Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 66, Issue -, Pages 59-63Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2016.01.020
Keywords
Crystal structures; Lanthanide complexes; Solvothermal synthesis; Magnetic properties
Categories
Funding
- National Natural Science Foundation of China [50872057]
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A new series of lanthanide metal complexes [Ln(L)(3)](n) (L = p-methoxybenzoic acid, Ln = Pr 1, Eu 2, Tb 3, Dy 4, Ho 5, Er 6, Yb 7) have been synthesized under hydrothermal conditions. Single-crystal X-ray diffraction measurements reveal that these compounds are isostructural, crystallizing in the monoclinic space group P2(1)/c and giving 1D chain structures. Magnetic studies reveal antiferromagnetic behavior for complexes 1, 3, 5 and 6, ferromagnetic behavior for complex 4 and spin-canting behavior for 7. (C) 2016 Elsevier B.V. All rights reserved.
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