Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 70, Issue -, Pages 157-159Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.inoche.2016.06.009
Keywords
Crystal engineering; Silver cluster; Anions sensor; Fluorescence spectrum
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An unique and novel octanuclear silver(I) cluster compound, [Ag-8(ADC)(4)](n) (1) (H(2)ADC = 1,3-adamantanedicarboxylic acid), has been synthesized and characterized. Compound 1 exhibits significant Ag-Ag interactions to form 2D infinite silver layers with multiple unsaturated Ag atoms. Moreover, Luminescent investigations show that 1 can exhibit highly selective response to Cr2O72- through luminescence quenching effect in aqueous solution, which make its good candidate as luminescent sensor. (C) 2016 Elsevier B.V. All rights reserved.
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