4.7 Article

Dual-wavelength extinction rainbow refractometry for in-situ characterization of colloidal droplets

Journal

POWDER TECHNOLOGY
Volume 399, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.powtec.2021.117098

Keywords

Colloidal suspension droplet; Rainbow refractometry; In situ multi-parameter characterization; Nanoparticle size and concentration; Extinction

Funding

  1. National Natural Science Foundation of China [52006193]
  2. Natural Science Foundation of Jiangsu Province [BK20190439]
  3. Shuangchuang Program of Jiangsu Province [JSSCBS20210207]

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There is significant interest and demand for the multi-parameter characterization of colloidal droplets. However, optical in-situ characterization of such droplets poses a challenge due to their heterogeneous and multi-scale nature. This study proposes an analytical model for dual-wavelength extinction rainbow refractometry, which allows for the simultaneous measurement of inclusion concentration, particle size, refractive index, and droplet diameter. Validation experiments demonstrate the effectiveness of this method, and the measurement errors and limitations are analyzed.
Considerable interest and demand exists in multi-parameter characterization of colloidal droplets. However, an optical in-situ characterization of such droplets is a particular challenge due to its heterogeneous and multi-scale nature, motivating the investigation of a dual-wavelength extinction rainbow refractometry. An analytical model is proposed, in which dual-wavelength extinction effect of the inclusions on the amplitude of the primary rainbow peak allows measurement of inclusion concentration and particle size. The rainbow pattern itself yields the refractive index and diameter of the host droplet. Validation experiments using deionized monodisperse water droplets containing standard polystyrene nanoparticles with different concentrations (0%, 0.1%, 0.2%, 0.3%) and particle sizes (210 nm, 530 nm) were conducted. Measured refractive indices and droplet diameters agree well with the known values. Measurement errors of inclusion concentration and size were analyzed with and without a prior knowledge of the inclusion size. Measurement limits of this approach are also discussed. (c) 2022 Elsevier B.V. All rights reserved.

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