICAL REVIEWS

Why Is (SiO)4 Calculated To Be Tetrahedral, Whereas (CO)4 Is Square Planar? A Molecular Orbital Analysis

(2013) Sebastian Kozuch et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Kohn–Sham gap, the fundamental gap and the optical gap: the physical meaning of occupied and virtual Kohn–Sham orbital energies

(2013) E. J. Baerends et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Main Group Redox Catalysis: Reversible PIII/PV Redox Cycling at a Phosphorus Platform

(2012) Nicole L. Dunn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

SiC2Silagraphene and Its One-Dimensional Derivatives: Where Planar Tetracoordinate Silicon Happens

(2010) Yafei Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stabilization of Square Planar Silicon: A New Building Block for Conjugated Si-Containing Systems

(2009) D. Szieberth et al.   JOURNAL OF PHYSICAL CHEMISTRY A

Designing 3-D Molecular Stars

(2009) William Tiznado et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Divalent Carbon(0) Chemistry, Part 1: Parent Compounds

(2008) Ralf Tonner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Fifty years of the VSEPR model

(2007) R.J. Gillespie   COORDINATION CHEMISTRY REVIEWS