Article
Nanoscience & Nanotechnology
Enrica Luzzi, Paolo Aprea, Martina Salzano de Luna, Domenico Caputo, Giovanni Filippone
Summary: The study successfully prepared bead-shaped adsorbents with a high content of zeolite 13X using chitosan aerogel as a binding agent, achieving high specific surface area and excellent CO2 uptake capacity.
ACS APPLIED MATERIALS & INTERFACES
(2021)
Article
Engineering, Environmental
A. Gutierrez-Ortega, R. Nomen, J. Sempere, J. B. Parra, M. A. Montes-Moran, R. Gonzalez-Olmos
Summary: A new methodology for evaluating commercial adsorbents for CO2 capture using temperature swing adsorption has been developed. The study found that binderless zeolites performed better in CO2 production and desorption energy compared to their binder-based counterparts. The 13XBL binderless zeolite had the highest CO2 production and lowest desorption energy, while the 5A zeolites had the lowest CO2 production and highest desorption energy among the zeolites.
CHEMICAL ENGINEERING JOURNAL
(2022)
Article
Engineering, Environmental
Kourosh Kian, Simona Liguori, Helene Pilorge, James M. Crawford, Moises A. Carreon, Julia L. Martin, Ronald L. Grimm, Jennifer Wilcox
Summary: In this work, steam methane reforming was conducted in a palladium-based membrane reactor to produce ultrahigh purity hydrogen with methane conversions as high as 40%, even in the absence of sweep gas. The membrane reactor showed high selectivity towards hydrogen, with a maximum hydrogen recovery value of 43% achieved at an operating pressure of 400 kPa.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Chemistry, Multidisciplinary
Hammed A. Balogun, Daniel Bahamon, Saeed AlMenhali, Lourdes F. Vega, Ahmed Alhajaj
Summary: Adsorption of CO2 with porous solid materials is gaining attention as a promising CO2 capture technology. This study investigates the potential performance of MOFs Cu-BTC, Mg-MOF-74, and UTSA-16 at a commercial large-scale using multiscale modeling. The study shows that UTSA-16 MOF can be as effective as traditional zeolite 13X for industrial-scale carbon capture.
ENERGY & ENVIRONMENTAL SCIENCE
(2021)
Article
Engineering, Chemical
Joao Tingelinhas, Carolina Saragoca, Abeer Al Mohtar, Margarida Mateus, Moises L. Pinto
Summary: CO2 adsorption technology is considered a promising solution for mitigating greenhouse effects. This study focuses on the use of aluminum oxide (Al-PILC) and zirconium oxide (Zr-PILC) as adsorbents in the pressure swing adsorption (PSA) technology for carbon dioxide capture in the cement industry. Comparison with zeolite 13X shows that Zr-PILC exhibits the best performance with a purity of 76.6% and recovery of 72.1%.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Engineering, Environmental
Ana Pereira, Alexandre F. P. Ferreira, Alirio Rodrigues, Ana Mafalda Ribeiro, Maria Joao Regufe
Summary: This study assesses the potential of using additive manufacturing to produce hierarchically structured adsorbent materials with electrical conductivity for CO2 capture. The monolithic-shaped material obtained through direct ink writing process shows higher efficiency and faster regeneration in capturing CO2 compared to traditional packed beds. This research demonstrates the potential of employing direct ink writing technique to produce structured adsorbents for CO2 capture using electrical swing adsorption process.
CHEMICAL ENGINEERING JOURNAL
(2022)
Review
Chemistry, Physical
Dina G. Boer, Jort Langerak, Paolo P. Pescarmona
Summary: This article reviews the properties of zeolites as CO2 adsorbents and critically presents and discusses their advantages and limitations. Firstly, an overview of the CO2 adsorption mechanisms on different types of zeolites is provided. Then, the relationship between the physicochemical properties of zeolites (framework type, Si/Al ratio, and extra-framework cations) and their performance as CO2 adsorbents for the separation of CO2/CH4 (biogas) and CO2/N2 (flue gas) mixtures is systematically discussed. Based on the identified trends and properties, a comparison of different zeolites is made, highlighting their advantages and drawbacks for CO2 adsorption. Finally, the state of the art in the shaping of zeolites in macroscopic format, which is crucial for their industrial utilization as adsorbents, is presented.
ACS APPLIED ENERGY MATERIALS
(2023)
Article
Engineering, Environmental
Tai T. T. Nguyen, Jian-Bin Lin, George K. H. Shimizu, Arvind Rajendran
Summary: This study measured the adsorption equilibrium of pure CO2 and N-2 on a hydrophobic metal-organic framework called CALF-20, using volumetric and gravimetric methods. The competitive adsorption of CO2 and N-2 and the column dynamics were also examined. The results showed that CALF-20 had comparable performance with benchmark materials zeolite 13X and UTSA-16 in capturing CO2 under specific conditions.
CHEMICAL ENGINEERING JOURNAL
(2022)
Review
Chemistry, Multidisciplinary
Anuradha Sharma, Jitender Jindal, Anuj Mittal, Kavitha Kumari, Sanjeev Maken, Naveen Kumar
Summary: Environmental pollution is a serious issue, particularly due to fossil fuel pollution increasing atmospheric CO2 levels. The use of carbon capture and storage technologies, as well as adsorption techniques with carbon materials, show promise for addressing this issue. Factors such as micropore volume, surface area, and introduction of basic functional groups play crucial roles in CO2 adsorption.
ENVIRONMENTAL CHEMISTRY LETTERS
(2021)
Article
Engineering, Environmental
Matthias Schoukens, Mohsen Gholami, Gino V. Baron, Tom Van Assche, Joeri F. M. Denayer
Summary: In this study, a fully electrified temperature vacuum swing adsorption (TVSA) method was investigated for adsorbent regeneration in post-combustion carbon capture. Different strategies of simultaneous and sequential heating and evacuation were applied, and the performance indicators included the adsorbate loading, bed pressure, bed temperature, and mole fraction of CO2 at the outlet. By using the inductive TVSA process, it took significantly less time to reach a 90% regeneration level compared to using only vacuum evacuation. Additionally, short heating and evacuation times were found to maintain a large portion of the total bed capacity as working capacity.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
Shuang Zheng, Shaojuan Zeng, Yue Li, Lu Bai, Yinge Bai, Xiangping Zhang, Xiaodong Liang, Suojiang Zhang
Summary: The use of IL-modified adsorbents for CO2 capture shows promising application prospects due to the advantages of both ILs and porous supports, resulting in improved CO2 selectivity and specific surface area.
Article
Chemistry, Multidisciplinary
D. G. Boer, Z. Asgar Pour, S. Poli, J. Langerak, B. Bakker, P. P. Pescarmona
Summary: This article investigates a novel core-shell zeolite with a ZSM-5 core and a Silicalite-1 shell, which combines high CO2 adsorption capacity with hydrophobicity, making it suitable for the adsorption of CO2 from water-containing streams.
MATERIALS TODAY CHEMISTRY
(2023)
Article
Engineering, Environmental
Chongming Chen, Jinxing Yu, Guosheng Song, Kai Che
Summary: CO2 capture is a necessary option for carbon reduction, and adsorption-based CO2 capture technology provides a promising approach for lowering the energy cost of the mature amine-scrubbing method. Recent studies have focused on materials with high adsorption capacities, while overlooking desorption performance and the recovery of high purity CO2. In this study, four commercial zeolites were tested for CO2 capture from simulated flue gas, and 5 A zeolite was selected for systematic investigation of desorption behavior. A more practical temperature-swing procedure was proposed for desorption and regeneration of the material, achieving a CO2 stream with over 70% purity and 90% recovery in a single-stage adsorption.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2023)
Review
Chemistry, Multidisciplinary
Thien S. Nguyen, Nesibe A. Dogan, Haeseong Lim, Cafer T. Yavuz
Summary: The development of porous solid materials with tunable amine content is necessary for efficient CO2 capture, and unifying both sorbents in one system can address regeneration issues.
ACCOUNTS OF CHEMICAL RESEARCH
(2023)
Article
Engineering, Environmental
Anthony Vallace, Yi Ren, Christopher W. Jones, Ryan P. Lively
Summary: A reaction-diffusion shrinking core model is used to describe the decay in diffusivity of supported amine sorbents upon CO2 sorption. The decay is caused by crosslinking and pore blockage, which occur as CO2 is adsorbed. Four kinetic parameters governing CO2 uptake kinetics and working capacity are obtained from the model. The kinetic performance is correlated to the dispersion of sorption sites and morphology of the active sorbent phase. This work provides a first principles kinetic analysis of CO2 sorption, improving upon previous semi-empirical models.
CHEMICAL ENGINEERING JOURNAL
(2023)
Article
Engineering, Environmental
Sarra Wjihi, Fatma Aouaini, Alessandro Erto, Marco Balsamo, Abdelmottaleb Ben Lamine
Summary: The study investigates the CO2 adsorption from simulated flue-gas using three different activated carbons. It shows that micropore volume affects the adsorption capacity, while chemical properties play a secondary role. Advanced models derived from statistical physics are used to interpret the adsorption isotherms and provide insights into the adsorption mechanisms.
CHEMICAL ENGINEERING JOURNAL
(2021)
Article
Engineering, Chemical
Vassilis J. Inglezakis, Marco Balsamo, Fabio Montagnaro
Article
Chemistry, Physical
Salima Hamadouche, Ali Ounissi, Kaouther Baira, Nadia Ouddai, Marco Balsamo, Alessandro Erto, Yacine Benguerba
Summary: This study investigates the antiradical potential of four different compounds and their oxidation mechanisms and antioxidant activity rankings. The results indicate that T-OXY and T-CYCLE-OXY are the most effective antioxidant candidates among those tested.
JOURNAL OF MOLECULAR STRUCTURE
(2021)
Article
Chemistry, Physical
Khaoula Laouameur, Abdenacer Flilissa, Alessandro Erto, Marco Balsamo, Barbara Ernst, Guilherme Dotto, Yacine Benguerba
Summary: The study investigates the removal of benzodiazepine (clorazepate, CLZ) from aqueous solution by adsorption onto maghnite clay, supported by theoretical simulations. The results show that adsorption is maximum at low pH, driven mainly by electrostatic interactions, and follows the pseudo-first-order kinetic model. The complementary theoretical study reveals that CLZ assumes a horizontal position on the maghnite surface upon adsorption, characterized by high energy adsorption.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Thermodynamics
Amira Neni, Yacine Benguerba, Marco Balsamo, Alessandro Erto, Barbara Ernst, Djafer Benachour
Summary: The study focuses on Sorption-Enhanced Methane Steam Reforming (SE-MSR) process, highlighting the importance of temperature as a key parameter and the impact of exothermic carbonation reaction on the thermal regimes and performance of catalyst. Optimal operating conditions of both catalyst and adsorbent are crucial for maximizing hydrogen production and reducing CO2-related coke deposition.
INTERNATIONAL JOURNAL OF HEAT AND MASS TRANSFER
(2021)
Article
Chemistry, Physical
Walid Bououden, Yacine Benguerba, Ahmad S. Darwish, Ayoub Attoui, Tarek Lemaoui, Marco Balsamo, Alessandro Erto, Inas M. Alnashef
Summary: This study investigates the adsorption mechanisms and interactions of the anticancer molecule Crizotinib on carbon nanotubes (CNTs) and boron nitride nanotubes (BNNTs) using DFT and COSMO-RS. The results show that CZT has higher stability and adsorption energy on CNTs compared to BNNTs, indicating that CNTs are more stable and better carriers for drug delivery.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Article
Chemistry, Physical
Samra Amamra, Brahim Djellouli, Hayet Elkolli, Yacine Benguerba, Alessandro Erto, Marco Balsamo, Barbara Ernst, Djafer Benachour
Summary: This study focuses on the encapsulation/adsorption of sodium diclofenac on hydrotalcite cationic clays, exploring the mechanisms and influencing factors. Experimental data and various techniques confirm a strong interaction between sodium diclofenac and hydrotalcite.
JOURNAL OF MOLECULAR LIQUIDS
(2021)
Review
Chemistry, Physical
Oualid Alioui, Michael Badawi, Alessandro Erto, Mohammed A. Amin, Vineet Tirth, Byong-Hun Jeon, Saiful Islam, Marco Balsamo, Mirella Virginie, Barbara Ernst, Yacine Benguerba
Summary: Density Functional Theory (DFT) simulations play a significant role in gaining insights into the Dry Reforming of Methane (DRM) process and designing appropriate catalytic systems.
CATALYSIS REVIEWS-SCIENCE AND ENGINEERING
(2023)
Article
Energy & Fuels
Mauro Luberti, Alexander Brown, Marco Balsamo, Mauro Capocelli
Summary: The increasing demand for energy and commodities has led to a rise in greenhouse gas emissions, particularly carbon dioxide (CO2). Blue hydrogen (H-2), a low-carbon alternative to fossil fuels, has been suggested as an option for industries with hard-to-abate emissions. This study focuses on designing a vacuum pressure swing adsorption (VPSA) process that can capture CO2 from the tail gas of an industrial hydrogen plant. The research evaluates the impact of operating conditions on CO2 purity, recovery, bed productivity, and energy consumption. Conventional cycle configurations were found to be effective in concentrating CO2, making them suitable for decarbonizing existing hydrogen plants and producing blue H-2.
Article
Engineering, Chemical
Marco Balsamo, Fabio Montagnaro
Summary: The capture of CO2 from industrial flue gas by CaO in fluidized bed calcium looping processes is an effective way to reduce greenhouse gas emissions. This study developed an expression for the diffusivity of the product layer that takes into account the carbonation time using fractal-like dynamics concepts. The proposed fractal model based on the canonical random pore model demonstrated superior accuracy in predicting CO2 diffusion in the product layer under realistic operating conditions.
CHEMICAL ENGINEERING SCIENCE
(2022)
Article
Engineering, Chemical
Alzhan Baimenov, Fabio Montagnaro, Vassilis J. Inglezakis, Marco Balsamo
Summary: Two cryogels with different functional groups were used as adsorbents for the removal of cesium and strontium ions from aqueous solutions, and compared with commercial adsorbents. The cryogels exhibited competitive effectiveness for the removal of Cs+ and Sr2+, with only slight loss of adsorption capacity after multiple experiments.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2022)
Article
Engineering, Chemical
Maroua Nessaibia, Houria Ghodbane, Ilhem Djaghout, Abdelhalim Fetimi, Slimane Merouani, Manawwer Alam, Marco Balsamo, Alessandro Erto, Yacine Benguerba
Summary: This study investigates the decomposition of Acid Orange 10 dye using the H2O2/IO4- reactive system and evaluates the impact of various factors on the process efficiency. It found that the concentrations of H2O2 and IO4- exert a nonmonotonic effect on the removal of AO10, and acidic conditions significantly promote the degradation efficiency. Moreover, an increase in salinity decreases the effectiveness of AO10 removal.
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
(2023)
Article
Materials Science, Multidisciplinary
Majid Ghanimati, Mohsen Lashgari, Fabio Montagnaro, Vassilios Binas, Michalis Konsolakis, Marco Balsamo
Summary: The synthesis of low-cost, eco-friendly semiconducting solar-energy materials with excellent photocatalytic activity is important for environmental remediation, green energy, and fuel production. In this study, a magnetic heterojunction of CoMn2O4-MgFe2O4 and reduced graphene oxide (rGO) was synthesized, and the resulting nanocomposite exhibited improved reactant adsorption capacity and enhanced photocatalytic activity for hydrogen fuel production.
MATERIALS ADVANCES
(2023)
Article
Engineering, Environmental
Fabrizio Rainone, Ottavia D'Agostino, Alessandro Erto, Marco Balsamo, Amedeo Lancia
Summary: Biomethane production through biogas upgrading using commercial carbonaceous adsorbents was experimentally investigated in this study. It was found that activated carbon (AC) exhibited higher adsorption capacity and better kinetic performance, while carbon molecular sieves (CMSs) showed higher selectivity for CO2/CH4 separation and faster kinetics, with Xintao sample showing the best overall performance. Modeling of breakthrough curves indicated intraparticle diffusion as the rate-limiting step for CO2 adsorption.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Engineering, Chemical
Yunfei Yu, Xue Yang, Chenchen Zhang, Jie Chen, Wei Lin, Jianqiang Meng
Summary: This study reports an environmentally friendly and simple approach for preparing double-network (DN) ion gel membranes with high strength and excellent gas separation performance. By optimizing crosslinking density, mass ratio, and the type and content of free ionic liquid, the mechanical and gas separation properties of the DN membrane are improved.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Si-qi Jiang, Qiang Gao, Xi-guang Li, Chao-zhu Deng, Jun Qiu, Xiang-nan Zhu
Summary: A dual-strengthening pretreatment method is proposed to remove PVDF more efficiently and enhance the leaching of LiCoO2. Experimental results show that dual-strengthening pretreatment can effectively remove PVDF and significantly improve the leaching efficiency compared to single pretreatment methods.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Zengchi Hu, Xiaoyu Wang, Xiaohui Zhang, Xue Li, Jiangbin Xia
Summary: The rapid fabrication of high-performance composite membranes based on CMPs using simple and low-cost methods is challenging. In this study, three CMPs-based composite membranes were rapidly fabricated with adjustable size using unidirectional diffusion synthesis. The microstructural design enhanced the rejection rates of the membranes and they showed strong hydrolytic resistance, thermal stability, and acid-base resistance. Electrostatic adsorption and the adjustable microstructures significantly varied the repellence of the membranes to different charged molecules.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Farzaneh Rouhani, Matineh Ayedi, Nasser Safari
Summary: Introducing defects into porous metal-organic frameworks is important for improving their adsorption performance. Quasi-MOFs, an underutilized variant of large-scale, fundamentally deficient MOFs, have been found to have substantial amounts of unsaturated metal sites to offset the drawbacks of MOFs. In this study, a quasi-MOF was produced using a water-stable MOF and demonstrated significantly improved phosphate adsorption capability due to the presence of defect sites.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Valentin Reungoat, Morad Chadni, Louis M. M. Mouterde, Fanny Brunissen, Florent Allais, Helene Ducatel, Irina Ioannou
Summary: This study focuses on the recovery of sinapic acid using liquid-liquid extraction assisted by a hollow fiber membrane contactor from an aqueous feed obtained through the hydrolysis of mustard bran. The screening of solvents of different chemical nature showed that all tested solvents had an extraction efficiency of more than 80% for pH < 5. Four solvents were selected for use in the hollow fiber membrane contactor, and the volatile solvents showed higher mass transfer coefficients compared to non-volatile solvents. The extraction efficiency was intensified by increasing the initial concentration of sinapic acid and the feed-to-solvent ratio. CPME was found to have optimal recovery efficiency at a phase ratio of 8:1, yielding 0.9 g of sinapic acid per liter of CPME used.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Takahiro Sakamoto, Takafumi Hanada, Hayate Sato, Mayu Kamisono, Masahiro Goto
Summary: The emergence of the battery society has led to a high demand for battery metals, resulting in a strain on their supply. This study introduces a novel technique using a hydrophobic deep eutectic solvent (DES) for leaching and recovering battery metals from low-grade nickel laterite ores. The DES enables selective leaching and recovery of the metals, offering a promising pathway for the extraction of critical battery metals.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Rongrong He, Jiarui Chen, Chunyao Zhang, Dan Lu, Lin Zhang, Tao He
Summary: Researcher has developed a method to quantify the charge density in nanofiltration (NF) membrane separation layer and applied it in NF membranes that can separate Mg2+ and Li+. The results showed that overcompensated amine groups played a major role, and there was a linear relationship between charge density and coating bi-layers or PAH layers.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Zhijian Zhang, Min Chen, Zhe Lin, Zhichao Yang, Yafeng Du, Zhihui Chen, Zhenhao Yang, Kongyin Zhao, Ligang Lin
Summary: Membrane technology plays an important role in molecular/ion separation processes, but faces challenges such as membrane fouling. This study introduces a new ion-crosslinking method to fabricate copper alginate hydrogel membranes with improved mechanical strength and antimicrobial capabilities. The membranes exhibit excellent separation performance and enhanced long-term molecule/ion separation through improved anti-swelling properties. Molecular dynamics simulations and life cycle analysis highlight the pore structure and environmental friendliness of the hydrogel membranes. These findings provide valuable insights for developing sustainable hydrogel membranes with stable performance and high separation efficiency.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Dongmei Liu, Aiying Guo, Yanling Qi, Zhixin Ji, Hongjuan Li, Zhiwei Zhang, Xinyue Zhang, Kunze Wu, Aijun Cai
Summary: In this study, a stable magnetic Mg/Mn-layered double oxide-doped biochar composite (MgMnLDO-MBC) was prepared and successfully used for the removal of antibiotics and bacteria from wastewater. The composite exhibited enhanced surface areas, adsorption sites, and free radicals, leading to improved catalytic activity. The effects of different factors on the removal efficiency were evaluated, and the composite showed good reusability.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Feng Wang, Zhaoyong Bian, Yaru Zhang, Wenchao Yu, Qiang Zhang, Hui Wang
Summary: In this study, a nanofibrous layered structure of Ff-Ti3C2Tx-Co3O4 was prepared by self-assembling nanofibrous Co3O4 with lamellar fluorine-free MXene (Ff-Ti3C2Tx). The Ff-Ti3C2Tx-Co3O4 exhibited excellent catalytic activity for degradation, resistant to ionic interference, and maintained high removal efficiency of sulfamethoxazole (SMX) in municipal wastewater. The rapid SMX degradation involved fast electron transfer in redox cycles with PMS and the generation of 1O2 via PMS ->center dot O2 -> 1O2. This work provides new insights into antibiotic degradation mechanisms and electron transfer based on PMS activation.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Weipeng He, Jiacheng Luo, Yujie Wu, Tianhao Luo, Chen Tang
Summary: This study comparatively evaluated the role of cationic, anionic, and nonionic polyacrylamides (PAMs) in ballasted flocculation of clay suspensions under different aluminum sulfate (AS) coagulant dosages. The selection of PAMs and AS dosage had a significant influence on the size and shear resistance of ballasted floc aggregates.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Lixian Wang, Lizhi Zhao, Didi Si, Zhixin Li, Huiqin An, Hui Ye, Qingping Xin, Hong Li, Yuzhong Zhang
Summary: Metalloporphyrin-based nanozymes integrated with poly (vinylidene fluoride) membrane show high catalytic activity and reusability for the decolorization of Congo Red dye in continuous flow process.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Yongfei Ma, Chenyu Zeng, Yongzhen Ding, Jiayi Tang, Ondrej Masek, Zhikang Deng, Rui Mu, Zulin Zhang
Summary: In this study, sludge-derived biochar (SBC) was functionalized with various iron salts to enhance its adsorption ability for sulfamethoxazole (SMX) and magnetic collection performance. Ball milling was further employed to treat the optimal iron salt functionalized SBC (MSBC), resulting in ball milled SBC (BMSBC) with improved adsorption performance for SMX. The dominant driving mechanism for SMX adsorption onto BMSBC was confirmed to be multiple physicochemical forces, including 7C-7C conjugation, pore filling, H-bonding, Fe-O complexation, and electrostatic interactions. BMSBC exhibited favorable adsorption ability for SMX in actual waters and could be easily collected within 1 min due to its magnetic sensitivity.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Jinglin Tan, Xiaohui Mao, Wenjihao Hu, Hongbo Zeng
Summary: This study investigates the influence of PDMS chain architectures on surface properties and reveals that PDMS coatings with looped structures exhibit superior hydrophobicity, self-cleaning, and water sliding compared to coatings with linear structures. Additionally, both looped and linear PDMS coated stainless steel mesh/polyester fibers show efficient separation of oil/water mixture.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)
Article
Engineering, Chemical
Wei-Liang Chen, Chih-Chia Cheng, Chien-Hsing Lu, Jem-Kun Chen
Summary: This study designs a novel sandwich-structured capacitor that reduces the absorption time of pollutants using dielectrophoresis force. By coating graphene oxide on polystyrene microspheres as adsorbents and encapsulating them within the capacitor, the adsorption rate is significantly enhanced. Additionally, frequency manipulation allows for the recycling of adsorbents and concentration of dyes, minimizing secondary pollution.
SEPARATION AND PURIFICATION TECHNOLOGY
(2024)