4.7 Article

Purification of landfill gas by extracted calcium ions from municipal solid waste incineration fly ash

Journal

SCIENCE OF THE TOTAL ENVIRONMENT
Volume 807, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.scitotenv.2021.150729

Keywords

Carbon capture and utilization; MSWI fly ash; Gas purification; Extraction method; Landfill gas; Resource recovery

Funding

  1. Korea South-East Power Co. [2020-KOEN]
  2. Korea Environment Industry & Technology Institute (KEITI) - Korea Ministry of Environment (MOE) [2021003280002]

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This study proposed a method for purifying landfill gas by utilizing CO2, involving the absorption of CO2 from landfill gas, extraction of calcium ions from fly ash, and formation of calcium carbonate. Different acids were used for calcium ion extraction, resulting in varying calcium ion recovery rates and different crystal structures of calcium carbonate. The results can be applied to various CO2 utilization processes based on landfill gas and fly ash from municipal solid waste incineration.
This study proposes the utilization of CO2 based on the purification of landfill gas (LFG). The process included absorption of CO2 from LFG using monoethanolamine (MEA) absorbent, extraction of calcium ions from municipal solid waste incineration (MSWI) fly ash using various acids, and formation of calcium carbonate using the extracted calcium ions. During LFG purification, the concentration of CH4 in the gas after absorption was time dependent. The pH swing method was used for the extraction of calcium ions and comprised three phases: calcium ion leaching from MSWI fly ash phase, removal of cations from the supernatant, and calcium ion recovery. Hydrochloric and nitric acids, known as strong acids, and citric, acetic, and formic acids, which are weak acids, were used as extraction agents. Hydrochloric acid, nitric acid, acetic acid, and formic acid showed significant calcium ion recovery rates of 99.32%, 99.18%, 98.35%, and 97.99%, respectively, whereas citric acid showed a relatively low recovery rate of 82.82%. The extracted calcium ions were converted into calcium carbonate by reacting with ionic CO2 in the saturated MEA. The calcium carbonate formed showed different crystal structures based on the extraction agent used: aragonite for hydrochloric acid and nitric acid, amorphous CaCO3 for citric acid, vaterite for acetic acid, and calcite for formic acid. The results of this study can be applied to various CO2 utilization processes based on LFG and MSWI fly ash. (C) 2021 Published by Elsevier B.V.

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